Method for preparing lithium secondary battery and lithium secondary battery prepared therefrom
View Patent ↗The present disclosure provides a method for preparing a lithium secondary battery by bringing a first cell using a first cathode active material of formula (I) Li(Li x M y−y′ M′ y′ )O 2−z A z (I) wherein, x, y, y′, and z satisfy 0<x<0.5, 0.6<y<1.1, 0≤y′<0.2, and 0≤z<0.2, M is any one selected from the group consisting of Mn, Ni, Co, Fe, Cr, V, Cu, Zn, and Ti, M′ is any one selected from the group consisting of Al, Mg and B; and A is any one selected from the group consisting of F, S and N and a second cell using a second cathode active material being generally used into activation under different voltage conditions, and then electrically connecting the first cell and the second cell in the step of assembling unit cells; and a lithium secondary battery prepared from the method. According to the present disclosure, a lithium secondary battery can be prepared by bringing a first cell using a first cathode active material of formula (I) and a second cell using a second cathode active material being generally used into activation under different voltage conditions, and then electrically connecting the first cell and the second cell in the step of assembling unit cells, thereby achieving high capacity from the first cell and life performance improvement from the second cell in balance.
1. A method for preparing a lithium secondary battery, comprising:
(S1) bringing a first cell comprising a first cathode active material of formula (I) into activation under voltage conditions ranging from 4.3 V to 4.8V, and bringing a second cell comprising a second cathode active material into activation under voltage conditions of 4.3 V or less, wherein the activation voltages for the first cell and the second cell are different; and
(S2) after completing the activation of the first and second cells, electrically connecting the first cell and the second cell in parallel or series:
Li(Li x M y−y′ M′ y′ )O 2−z A z (I)
wherein, x, y, y′, and z satisfy 0<x<0.5, 0.6<y<1.1, 0≤y′<0.2, and 0≤z<0.2,
M is any one selected from the group consisting of Mn, Ni, Co, Fe, Cr, V, Cu, Zn, and Ti,
M′ is any one selected from the group consisting of Al, Mg and B; and
A is any one selected from the group consisting of F, S and N.
2. The method of claim 1 , wherein, the second cathode active material is at least one of of LiNiO 2 , LiCoO 2 , LiMn 2 O 4 , LiFePO 4 , LiNi x Co x−1 O 2 (1≤x≤2), LiNi 1−x−y Co x Mn y O 2 (0≤x≤0.5, 0≤y≤0.5), or a mixture thereof.
3. The method of claim 1 , wherein in the step (S1) further comprises removing gases in the first and second cells, under same or different conditions for each of the first cell and the second cell.
4. The method of claim 1 , wherein the step (S1) further comprises aging of the first and second cells under same or different conditions for each of the first cell and the second cell.
5. A lithium secondary battery prepared from the method of claim 1 .
6. The lithium secondary battery of claim 5 , which is operated at 4.3V or less.