Golf ball layers produced using crosslinked highly-neutralized polymer materials
View Patent ↗The invention relates to golf balls having at least one layer formed from a highly-neutralized polymer material that has been crosslinked. In particular, the compositions of the invention include a highly-neutralized polymer, at least one crosslinking initiator, and at least one coagent. The invention also relates to methods of making the compositions and golf ball constructions that incorporate the compositions of the invention in at least a portion thereof.
1. A golf ball comprising:
a cover layer formed from a crosslinked composition consisting essentially of:
a thermoplastic highly-neutralized polymer material comprising:
an acid polymer comprising ethylene, a C 3-8 α, β-ethylenically unsaturated carboxylic acid, and a softening monomer;
an organic acid or salt thereof; and
a cation source present in an amount sufficient to neutralize at least 80% of all acid groups;
at least one crosslinking initiator and at least one liquid coagent, wherein the at least one crosslinking initiator comprises a peroxide, a carbon-carbon initiator, or combinations thereof; and
a core.
2. The golf ball of claim 1 , wherein the C 3-8 α, β-ethylenically unsaturated carboxylic acid is selected from the group consisting of acrylic acid, methacrylic acid, ethacrylic acid, maleic acid, crotonic acid, fumaric acid, and itaconic acid.
3. The golf ball of claim 1 , wherein the cation source is present in an amount sufficient to neutralize at least 90% of all acid groups.
4. The golf ball of claim 3 , wherein the cation source is present in an amount sufficient to neutralize 100% of all acid groups.
5. The golf ball of claim 1 , wherein the acid polymer is selected from the group consisting of ethylene/(meth) acrylic acid/n-butyl acrylate, ethylene/(meth) acrylic acid/methyl acrylate, and ethylene/(meth) acrylic acid/ethyl acrylate.
6. The golf ball of claim 1 , wherein the carbon-carbon initiator has the following general structure:
where each of R 3 , R 4 , R 5 , and R 6 independently may be hydrogen, substituted and unsubstituted straight, branched, and cyclic, hydrocarbons (including aromatic hydrocarbons), and each of R x and R y independently may be substituted and unsubstituted aromatic hydrocarbons.
7. The golf ball of claim 1 , wherein the at least one crosslinking initiator is a carbon-carbon initiator.
8. The golf ball of claim 1 , wherein the at least one liquid coagent is selected from the group consisting of trimethylolpropane trimethacrylate, acrylate-terminated liquid polybutadiene, and combinations thereof.
9. A golf ball comprising:
a cover formed from a crosslinked composition consisting essentially of:
a thermoplastic highly-neutralized polymer material comprising:
an acid polymer comprising ethylene, a C 3-8 α, β-ethylenically unsaturated carboxylic acid, and a softening monomer;
an organic acid or salt thereof; and
a cation source present in an amount sufficient to neutralize at least 90% of all acid groups; and
at least one free radical initiator comprising a peroxide, a carbon-carbon initiator, persulfate, azo compound, benzophenone, hydrazide, or combinations thereof;
at least one liquid coagent, wherein the liquid coagent is selected from the group consisting of trimethylolpropane trimethacrylate, acrylate-terminated liquid polybutadiene, and combinations thereof;
and a melt flow modifier; and
a core.
10. The golf ball of claim 9 , wherein the core has a hardness of about 50 Shore C to about 85 Shore C.
11. The golf ball of claim 9 , wherein the peroxide is selected from the group consisting of dicumyl peroxide; n-butyl-4,4-di(t-butylperoxy) valerate; 1,1-di(t-butylperoxy)3,3,5-trimethylcyclohexane; 2,5-dimethyl-2,5-di(t-butylperoxy) hexane; di-t-butyl peroxide; di-t-amyl peroxide; t-butyl peroxide; t-butyl cumyl peroxide; 2,5-dimethyl-2,5-di(t-butylperoxy)hexyne-3; di(2-t-butyl-peroxyisopropyl)benzene; dilauroyl peroxide; dibenzoyl peroxide; t-butyl hydroperoxide; lauryl peroxide; and benzoyl peroxide.
12. The golf ball of claim 9 , wherein the softening monomer is an alkyl acrylate and methacrylate, where the alkyl groups have from 1 to 8 carbon atoms.
13. The golf ball of claim 9 , wherein the melt flow modifier is selected from the group consisting of organic acids and salts thereof, polyamides, polyesters, polyacrylates, polyurethanes, polyethers, polyureas, polyhydric alcohols, non-fatty acids, and combinations thereof.
14. The golf ball of claim 9 , wherein the at least one free radical initiator is a carbon-carbon initiator.
15. The golf ball of claim 14 , wherein the carbon-carbon initiator has the following general structure:
where each of R 3 , R 4 , R 5 , and R 6 independently may be hydrogen, substituted and unsubstituted straight, branched, and cyclic, hydrocarbons (including aromatic hydrocarbons), and each of R x and R y independently may be substituted and unsubstituted aromatic hydrocarbons.