Yellow-green to yellow-emitting phosphors based on halogenated-aluminates
View Patent ↗Disclosed herein are yellow-green and yellow-emitting aluminate based phosphors for use in white LEDs, general lighting, and LED and backlighting displays. In one embodiment of the present invention, the cerium-activated, yellow-green to yellow-emitting aluminate phosphor comprises the rare earth lutetium, at least one alkaline earth metal, aluminum, oxygen, at least one halogen, and at least one rare earth element other than lutetium, wherein the phosphor is configured to absorb excitation radiation having a wavelength ranging from about 380 nm to about 480 nm, and to emit light having a peak emission wavelength ranging from about 550 nm to about 600 nm.
1. A cerium-activated, yellow-green to yellow-emitting aluminate phosphor comprising the rare earth lutetium, at least one alkaline earth metal, aluminum, oxygen, at least one halogen, and at least one rare earth element other than lutetium, wherein the phosphor is configured to absorb excitation radiation having a wavelength ranging from about 380 nm to about 480 nm, and to emit light having a peak emission wavelength ranging from about 550 nm to about 600 nm, and wherein the stoichiometric ratio of alkaline earth metal to halogen is less than 2 and greater than or equal to 1.
2. The cerium-activated, yellow-green to yellow-emitting aluminate phosphor of claim 1 , wherein the excitation radiation has a wavelength ranging from about 420 nm to about 480 nm.
3. The cerium-activated yellow-green to yellow-emitting aluminate phosphor of claim 1 , further including any of the rare earth elements scandium (Sc), gadolinium (Gd), lanthanum (Lm), and terbium (Tb).
4. The cerium-activated, yellow-green to yellow-emitting aluminate phosphor of claim 1 , wherein the stoichiometric ratio of alkaline earth metal to halogen is less than 2 and greater than or equal to 1.5.
5. The cerium-activated, yellow-green to yellow-emitting aluminate phosphor of claim 1 , wherein the stoichiometric ratio of alkaline earth metal to halogen is less than 2 and greater than or equal to 1.8.
6. The cerium-activated, yellow-green to yellow-emitting aluminate phosphor of claim 1 , wherein the stoichiometric ratio of alkaline earth metal to halogen is less than 2 and greater than or equal to 1.9.
7. A yellow-green to yellow-emitting halogenated aluminate phosphor having the formula:
(Lu 1-x-y A x Ce y ) 3 B z Al 5 O 12 C w ; where
A is at least one of Sc, La, Gd, and Tb;
B is at least one of Mg, Sr, Ca, and Ba;
C is at least one of F, C, Br, and I;
0≦x≦0.5;
0.001≦y≦0.2;
0.001≦z≦0.5 and
2z>w≧z.
8. The yellow-green to yellow-emitting halogenated aluminate phosphor of claim 7 , wherein A is Gd.
9. The yellow-green to yellow-emitting halogenated aluminate phosphor of claim 7 , wherein B is Ba or Sr.
10. The yellow-green to yellow-emitting halogenated aluminate phosphor of claim 7 , wherein C is F.
11. The yellow-green to yellow-emitting halogenated aluminate phosphor of claim 7 , wherein 2z>w≧1.5z.
12. The yellow-green to yellow-emitting halogenated aluminate phosphor of claim 7 , wherein 2z>w≧1.8z.
13. The yellow-green to yellow-emitting halogenated aluminate phosphor of claim 7 , wherein 2z>w≧1.9z.
14. The yellow-green to yellow-emitting halogenated aluminate phosphor of claim 7 , wherein A is Gd, 0.07≦x≦0.33, B is Ba and C is F.
15. The yellow-green to yellow-emitting halogenated aluminate phosphor of claim 7 , wherein A is Gd, 0.03≦x≦0.13, B is Sr and C is F.
16. A white LED comprising:
a radiation source for configured to provide radiation having a wavelength greater than about 280 nm;
a cerium-activated, yellow-green to yellow-emitting aluminate phosphor comprising the rare earth lutetium, at least one alkaline earth metal, aluminum, oxygen, at least one halogen, and at least one rare earth element other than lutetium, wherein the phosphor is configured to absorb excitation radiation having a wavelength ranging from about 380 nm to about 480 nm, and to emit light having a peak emission wavelength ranging from about 550 nm to about 600 nm, and wherein the stoichiometric ratio of alkaline earth metal to halogen is less than 2 and greater than or equal to 1; and
at least one of a red-emitting phosphor or a yellow-emitting phosphor.
17. The white LED of claim 16 , wherein the red-emitting phosphor is a nitride.
18. The white LED of claim 17 , wherein the nitride has the formula (Ca,Sr)AlSiN 3 :Eu 2+ .
19. The white LED of claim 16 , wherein the yellow-emitting phosphor is a silicate.
20. The white LED of claim 19 , wherein the silicate has the formula (Sr,Ba) 2 SiO 4 :Eu 2+ .
21. The white LED of claim 16 , wherein the stoichiometric ratio of alkaline earth metal to halogen is less than 2 and greater than or equal to 1.5.
22. The white LED of claim 16 , wherein the stoichiometric ratio of alkaline earth metal to halogen is less than 2 and greater than or equal to 1.8.
23. The white LED of claim 16 , wherein the stoichiometric ratio of alkaline earth metal to halogen is less than 2 and greater than or equal to 1.9.