Granted Patent B2

US 9,550,908 · App. 14/493,398 · Granted Jan 24, 2017

Inventors: Gordon Sisler (Ontario, CA); Guiqin Song (Milton, CA); Marcel P. Breton (Mississauga, CA); Suxia Yang (Mississauga, CA)

Assignee: XEROX CORPORATION

C09D129/04B41J2/0057C09D7/1233C09D103/12C09D133/10C09D133/26C09D139/06C09D171/02C08K5/053C08K5/06C08K5/5419

Abstract

Claims (49)

1. An indirect printing apparatus comprising:

an intermediate transfer member; a sacrificial coating on the intermediate transfer member, the sacrificial coating made from ingredients comprising:

at least one hydrophilic polymer;

at least one hygroscopic material;

at least one oil-in-water emulsion; and

at least one surfactant,

a coating mechanism for forming the sacrificial coating onto the intermediate transfer member;

a drying station for drying the sacrificial coating;

at least one ink jet nozzle positioned proximate the intermediate transfer member and configured for jetting ink droplets onto the sacrificial coating formed on the intermediate transfer member;

an ink processing station configured to at least partially dry the ink on the sacrificial coating formed on the intermediate transfer member; and

a substrate transfer mechanism for moving a substrate into contact with the intermediate transfer member,

wherein the at least one hydrophilic polymer is polyvinyl alcohol having a hydrolysis degree ranging from about 75% to about 99.5% and weight average molecular weight ranging from about 8000 to about 30,000 g-mole −1 .

2. An indirect printing apparatus comprising:

an intermediate transfer member; a sacrificial coating on the intermediate transfer member, the sacrificial coating made by mixing ingredients to form a wet coating composition and then coating the wet coating composition onto the intermediate transfer member, the ingredients comprising:

at least one hydrophilic polymer;

at least one hygroscopic material;

at least one oil-in-water emulsion; and

at least one surfactant,

a coating mechanism for forming the sacrificial coating onto the intermediate transfer member;

a drying station for drying the sacrificial coating;

at least one ink jet nozzle positioned proximate the intermediate transfer member and configured for jetting ink droplets onto the sacrificial coating formed on the intermediate transfer member;

an ink processing station configured to at least partially dry the ink on the sacrificial coating formed on the intermediate transfer member; and

a substrate transfer mechanism for moving a substrate into contact with the intermediate transfer member.

3. The indirect printing apparatus of claim 2 , wherein the at least one hydrophilic polymer is selected from the group consisting of polyvinyl alcohol, a copolymer of vinyl alcohol and alkene monomers, poly(vinylpyrrolidinone) (“PVP”), poly(ethylene oxide), hydroxyethyl cellulose, cellulose acetate, poly(ethylene glycol), copolymers of poly(ethylene glycol), polyacrylamide (PAM), poly(N-isopropylacrylamide) (“PNIPAM”), poly(acrylic acid), polymethacrylate, acrylic polymers, maleic anhydride copolymers, sulfonated polyesters, polysaccharides, waxy maize starches and the mixtures thereof.

4. The indirect printing apparatus of claim 2 , wherein the at least one hydrophilic polymer is selected from waxy maize starches comprising more than 90 weight percent amylopectin.

5. The indirect printing apparatus of claim 2 , wherein the at least one oil-in-water emulsion is present in an amount ranging from about 0.05% to about 8% by weight relative to the total composition weight.

6. The indirect printing apparatus of claim 2 , wherein the at least one hygroscopic material is selected from the group consisting of glycerol, sorbitol, glycols, vinyl alcohols, xylitol, maltitol, polymeric polyols, glyceryl triacetate, glycouril, ionic liquids and mixtures thereof.

7. The indirect printing apparatus of claim 2 , wherein the at least one oil-in-water emulsion comprises an oil selected from the group consisting of a silicone oil, a perfluoroether oil, a hydrocarbon oil and mixtures thereof.

8. The indirect printing apparatus of claim 7 , wherein a viscosity of the silicone oil is less than 1000 centipoises.

9. The indirect printing apparatus of claim 2 , wherein the at least one oil-in-water emulsion comprises a mineral oil selected from the group consisting of paraffinic oils, naphthenic oils, aromatic oils and mixtures thereof.

10. The indirect printing apparatus of claim 2 , wherein the oil-in-water emulsion comprises at least one nonionic surfactant with hydrophile lipophile balance (HLB) value from 4 to 15.

11. The indirect printing apparatus of claim 2 , wherein the surfactant comprises a mixture of a first surfactant and a second surfactant, the first surfactant having a hydrophile lipophile balance (“HLB”) value ranging from about 8 to about 15 and the second surfactant having an HLB value ranging from about 4 to about 10, the HLB value for the first surfactant being higher that the HLB value for the second surfactant.

12. The indirect printing apparatus of claim 2 , wherein the surfactant is a secondary alcohol ethoxylate.

13. The indirect printing apparatus of claim 2 , wherein the surfactant is a branched secondary alcohol ethoxylate with 6 to 12 moles of ethylene oxide (EO).

14. The apparatus of claim 2 , wherein the oil-in-water emulsion comprises an oil selected from the group consisting of a silicone oil and a hydrocarbon oil; and the at least one hydrophilic polymer is polyvinyl alcohol having a hydrolysis degree ranging from about 75% to about 99.5% and weight average molecular weight ranging from about 8000 to about 30,000 g-mole −1 .

15. An indirect printing process comprising:

providing an ink composition to an inkjet printing apparatus comprising an intermediate transfer member;

forming a sacrificial coating onto the intermediate transfer member, the sacrificial coating made by mixing ingredients to form a wet coating composition and then coating the wet coating composition onto the intermediate transfer member, the ingredients comprising:

at least one hydrophilic polymer;

at least one hygroscopic material;

at least one oil-in-water emulsion; and

at least one surfactant;

drying the sacrificial coating to form at least a partially dry sacrificial coating;

ejecting droplets of ink in an imagewise pattern onto the at least partially dry sacrificial coating;

at least partially drying the ink to form a substantially dry ink pattern on the intermediate transfer member; and

transferring both the substantially dry ink pattern and the at least partially dry sacrificial coating from the intermediate transfer member to a final substrate.

16. The process of claim 15 , wherein the substantially dry ink pattern comprises less than 5% water and other liquid vehicles, based on the total weight of the dry ink.

17. The process of claim 15 , wherein the oil is selected from the group consisting of a silicone oil and a hydrocarbon oil; and the at least one hydrophilic polymer is polyvinyl alcohol having a hydrolysis degree ranging from about 75% to about 99.5% and weight average molecular weight ranging from about 8000 to about 30,000 g-mole −1 .

18. The process of claim 15 , wherein the at least one hydrophilic polymer is selected from the group consisting of polyvinyl alcohol, a copolymer of vinyl alcohol and alkene monomers, poly(vinylpyrrolidinone) (“PVP”), poly(ethylene oxide), hydroxyethyl cellulose, cellulose acetate, poly(ethylene glycol), copolymers of poly(ethylene glycol), polyacrylamide (PAM), poly(N-isopropylacrylamide) (“PNIPAM”), poly(acrylic acid), polymethacrylate, acrylic polymers, maleic anhydride copolymers, sulfonated polyesters, polysaccharides, and the mixtures thereof.

Assignments (8)

Continuity (1)