Ceramic electrode including a perovskite or spinel structure for an ignition device and method of manufacturing
View Patent ↗A spark plug and method of construction is provided. The spark plug has a generally annular ceramic insulator extending between a terminal end and a nose end. A conductive shell surrounds at least a portion of the ceramic insulator and a ground electrode having a ground electrode sparking surface is operatively attached to the shell. An elongate center electrode has a body extending between opposite ends. The body of the center electrode is formed of a compacted and sintered conductive or semi-conductive ceramic material. The ceramic material of the body comprises at least one oxide. For example, the body of the center electrode can be formed of a perovskite structure or a spinel structure.
1. A spark plug comprising:
an insulator formed of a first ceramic material extending along a longitudinal axis and presenting a central passage between a terminal end and a nose end;
a center electrode disposed in said central passage of said insulator;
said center electrode including an elongate body formed of a second ceramic material;
said second ceramic material comprising at least one perovskite structure having the general formulation ABO 3 , wherein component A includes at least one of La, Ca, Ba, Sr, Y, and Gd; component B includes at least one of Sc, Ti, Zr, Hf, Nb, Ta, Mo, W, Re, V, Cr, Mn, Tc, Fe, Ru, Co, Rh, Ga, and Ni; and optionally at least a portion of component A and/or at least a portion of component B of the perovskite structure is replaced with component C and/or component D, wherein component C is different from components A and B and includes at least one of La, Ca, Ba, Sr, Y, and Gd; and component D is different from components A and B and includes at least one of Sc, Ti, Zr, Hf, Nb, Ta, Mo, W, Re, V, Cr, Mn, Tc, Fe, Ru, Co, Rh, Ga, and Ni.
2. The spark plug of claim 1 , wherein at least 50 wt. % of the elongate body consists of the perovskite structure.
3. The spark plug of claim 1 , wherein at least a portion of component A and/or at least a portion of component B of the perovskite structure is replaced with component C and/or component D.
4. A spark plug comprising:
an insulator formed of a first ceramic material extending along a longitudinal axis and presenting a central passage between a terminal end and a nose end;
a center electrode disposed in said central passage of said insulator;
said center electrode including an elongate body formed of a second ceramic material; and
said second ceramic material comprising at least one of LaCrO 3 , LaMnO 3 , LaFeO 3 , LaGaO 3 , and LaCoO 3 .
5. A spark plug comprising:
an insulator formed of a first ceramic material extending along a longitudinal axis and presenting a central passage between a terminal end and a nose end;
a center electrode disposed in said central passage of said insulator;
said center electrode including an elongate body formed of a second ceramic material;
said second ceramic material comprising at least one perovskite structure having one of the following formulations: (A x C 1−x )BO 3 , A(B y D 1−y )O 3 , or (A x B 1−x )(C y D 1−y )O 3 ; wherein component A includes at least one of La, Ca, Ba, Sr, Y, and Gd; component B includes at least one of Sc, Ti, Zr, Hf, Nb, Ta, Mo, W, Re, V, Cr, Mn, Tc, Fe, Ru, Co, Rh, Ga, and Ni; x is between 0 and 0.5; and y is between 0 and 0.5.
6. The spark plug of claim 5 , wherein the at least one perovskite structure includes La 1−x Sr x MnO 3 .
7. A spark plug comprising:
an insulator formed of a first ceramic material extending along a longitudinal axis and presenting a central passage between a terminal end and a nose end;
a center electrode disposed in said central passage of said insulator;
said center electrode including an elongate body formed of a second ceramic material;
said second ceramic material comprising at least one perovskite structure having the general formulation M x N 1−y O 3−z , wherein component M comprises component A and at least one other metallic element; component A includes at least one of La, Ca, Ba, Sr, Y, and Gd; component N comprises component B and at least one other metallic element; component B includes at least one of Sc, Ti, Zr, Hf, Nb, Ta, Mo, W, Re, V, Cr, Mn, Tc, Fe, Ru, Co, Rh, Ga, and Ni; x ranges from 0.9 to 1.1; y ranges from 0.9 to 1.1; and z ranges from −0.2 to 0.2.
8. The spark plug of claim 7 , wherein at least 50 wt. % of the elongate body consists of the perovskite structure.
9. The spark plug of claim 7 , wherein the at least one other metallic element of component M includes at least one of La, Ca, Ba, Sr, Y, Gd, Sc, Ti, Zr, Hf, Nb, Ta, Mo, W, Re, V, Cr, Mn, Tc, Fe, Ru, Co, Rh, Ni, Cu, Zn, Ag, Ga, Al, and Si; and the at least one other metallic element of component N includes at least one of La, Ca, Ba, Sr, Y, Gd, Sc, Ti, Zr, Hf, Nb, Ta, Mo, W, Re, V, Cr, Mn, Tc, Fe, Ru, Co, Rh, Ni, Cu, Zn, Ag, Ga, Al, and Si.
10. The spark plug of claim 9 , wherein the at least one other metallic element of component M has a valence charge different from the valence charge of component A; and the at least one other metallic element of component N has a valence charge different from the valence charge of component B.
11. A spark plug comprising:
an insulator formed of a first ceramic material extending along a longitudinal axis and presenting a central passage between a terminal end and a nose end;
a center electrode disposed in said central passage of said insulator;
said center electrode including an elongate body formed of a second ceramic material; and
said second ceramic material comprising at least one spinel structure.
12. The spark plug of claim 11 , wherein at least 50 wt. % of the elongate body consists of the spinel structure.
13. The spark plug of claim 11 , wherein the spinel structure is nickel ferrite having the formulation Ni 1−x Fe 2+x O 4 or Ni 1+x Fe 2−x O 4 ; and x ranges from 0 to 0.5.
14. The spark plug of claim 13 , wherein the nickel ferrite has the formulation NiFe 2 O 4 .
15. The spark plug of claim 11 , wherein the spinel structure has the general formulation AB 2 O 4 , wherein component A includes at least one of Li, Co, Mg, Zn, Ni, Fe, Cd, Mn, and Cu; component B includes at least one of Al, Cr, and Fe; and optionally at least a portion of component A and/or at least a portion of component B is replaced with component C and/or component D; wherein component C is different from component A and B and includes at least one of Li, Co, Mg, Zn, Ni, Fe, Cd, Mn, Cu, Mo, W, Cr and V; and component D is different from component A and B and includes at least one of Al, Cr, Fe, Co, Ga and Mo.
16. The spark plug of claim 15 , wherein the spinel structure has the general formulation M x N 2−y O 4−z , wherein component M comprises component A and at least one other metallic element; component N comprises component B and at least one other metallic element; x ranges from −0.1 to 0.1; y ranges from −0.1 to 0.1; and z ranges from −0.2 to 0.2.
17. The spark plug of claim 16 , wherein the at least one other metallic element of M is selected from the following group: Ge, V, Te, Ti, Sb, Nb, Ta, W, Sn, Hf, Zr, Sc, Bi, and In.
18. The spark plug of claim 16 , wherein the at least one other metallic element of N is selected from the following group: Ge, V, Te, Ti, Sb, Nb, Ta, W, Sn, Hf, Zr, Sc, Bi, and In.
19. A method of manufacturing a spark plug, comprising the steps of:
compacting a first ceramic material to form an insulator having a central passage extending between a terminal end and a nose end;
compacting a second ceramic material to form an elongate center electrode, wherein the second ceramic material comprises at least one of a perovskite structure, a spinel structure, and a precursor material that forms a perovskite or spinel structure upon sintering; and
sintering the compacted ceramic materials of the insulator and the center electrode.
20. The method of claim 19 , further including the steps of: providing a conductive shell and a ground electrode; attaching the ground electrode to the shell; and disposing the insulator and the center electrode in the shell.