Use of oil-soluble surfactants as breaker enhancers for VES-gelled fluids
View Patent ↗Fluids viscosified with viscoelastic surfactants (VESs) may have their viscosities reduced (gels broken) by the direct or indirect action of an internal breaker composition that contains at least one mineral oil, at least one polyalphaolefin oil, at least one saturated fatty acid and/or at least one unsaturated fatty acid. The internal breaker may initially be dispersed oil droplets in an internal, discontinuous phase of the fluid. In one non-limiting embodiment, the internal breaker, e.g. mineral oil, is added to the fluid after it has been substantially gelled. An oil-soluble surfactant is present to enhance or accelerate the reduction of viscosity of the gelled aqueous fluid.
1. An aqueous fluid comprising:
water;
at least one viscoelastic surfactant (VES) in an amount effective to increase the viscosity of the aqueous fluid;
at least one internal breaker in an amount effective to reduce the viscosity of the gelled aqueous fluid, where the internal breaker is selected from the group consisting of mineral oils, hydrogenated polyalphaolefin oils, saturated fatty acids, and unsaturated fatty acids; and
an oil-soluble surfactant breaker enhancer in an amount effective to accelerate reduction of viscosity of the gelled aqueous fluid, where the oil-soluble surfactant breaker enhancer is selected from the group consisting of sorbitan fatty acid esters, saponified hard oils, long chain alcohols, long chain fatty acid alcohols, long chain fatty amines, long chain sulfates, long chain sulfonates, phosopholipids, and lignins,
where the aqueous fluid does not include any other viscosity reducing agent.
2. The aqueous fluid of claim 1 where
when the internal breaker is a mineral oil, it is present in an amount from about 5 to about 18,000 ppm based on the total fluid,
when the internal breaker is an unsaturated fatty acid it is present in an amount from about 100 to about 20,000 ppm based on the total fluid, and
the breaker enhancer is present in an amount from about 0.001 to about 10 wt % based on the total fluid.
3. The aqueous fluid of claim 1 where the internal breaker is a mineral oil and is at least about 99 wt % paraffin.
4. The aqueous fluid of claim 1 where the internal breaker is a mineral oil and has a distillation temperature in the range from about 160 to about 550° C., and a kinematic viscosity at 40° C. of from about 1 to about 250 cSt.
5. The aqueous fluid of claim 1 where the internal breaker is selected from the group consisting of: polyenoic acids and monoenoic acids.
6. The aqueous fluid of claim 5 where the polyenoic acid is selected from the group consisting of linoleic acid, omega-3 fatty acids, omega-6 fatty acids, stearidonic acid, eleostearic acid, eicosadienoic acid, eicosatrienoic acid, arachidonic acid or eicosatetraenoic acid, eicosapentaenoic acid, docosapentaenoic acid, docosahexaenoic acid, cis-linoleic acid, cis-linolenic acid, gamma-linolenic acid, and conjugated polyenes.
7. The aqueous fluid of claim 5 where the monoenoic acid is selected from the group consisting of obtusilic acid, caproleic acid, lauroleic acid, linderic acid, myristoleic acid, physeteric acid, tsuzuic acid, palm itoleic acid, petroselinic acid, oleic acid, vaccenic acid, gadoleic acid, gondoic acid, cetoleic acid, nervonic acid, erucic acid, elaidic acid, and t-vaccenic acid.
8. The aqueous fluid of claim 1 where the internal breaker is present in an oil-soluble internal phase of the aqueous fluid.
9. The aqueous fluid of claim 1 where the oil-soluble surfactant breaker enhancer is selected from the group consisting of sorbitan fatty acid esters, saponified hard oils, long chain alcohols, long chain fatty acid alcohols, long chain fatty amines, long chain sulfates, long chain sulfonates, phospholipids, and lignins.
10. An aqueous fluid comprising:
water;
at least one viscoelastic surfactant (VES) in an amount effective to increase the viscosity of the aqueous fluid;
at least one internal breaker in an amount effective to reduce the viscosity of the gelled aqueous fluid, where the internal breaker is selected from the group consisting of mineral oils, hydrogenated polyalphaolefin oils, saturated fatty acids, and unsaturated fatty acids; and
from about 0.001 to about 10 wt % based on the total fluid of an oil-soluble surfactant breaker enhancer, where the oil-soluble surfactant breaker enhancer is selected from the group consisting of sorbitan fatty acid esters, saponified hard oils, long chain alcohols, long chain fatty acid alcohols, long chain fatty amines, long chain sulfates, long chain sulfonates, phosopholipids, and lignins;
where the aqueous fluid does not include any other viscosity reducing agent.
11. The aqueous fluid of claim 10 where the internal breaker is a mineral oil and is at least about 99 wt % paraffin.
12. The aqueous fluid of claim 10 where the internal breaker is a mineral oil and has a distillation temperature in the range from about 160 to about 550° C., and a kinematic viscosity at 40° C. of from about 1 to about 250 cSt.
13. The aqueous fluid of claim 10 where the internal breaker is selected from the group consisting of: polyenoic acids and monoenoic acids.
14. The aqueous fluid of claim 13 where the polyenoic acid is selected from the group consisting of linoleic acid, omega-3 fatty acids, omega-6 fatty acids, stearidonic acid, eleostearic acid, eicosadienoic acid, eicosatrienoic acid, arachidonic acid or eicosatetraenoic acid, eicosapentaenoic acid, docosapentaenoic acid, docosahexaenoic acid, cis-linoleic acid, cis-linolenic acid, gamma-linolenic acid, and conjugated polyenes.
15. The aqueous fluid of claim 13 where the monoenoic acid is selected from the group consisting of obtusilic acid, caproleic acid, lauroleic acid, linderic acid, myristoleic acid, physeteric acid, tsuzuic acid, palmitoleic acid, petroselinic acid, oleic acid, vaccenic acid, gadoleic acid, gondoic acid, cetoleic acid, nervonic acid, erucic acid, elaidic acid, and t-vaccenic acid.
16. The aqueous fluid of claim 10 where the internal breaker is present in an oil-soluble internal phase of the aqueous fluid.
17. An aqueous fluid comprising:
water;
from about 5 to about 18,000 ppm based on the total fluid of at least one viscoelastic surfactant (VES) in an amount effective to increase the viscosity of the aqueous fluid;
from about 100 to about 20,000 ppm based on the total fluid of at least one internal breaker in an amount effective to reduce the viscosity of the gelled aqueous fluid, where the internal breaker is selected from the group consisting of mineral oils, hydrogenated polyalphaolefin oils, saturated fatty acids, and unsaturated fatty acids, where the internal breaker is present in an oil-soluble internal phase of the aqueous fluid; and
from about 0.001 to about 10 wt % based on the total fluid of an oil-soluble surfactant breaker enhancer, where the oil-soluble surfactant breaker enhancer is selected from the group consisting of sorbitan fatty acid esters, saponified hard oils, long chain alcohols, long chain fatty acid alcohols, long chain fatty amines, long chain sulfates, long chain sulfonates, phosopholipids, and lignins;
where the aqueous fluid does not include any other viscosity reducing agent.