Nickel based alloy for forging
A nickel (Ni) based alloy for forging includes: 0.001 to 0.1 wt. % of carbon (C); 12 to 23 wt. % of chromium (Cr); 3.5 to 5.0 wt. % of aluminum (Al); 5 to 12 combined wt. % of tungsten (W) and molybdenum (Mo) in which the Mo content is 5 wt. % or less; a negligible small amount of titanium (Ti), tantalate (Ta) and niobium (Nb); and the balance of Ni and inevitable impurities.
1. A steam turbine rotor used at a temperature of 750° C. or higher, comprising at least two parts along a steam flow direction and assembled by welding the at least two parts, wherein a higher temperature part of the at least two parts on a side where steam enters is a forged product made of a Ni based alloy, the Ni based alloy including:
0.001 to 0.04 wt. % of C; 12 to 23 wt. % of Cr; 3.5 to 5.0 wt. % of Al; more than 15 wt. % but not more than 23 wt. % of Co; 5 to 12 combined wt. % of W and Mo in which the Mo content is 5 wt. % or less; 0.5 or less combined wt. % of Ti, Ta and Nb; and the balance of Ni and inevitable impurities,
wherein Ni 3 Al phase grains of an average diameter of 50 to 100 nm precipitate in the alloy with a volume percentage of 30% or more at or below 700° C.; temperature of solid solution limit line (solvus temperature) of the Ni 3 Al phase is 1000° C. or lower; and 100,000-hour creep rupture strength of the alloy is 100 MPa or more at 750° C.
2. The steam turbine rotor according to claim 1 , wherein the forged product is prepared by a procedure including:
(a) hot forging the Ni based alloy into a predetermined shape at a temperature higher than a temperature of solid solution limit line (solvus temperature) of Ni 3 Al phase,
(b) subjecting the hot forged alloy to a solution treatment above the temperature of solid solution limit line of the Ni 3 Al phase, and
(c) subjecting the heat treated alloy to an artificially aging treatment below the temperature of solid solution limit line of the Ni 3 Al phase to precipitate Ni 3 Al phase grains in the alloy.