Method for producing rubber composition and rubber composition
View Patent ↗A method for producing a rubber composition include a mixing step, a drying step, and a dispersion step. In the mixing step, an aqueous solution that includes at least one of oxycellulose fibers and cellulose nanofibers is mixed with rubber latex to obtain a first mixture. In the drying step, the first mixture is dried to obtain a second mixture. In the dispersion step, the second mixture is tight-milled using an open roll to obtain a rubber composition. The rubber composition does not include an aggregate that includes at least one of the oxycellulose fibers and the cellulose nanofibers, and has a diameter of 0.1 mm or more.
1. A method for producing a rubber composition comprising:
a mixing step that mixes an aqueous solution that includes at least one of oxycellulose fibers and cellulose nanofibers with rubber latex using an open roll to obtain a first mixture;
a drying step that dries the first mixture to obtain a second mixture; and
a dispersion step that tight-mills the second mixture using an open roll to obtain a rubber composition,
wherein the mixing step includes repeating the following steps (1) to (4) a plurality of times:
(1) mixing the aqueous solution and the rubber latex using the open roll to obtain a mixture;
(2) removing the mixture from the open roll when the viscosity of the mixture has increased;
(3) after step (2), reducing a roll distance of the open roll; and
(4) after step (3), supplying the mixture to the open roll again,
wherein the mixing step obtains the first mixture in which at least one of the oxycellulose fibers and the cellulose nanofibers enter rubber microparticles in the rubber latex by repeatedly performing the steps (1) to (4),
wherein the aqueous solution includes at least one of the oxycellulose fibers and the cellulose nanofibers in a ratio of 0.1 to 10 mass %, and
wherein the dispersion step tight-mills the second mixture that includes at least one of the oxycellulose fibers and the cellulose nanofibers in an amount of 0.1 to 60 parts by mass based on 100 parts by mass of rubber, using the open roll at a roll distance of 0 to 0.5 mm and a roll temperature of 0 to 50° C.
2. The method for producing a rubber composition as defined in claim 1 , wherein the oxycellulose fibers have an average fiber diameter of 10 to 30 micrometers, and the cellulose nanofibers have an average fiber diameter of 1 to 200 nm.
3. The method for producing a rubber composition as defined in claim 1 , further comprising: a coagulation step that is performed between the mixing step and the drying step, the coagulation step coagulating the rubber latex included in the first mixture.