Depressants for use in separation processes
View Patent ↗Methods for removing particulates from an aqueous suspension are provided. In at least one specific embodiment, the method can include mixing a polyamidoamine-epihalohydrin resin with an aqueous suspension comprising one or more first particulates to produce a treated mixture. An amount of the polyamidoamine-epihalohydrin resin in the treated mixture can be less than 500 g/tonne of the one or more first particulates. The method can also include recovering from the treated mixture a purified water having a reduced concentration of the one or more first particulates relative to the aqueous suspension, a purified first particulate product having a reduced concentration of water relative to the aqueous suspension, or both.
1. A method for separating particulates from an aqueous suspension, comprising:
mixing a polyamidoamine-epihalohydrin resin with an aqueous suspension comprising one or more first particulates to produce a treated mixture, wherein an amount of the polyamidoamine-epihalohydrin resin in the treated mixture is less than 500 g/tonne of the one or more first particulates, and wherein the treated mixture comprises less than 0.5 wt % of any polysaccharide, based on a weight of the polyamidoamine-epihalohydrin resin in the treated mixture; and
recovering from the treated mixture a purified water having a reduced concentration of the one or more first particulates relative to the aqueous suspension, a purified first particulate product having a reduced concentration of water relative to the aqueous suspension, or both.
2. The method of claim 1 , wherein the one or more first particulates comprise clay, a clay mineral, sand, a glass sand containing quartz, a silicate, quartz, a carbonate, a metal, a metal oxide, or any mixture thereof.
3. The method of claim 1 , wherein the aqueous suspension further comprises one or more second particulates, wherein the one or more second particulates comprise antimony, barium, bauxite, bismuth, borate, borax, calcium, chromium, coal, cobalt, copper, feldspar, gold, graphite, gypsum, iron, lead, magnesium, manganese, molybdenum, nickel, palladium, phosphates, phosphorus, platinum, potash, scandium, yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, silver, magnesium silicate, sulfates, titanium, tungsten, uranium, zinc, oxides thereof, carbonates thereof, hydroxides thereof, or any mixture thereof, wherein the one or more first particulates are different than the one or more second particulates, and wherein the method further comprises recovering a purified second particulate product having a reduced concentration of water and the one or more first particulates relative to the aqueous suspension.
4. The method of claim 1 , wherein the aqueous suspension further comprises one or more second particulates, wherein the one or more first particulates are different than the one or more second particulates, wherein the one or more second particulates comprise a phosphorus ore, wherein the phosphorus ore comprises triphylite, monazite, hinsdalite, pyromorphite, vanadinite, erythrite, amblygonite, lazulite, wavellite, turquoise, autunite, carnotite, phosphophyllite, struvite, one or more apatites, one or more mitridatites, or any mixture thereof, and wherein the method further comprises recovering a purified second particulate product comprising the phosphorus ore having a reduced concentration of water and the one or more first particulates relative to the aqueous suspension.
5. The method of claim 1 , wherein the one or more first particulates comprise sand, clay, or a mixture thereof.
6. The method of claim 1 , wherein the amount of the polyamidoamine-epihalohydrin resin in the treated mixture is about 0.001 g/tonne of the one or more first particulates to less than 300 g/tonne of the one or more first particulates.
7. The method of claim 1 , wherein the polyamidoamine-epihalohydrin resin comprises a reaction product of about 0.56 moles to about 1.35 moles of a polyamidoamine and about 0.75 moles to about 1.8 moles of an epihalohydrin, and wherein the polyamidoamine is a reaction product of about 0.9 moles to about 1.1 moles of a polyamine and about 1.1 moles to about 0.9 moles of a dicarboxylic acid.
8. The method of claim 7 , wherein the epihalohydrin comprises epichlorohydrin, wherein the polyamine comprises diethylenetriamine, triethylenetetramine, tripropylenetetramine, tetraethylenepentamine, pentaethylenehexamine, or any mixture thereof, and wherein the dicarboxylic acid comprises malonic acid, succinic acid, glutaric acid, adipic acid, suberic acid, sebacic acid, or any mixture thereof.
9. The method of claim 1 , wherein the polyamidoamine-epihalohydrin resin has a weight average molecular weight of about 500,000 to about 1,300,000.
10. The method of claim 1 , wherein the polyamidoamine-epihalohydrin resin has a ratio of azetidinium ions to amide residues of about0.5 to about 0.9.
11. The method of claim 1 , wherein the polyamidoamine-epihalohydrin resin has a charge density of about 1.5 mEq/gram of solids to about 3 mEq/gram of solids.
12. The method of claim 1 , wherein:
the polyamidoamine-epihalohydrin resin comprises a reaction product of about 0.56 moles to about 1.35 moles of a polyamidoamine and about 0.75 moles to about 1.8 moles of an epihalohydrin,
the polyamidoamine comprises a reaction product of about 0.9 moles to about 1.1 moles of a polyamine and about 1.1 moles to about 0.9 moles of a dicarboxylic acid,
the epihalohydrin comprises epichlorohydrin,
the polyamine comprises diethylenetriamine, triethylenetetramine, tripropylenetetramine, tetraethylenepentamine, pentaethylenehexamine, or any mixture thereof,
the dicarboxylic acid comprises malonic acid, succinic acid, glutaric acid, adipic acid, suberic acid, sebacic acid, or any mixture thereof,
the polyamidoamine-epihalohydrin resin has a weight average molecular weight of about 700,000 to about 1,100,000,
the polyamidoamine-epihalohydrin resin has a ratio of azetidinium ions to amide residues of about 0.55 to about 0.8, and
the polyamidoamine-epihalohydrin resin has a charge density of about 1.5 mEq/gram of solids to about 3 mEq/gram of solids.
13. A method for separating particulates from an aqueous suspension, comprising:
mixing a polyamidoamine-epihalohydrin resin with an aqueous suspension comprising one or more particulates to produce a treated mixture, wherein an amount of the polyamidoamine-epihalohydrin resin in the treated mixture is less than 500 g/tonne of the one or more particulates, and wherein the treated mixture comprises less than 0.5 wt % of any polysaccharide, based on a weight of the polyamidoamine-epihalohydrin resin in the treated mixture; and
removing water from the treated mixture by drainage, filtration, sedimentation, mechanical compression, or any combination thereof to produce a purified water having a reduced concentration of the one or more particulates relative to the aqueous suspension.
14. The method of claim 13 , wherein the one or more particulates comprise sand, clay, or a mixture thereof.
15. The method of claim 13 , wherein the polyamidoamine-epihalohydrin resin comprises a reaction product of about 0.56 moles to about 1.35 moles of a polyamidoamine and about 0.75 moles to about 1.8 moles epihalohydrin, and wherein the polyamidoamine comprises a reaction product of about 0.9 moles to about 1.1 moles of a polyamine and about 1.1 moles to about 0.9 moles of a dicarboxylic acid.
16. The method of claim 13 , wherein the polyamidoamine-epihalohydrin resin has weight average molecular weight of about 750,000 to about 950,000.
17. A method for separating particulates from an aqueous suspension, comprising:
dispersing a polyamidoamine-epihalohydrin resin in an aqueous suspension comprising one or more first particulates and one or more second particulates to produce a treated mixture, wherein an amount of the polyamidoamine-epihalohydrin resin in the treated mixture is less than 500 g/tonne of the one or more first particulates and the one or more second particulates, and wherein the treated mixture comprises less than 0.5 wt % of any polysaccharide, based on a weight of the polyamidoamine-epihalohydrin resin in the treated mixture;
passing air through the treated mixture to produce a hydrophobic fraction and a hydrophilic fraction; and
collecting a purified product comprising the one or more first particulates having a reduced concentration of the one or more second particulates relative to the aqueous suspension from the hydrophobic fraction or the hydrophilic fraction.
18. The method of claim 17 , wherein the one or more first particulates comprise clay, a clay mineral, sand, a glass sand containing quartz, a silicates, quartz, a carbonates, a metal, a metal oxide, or any mixture thereof, wherein the one or more second particulates comprise antimony, barium, bauxite, bismuth, borate, borax, calcium, chromium, coal, cobalt, copper, feldspar, gold, graphite, gypsum, iron, lead, magnesium, manganese, molybdenum, nickel, palladium, phosphates, phosphorus, platinum, potash, scandium, yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, silver, magnesium silicate, sulfates, titanium, tungsten, uranium, zinc, oxides thereof, carbonates thereof, hydroxides thereof, or any mixture thereof, and wherein the one or more first particulates are different than the one or more second particulates.
19. The method of claim 18 , wherein the polyamidoamine-epihalohydrin resin has a weight average molecular weight of about 500,000 to about 1,300,000.
20. The method of claim 19 , wherein the amount of the polyamidoamine-epihalohydrin resin in the treated mixture is about 0.001 g/tonne of the one or more first particulates to less than 300 g/tonne of the one or more first particulates.