Catalyst for the hydrotreatment of a heavy hydrocarbon feedstock
View Patent ↗Disclosed is a method of hydrotreating a heavy hydrocarbon feedstock using a hydrotreating catalyst having specific properties that make it effective in converting nitrogen, sulfur and micro-carbon residue of a heavy hydrocarbon feedstock. The catalyst comprises a calcined support particle impregnated with a Group 6 metal component (e.g., molybdenum), a nickel component, and a phosphorus component present at concentrations in the catalyst such that the atomic ratio of the Group 6 metal-to nickel metal are within a specified range. The nickel metal acid extractability property of the catalyst is at least 50 percent.
1. A method of making a catalyst composition useful in the hydrotreatment of a heavy hydrocarbon feedstock, wherein said method comprises the steps of:
incorporating a nickel compound into a support particle comprising an inorganic oxide material;
conducting a high-temperature calcination of the support particle so as to provide a calcined support particle;
impregnating said calcined support particle with an aqueous impregnation solution, wherein said aqueous impregnation solution comprises a Group 6 metal compound, a nickel compound and a phosphorus compound, and wherein said aqueous impregnation solution has an atomic ratio of nickel metal to a Group 6 metal in the range of from 0.5 to 0.75, to thereby provide an impregnated support particle; and
conducting a controlled low-temperature calcination of said impregnated support particle at a low calcination temperature of less than 450° C. (842° F.) so as to thereby provide a calcined catalyst particle having a nickel metal acid extractability property of at least 40%.
2. A method according to claim 1 , wherein said calcined catalyst particle contains: a Group 6 metal component in an amount in the range of from 8 wt % to 18 wt %; a nickel component in an amount in the range of from 2 wt % to 7 wt %; and a phosphorus component in an amount in the range of from 0.8 wt % to 4 wt %, all of which are based on the weight of calcined catalyst particle and the metal components as oxides regardless of their actual form.
3. A method according to claim 2 , wherein said Group 6 metal component is molybdenum.
4. A method according to claim 3 , wherein the total quantity of phosphorus in said calcined catalyst particle, calculated as phosphorus pentoxide, is greater than 10% of the total quantity of said Group 6 metal component in said calcined catalyst particle, calculated as molybdenum trioxide.
5. A method according to claim 4 , wherein said calcined catalyst particle has a surface area that exceeds 150 m 2 /g.
6. A method according to claim 5 , wherein said calcined catalyst particle has a mean pore diameter in the range of from 90 Å to 120 Å.
7. A method according to claim 6 , wherein said low calcination temperature is in the range of from 300° C. (572° F.) to less than 450° C. (842° F.).