Titanium alloy
View Patent ↗A titanium base alloy powder is formed by subsurface reduction of a chloride vapor with a molten alkali metal or molten alkaline earth metal to form reaction products comprising pre-alloy particles and a salt of the alkali metal or the alkaline earth metal. A majority of the pre-alloy particles have a composition of at least 50% by weight of titanium, about 5.38% to 6.95% by weight of aluminum, and about 3% to 5% by weight of vanadium. The pre-alloy particles are recovered from the reaction products to produce a titanium base alloy powder containing less than about 200 ppm alkali or alkaline earth metal.
1. A method of forming a titanium base alloy powder, the method comprising:
subsurface reduction of a chloride vapor with a molten alkali metal or molten alkaline earth metal to form reaction products comprising pre-alloy particles and a salt of the alkali metal or the alkaline earth metal, a majority of the pre-alloy particles having a composition of at least 50% by weight of titanium, 5.38% or more by weight of aluminum, and 3.45% or more by weight of vanadium, wherein the total amount of aluminum and vanadium is less than about 20% by weight; and
recovering the pre-alloy particles from the reaction products to produce a titanium base alloy powder containing less than about 200 ppm alkali or alkaline earth metal and a surface area as determined by BET analysis of at least about 3 square meters per gram after distillation of the powder at temperatures between about 500° C. and about 575° C. for about 8 to about 12 hours.
2. The method of claim 1 , wherein the titanium base alloy powder meets ASTM B265 grade 5 chemical specifications.
3. The method of claim 1 , wherein the alkali metal is Na, K or mixtures thereof and the alkaline earth metal is Mg, Ca, Ba or mixtures thereof.
4. The method of claim 1 , wherein the titanium alloy powder is in agglomerates having an average mean diameter as measured by sieve analysis greater than about 50 microns.
5. The method of claim 1 , wherein the titanium alloy powder contains less than about 100 ppm sodium, magnesium, calcium.
6. The method of claim 1 , further comprising forming the titanium alloy powder into a sintered product.
7. A method of forming a titanium base alloy powder, the method comprising:
subsurface reduction of a chloride vapor with a molten alkali metal or molten alkaline earth metal to form reaction products comprising pre-alloy particles and a salt of the alkali metal or the alkaline earth metal, a majority of the pre-alloy particles having a composition of at least 50% by weight of titanium, about 5.38% to 6.95% by weight of aluminum, and about 3% to 5% by weight of vanadium; and
recovering the pre-alloy particles from the reaction products to produce a titanium base alloy powder containing less than about 200 ppm alkali or alkaline earth metal and a surface area as determined by BET analysis of at least about 3 square meters per gram after distillation of the powder at temperatures between about 500° C. and about 575° C. for about 8 to about 12 hours.
8. The method of claim 7 , wherein the titanium base alloy powder meets ASTM B265 grade 5 chemical specifications.
9. The method of claim 7 , wherein the alkali metal is Na, K or mixtures thereof and the alkaline earth metal is Mg, Ca, Ba or mixtures thereof.
10. The method of claim 7 , wherein the titanium alloy powder is in agglomerates having an average mean diameter as measured by sieve analysis greater than about 50 microns.
11. The method of claim 7 , wherein the titanium alloy powder contains less than about 100 ppm sodium, magnesium, calcium.
12. The method of claim 7 , further comprising forming the titanium alloy powder into a sintered product.