Fluidized catalytic cracking apparatus
View Patent ↗The present application generally relates to a fluidized catalytic cracking apparatus having one or more ports for injecting a renewable fuel oil for co-processing the renewable fuel oil and a petroleum fraction.
1. A fluidized catalytic cracking apparatus for co-processing an unenriched renewable fuel oil and a petroleum fraction, comprising:
a riser having at least a first injection port and at least a second injection port;
the at least first injection port for injecting the petroleum fraction;
the at least second injection port for injecting the unenriched renewable fuel oil into the riser, the at least second injection port being corrosion resistant to the unenriched renewable fuel oil;
at least one tank for storing and delivering the unenriched renewable fuel oil, the at least one tank being corrosion resistant to the unenriched renewable fuel oil; and
a preheater to preheat the unenriched renewable fuel oil prior to injecting the unenriched renewable fuel oil into the riser,
wherein the unenriched renewable fuel oil is derived from a non-catalytic conversion of a cellulosic biomass and comprises a carbon content of at least 40 wt. % on a moisture-free basis, an oxygen content in the range of between 20-50 wt. % on a moisture-free basis, and a water content in the range of between 10-40 wt. %, and
wherein the at least second injection port is:
designed to inject less than 10 wt. % of the unenriched renewable fuel oil into the riser relative to the total amount of the petroleum fraction injected into the riser; and
located proximate the at least first injection port.
2. The apparatus of claim 1 , wherein the at least second injection port comprises 304 stainless steel.
3. The apparatus of claim 1 , wherein the at least second injection port is designed to inject 0.05-7 wt. % of the unenriched renewable fuel oil into the riser relative to the total amount of the petroleum fraction injected into the riser.
4. The apparatus of claim 1 , wherein the at least second injection port is designed to inject less than 1 wt. % of the unenriched renewable fuel oil into the riser relative to the total amount of the petroleum fraction injected into the riser.
5. The apparatus of claim 1 , wherein the at least first injection port and the at least second injection port are located in the lower third of the riser.
6. The apparatus of claim 1 , wherein the at least second injection port is further a port for introducing lift steam to the riser.
7. The apparatus of claim 1 , wherein the at least second injection port is further a port for introducing recycle lift vapor to the riser.
8. The apparatus of claim 1 , wherein the unenriched renewable fuel oil has a pH in the range of 3-7.
9. The apparatus of claim 1 , wherein the unenriched renewable fuel oil has a pH of less than 3.
10. The apparatus of claim 1 , wherein the unenriched renewable fuel oil has a solids content in the range of 0.5-3 wt. %.
11. The apparatus of claim 1 , wherein the unenriched renewable fuel oil has a solids content of less than 0.5 wt. %.
12. The apparatus of claim 1 , wherein:
i) the unenriched renewable fuel oil has a solids content of less than 0.5 wt. %;
ii) the unenriched renewable fuel oil has a pH of less than 3; and
iii) the at least first injection port and the at least second injection port are located in the lower third of the riser.
13. The apparatus of claim 12 , wherein the unenriched renewable fuel oil has an ash content of less than 0.1 wt. %.
14. The apparatus of claim 12 , wherein the at least second injection port is designed to inject 0.05-7 wt. % of the unenriched renewable fuel oil into the riser relative to the total amount of the petroleum fraction injected into the riser.
15. The apparatus of claim 12 , wherein the at least second injection port is designed to inject less than 1 wt. % of the unenriched renewable fuel oil into the riser relative to the total amount of the petroleum fraction injected into the riser.
16. The apparatus of claim 1 , wherein the unenriched renewable fuel oil has an ash content of less than 0.1 wt. %.
17. The apparatus of claim 1 , wherein the unenriched renewable fuel oil has an ash content of less than 0.05 wt. %.
18. The apparatus of claim 1 , wherein the at least second injection port comprises 316 stainless steel.
19. The apparatus of claim 1 , wherein the at least second injection port comprises titanium.