Tempered and non-tempered glass coatings having similar optical characteristics
View Patent ↗Temperable and non-temperable coatings are provided which have similar optical characteristics. The non-temperable coating is placed on glass that is not to be tempered and provides certain optical characteristics. The temperable coating is placed on a glass substrate and the coated substrate is then tempered. After tempering, the coated tempered glass sheet and the coated non-tempered glass sheet have similar optical characteristics. Both coatings have a plurality of metal layers, with at least one of the metallic layers being a discontinuous layer with a primer layer over the discontinuous metal layer. For the non-temperable coating, the discontinuous metal layer has an effective thickness in the range of 1.5 nm to 1.7 nm. For the temperable coating, the discontinuous metal layer has an effective thickness in the range of 1.7 nm to 1.8 nm. The primer layer of the temperable coating is thinner than the primer layer of the non-temperable coating.
1. An architectural transparency, which is non-tempered, comprising:
a) a first ply, comprising:
an annealed glass substrate; and
a coating stack over at least a portion of the substrate, the coating stack comprising:
a first dielectric layer;
a first continuous metal layer over at least a portion of the first dielectric layer;
a first primer layer over the first continuous metal layer;
a second dielectric layer over at least a portion of the first primer layer;
a second discontinuous metal layer over at least a portion of the second dielectric layer;
a second primer layer over at least a portion of the second discontinuous metal layer, wherein the second primer layer comprises titania;
a third dielectric layer over at least a portion of the second primer layer;
a third continuous metal layer over at least a portion of the third dielectric layer;
a third primer layer over at least a portion of the third continuous metal layer; and
an outermost protective coating over at least a portion of the third primer layer, wherein the protective coating comprises titania having a thickness in the range of 4 nm to 6 nm;
b) a second, transparent or translucent ply;
c) a spacer frame spacing the first ply and the second ply apart, the first ply, the second ply, and the spacer frame defining a chamber; and
d) a gas within the chamber.
2. The architectural transparency of claim 1 , wherein the second discontinuous metal layer has an effective thickness in the range of 1 nm to 2 nm.
3. The architectural transparency of claim 2 , wherein the second discontinuous metal layer has an effective thickness in the range of 1.5 nm to 1.7 nm.
4. The architectural transparency of claim 2 , wherein the second primer layer has a thickness in the range of 3 nm to 3.5 nm.
5. The architectural transparency of claim 2 , wherein the protective coating has a thickness in the range of 4 nm to 5 nm.
6. The architectural transparency of claim 1 , wherein the second discontinuous metal layer comprises silver having an effective thickness in the range of 1.5 nm to 1.7 nm, wherein the second primer layer comprises titania having a thickness in the range of 3 nm to 3.5 nm, and wherein the protective coating comprises titania having a thickness in the range of 4 nm to 5 nm.
7. The architectural transparency of claim 1 , wherein the gas is argon or krypton.
8. The architectural transparency of claim 1 , wherein the coating stack of the first ply is on a side of the first ply facing the chamber.
9. An architectural transparency, which is non-tempered, comprising:
a) a first ply, comprising:
an annealed glass substrate; and
a coating stack over at least a portion of the substrate, the coating stack comprising:
a first dielectric layer;
a first continuous metal layer over at least a portion of the first dielectric layer;
a first primer layer over the first continuous metal layer;
a second dielectric layer over at least a portion of the first primer layer;
a second discontinuous metal layer over at least a portion of the second dielectric layer;
a second primer layer over at least a portion of the second discontinuous metal layer;
a third dielectric layer over at least a portion of the second primer layer;
a third continuous metal layer over at least a portion of the third dielectric layer;
a third primer layer over at least a portion of the third continuous metal layer; and
an outermost protective coating over at least a portion of the third primer layer, and
wherein the coating is a non-temperable coating,
wherein the second discontinuous metal layer has effective thickness in the range of 1.5 nm to 1.7 nm;
b) a second, transparent or translucent ply;
c) a spacer frame spacing the first ply and the second ply apart, the first ply, the second ply, and the spacer frame defining a chamber; and
d) a gas within the chamber.
10. The architectural transparency of claim 9 , wherein the second primer layer has a thickness in the range of 3 nm to 3.5 nm.
11. The architectural transparency of claim 9 , wherein protective coating has a thickness in the range of 4 nm to 5 nm.
12. The architectural transparency of claim 9 , wherein the second discontinuous metal layer comprises silver, the second primer layer comprises titania having a thickness in the range of 3 nm to 3.5 nm, and the protective coating comprises titania having a thickness in the range of 4 nm to 5 nm.
13. An architectural transparency, which is non-tempered, comprising:
a) a first ply, comprising:
an annealed glass substrate; and
a coating stack over at least a portion of the substrate, the coating stack comprising:
a first dielectric layer comprising an oxide or alloy oxide including zinc;
a first continuous metal layer comprising silver over at least a portion of the first dielectric layer;
a first primer layer comprising titanium over the first continuous metal layer;
a second dielectric layer comprising an oxide or alloy oxide including zinc over at least a portion of the first primer layer;
a second discontinuous metal layer comprising silver having an effective thickness in the range of 1 nm to 3 nm over at least a portion of the second dielectric layer;
a second primer layer comprising titanium over at least a portion of the second discontinuous metal layer, wherein the second primer layer comprises titania;
a third dielectric layer comprising an oxide or alloy oxide including zinc over at least a portion of the second primer layer;
a third continuous metal layer comprising silver over at least a portion of the third dielectric layer;
a third primer layer comprising titanium over at least a portion of the third continuous metal layer;
a fourth dielectric layer comprising an oxide or alloy oxide including zinc over at least a portion of the third primer layer; and
an outermost protective coating over at least a portion of the third primer layer, wherein the protective coating comprises titania having a thickness in the range of 4 nm to 6 nm;
b) a second, transparent or translucent ply;
c) a spacer frame spacing the first ply and the second ply apart, the first ply, the second ply, and the spacer frame defining a chamber; and
d) a gas within the chamber.