MOULDING COMPOUND BASED ON A PARTIALLY AROMATIC COPOLYAMIDE
A moulding composition, comprising at least 40 wt. % of the following components: a) 60 to 99 parts by wt. of a partially aromatic copolyamide which comprises as polymerized monomer units: I. 30 to 90 mol % of a combination of hexamethylenediamine and terephthalic acid; and II. 70 to 10 mol % of a lactam and/or of an ω-aminocarboxylic acid with 11 or 12 C atoms; and b) 40 to 1 parts by wt. of an olefinic copolymer comprising as polymerized monomer units: i) 35 to 94.9 wt. % of ethene-based monomer units, ii) 5 to 65 wt. % of monomer units based on a 1-alkene with 4 to 8 C atoms, iii) 0 to 10 wt. % of monomer units based on an olefin different from i) and ii), and iv) 0.1 to 2.5 wt. % of monomer units based on an aliphatically unsaturated dicarboxylic acid anhydride, wherein a sum of the weight % values of i), ii), iii) and iv) is 100%, and the sum of the parts by wt. of a) and b) is 100; which can is processed into moulded articles with improved thermal aging resistance is provided.
1 . A moulding composition, comprising at least 40 wt. % of the following components:
a) 60 to 99 parts by wt. of a partially aromatic copolyamide which comprises as polymerized monomer units:
I. 30 to 90 mol % of a combination of hexamethylenediamine and terephthalic acid; and
II. 70 to 10 mol % of a lactam and/or of an ω-aminocarboxylic acid with 11 or 12 C atoms,
wherein the mol % values relate to the sum of I and II and wherein at most 20% of the hexamethylenediamine can be replaced by the equivalent quantity of another diamine and/or wherein at most 20% of the terephthalic acid can be replaced by the equivalent quantity of another aromatic dicarboxylic acid and/or 1,4-cyclohexanedicarboxylic acid and/or wherein at most 20% of the repeating units of a lactam and/or of an ω-aminocarboxylic acid with 11 or 12 C atoms can be replaced respectively by the equivalent number of units which are derived from a combination of hexamethylenediamine and a linear aliphatic dicarboxylic acid with 8 to 19 C atoms and/or caprolactam;
b) 40 to 1 parts by wt. of an olefinic copolymer comprising as polymerized monomer units:
i) 35 to 94.9 wt. % of ethene-based monomer units,
ii) 5 to 65 wt. % of monomer units based on a 1-alkene with 4 to 8 C atoms,
iii) 0 to 10 wt. % of monomer units based on an olefin different from i) and ii), and
iv) 0.1 to 2.5 wt. % of monomer units based on an aliphatically unsaturated dicarboxylic acid anhydride,
wherein
a sum of the weight % values of i), ii), iii) and iv) is 100%, and
the sum of the parts by wt. of a) and b) is 100.
2 . The moulding composition according to claim 1 ,
wherein a crystallite melting point T m of the copolyamide a) is from 240° C. to 300° C. when determined according to ISO 11357, measured during the 2nd heating stage.
3 . The moulding composition according to claim 1 ,
wherein a ratio of amino end groups to a sum of amino and carboxyl end groups of the partially aromatic copolyamide is from 0.3 to 0.7.
4 . The moulding moulding composition according to claim 1 ,
wherein the monomer unit iii) of the olefinic copolymer b) does not comprise an unconjugated diene.
5 . The moulding composition according to claim 1 ,
wherein the monomer unit iii) of the olefinic copolymer b) does not comprise styrene or propene.
6 . The moulding composition according to claim 1 , wherein
the olefinic copolymer consists of:
i) 35 to 94.9 wt. % of ethene-based monomer units,
ii) 5 to 65 wt. % of monomer units based on a 1-alkene with 4 to 8 C atoms, and
iv) 0.1 to 2.5 wt. % of monomer units based on an aliphatically unsaturated dicarboxylic acid anhydride.
7 . The moulding composition according to claim 1 ,
wherein the 1-alkene with 4 to 8 C atoms ii) is at least one of 1-butene, 1-hexene and 1-octene.
8 . The moulding composition according to claim 1 , further comprising 0.01 to 60 wt. % of an additive selected from the group consisting of a stabilizer, a polymer different from a) and b), a fibrous reinforcing material, a filler, a plasticizer, a pigment, a colorant, a flame retardant and a processing aid.
9 . The moulding composition according to claim 8 ,
wherein the moulding composition comprises a stabilizer which is a copper-containing stabilizer.
10 . The moulding composition according to claim 9 , wherein the copper-containing stabilizer is a copper(I) salt in combination with an alkali metal halide.
11 . The moulding composition according to claim 10 , wherein the copper(I) salt is selected from the group consisting of copper acetate, copper stearate, copper acetylacetonate, and a copper halide.
12 . The moulding composition according to claim 10 , wherein the alkali metal halide is selected from the group consisting of iodides and bromides of lithium, sodium and potassium.
13 . The moulding composition according to claim 9 , wherein a copper content of the moulding composition is from 20 to 2000 ppm of copper.
14 . The moulding composition according to claim 8 ,
wherein the moulding composition comprises a stabilizer which is an oxidation stabilizer.
15 . A moulded article comprising the moulding composition of claim 1 .
16 . The moulded article according to claim 15 , wherein the moulded article is a monolayer pipe or a multilayer pipe.
17 . The moulded article according to claim 15 , wherein the moulded article is a monolayer container or a multilayer container.