Glass and manufacturing method of glass plate
View Patent ↗To provide glass having a favorable color tone, and its production process. Glass comprising, as represented by mass percentage based on oxides, at least 60% and at most 75% of SiO 2 , at least 8% and at most 20% of Na 2 O, at least 4.5% of MgO, at least 1% and at most 10% of CaO, and at least 0.01% and at most 0.5% of Er 2 O 3 .
1. Glass comprising, as represented by mass percentage based on oxides:
SiO 2 : at least 60% and at most 75%,
Na 2 O: at least 8% and at most 20%,
MgO: at least 4.5%,
CaO: at least 1% and at most 10%, and
Er 2 O 3 : at least 0.01% and at most 0.5%,
wherein a Q value determined by the formula (MgO content/CaO content)×(CaO content+Na 2 O content−Al 2 O 3 content) as represented by mass percentage based on oxides, is at least 15.
2. The glass according to claim 1 , wherein the glass further comprises, as represented by mass percentage based on oxides, at least 0.5% and at most 15% of Al 2 O 3 .
3. The glass according to claim 1 , wherein the glass further comprises, as represented by mass percentage based on oxides, at least 0% and at most 0.1% of total iron as calculated as Fe 2 O 3 .
4. The glass according to claim 1 , wherein the glass comprises, as represented by mass percentage based on oxides, at most 8% of CaO when the SiO 2 content is at least 70%, or above 8% of CaO when the SiO 2 content is less than 70%.
5. The glass according to claim 1 , wherein the glass comprises, as represented by mass percentage based on oxides, at least 4.5% and at most 15% of MgO.
6. The glass according to claim 1 , wherein a ratio (MgO/CaO) of the MgO content to the CaO content is at least 0.8 and at most 25.
7. The glass according to claim 1 , wherein the glass further comprises SO 3 .
8. The glass according to claim 1 , wherein the glass further comprises TiO 2 .
9. The glass according to claim 1 , wherein the glass further comprises SnO 2 .
10. A manufacturing method of a glass plate according to claim 1 , wherein the manufacturing method comprises:
preparing glass raw materials so that a glass plate after forming comprises, as represented by mass percentage based on oxides, at least 60% and at most 75% of SiO 2 , at least 8% and at most 20% of Na 2 O, at least 4.5% of MgO, at least 1% and at most 10% of CaO, and at least 0.01% and at most 0.5% of Er 2 O 3 ;
melting the glass raw materials; and
forming the molten glass materials by a float process, a downdraw process or a rollout process,
wherein a Q value determined by the formula (MgO content/CaO content)×(CaO content+Na 2 O content−Al 2 O 3 content) as represented by mass percentage based on oxides, is at least 15.
11. The glass according to claim 1 , wherein the glass has a Redox of less than 33.0%.
12. The glass according to claim 1 , wherein the glass has a Redox of from 11.2 to 33.0%.
13. The glass according to claim 1 , wherein a Q value determined by the formula (MgO content/CaO content)×(CaO content+Na 2 O content−Al 2 O 3 content) as represented by mass percentage based on oxides, is at most 150.