IP Library Granted Patent US 9,784,081
Granted Patent B2
US 9,784,081 · App. 14/537,330 · Granted Oct 10, 2017

Oil recovery process

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Quick Facts
Patent No.
US 9,784,081
App. No.
14/537,330
Granted
Oct 10, 2017
Kind
B2
Abstract

The present invention provides a method for enhancing the recovery of oil from a formation. An enhanced oil recovery formulation comprising a gas comprised of a hydrocarbon-containing gas and an ether having from 2 to 4 carbons is injected into an oil-bearing formation to mobilize the oil. The mobilized oil is then produced from the formation.

Claims (16)

1. A method for recovering oil from an oil-bearing formation, comprising:

injecting into the formation an enhanced oil recovery formulation consisting of gas which gas comprises at least 5 mol % of an ether having from 2 to 4 carbon atoms and at least 70 mol % of a hydrocarbon-containing gas, where the hydrocarbon-containing gas is comprised of at least 70 mol % methane;

reducing via the ether the minimum miscibility pressure required for the methane present in the formulation, wherein the reduced miscibility pressure of the methane enables the enhanced oil recovery formulation to become miscible with the oil at the formation pressure;

contacting the enhanced oil recovery formulation with oil in the oil-bearing formation to mix the gas of the enhanced oil recovery formulation with the oil; and

producing oil from the formation.

2. The method of claim 1 wherein contacting the gas of the enhanced oil recovery formulation with oil in the oil-bearing formation to mix the gas with the oil mobilizes the contacted oil in the formation.

3. The method of claim 1 wherein contacting the gas of the enhanced oil recovery formulation with the oil in the oil-bearing formation to mix the gas with the oil swells the oil.

4. The method of claim 1 wherein contacting the gas of the enhanced oil recovery formulation with the oil in the oil-bearing formation reduces oil-water interfacial tension between oil and water in the formation.

5. The method of claim 1 wherein the formation is a subterranean formation.

6. The method of claim 5 wherein the subterranean formation is located at a depth of from 200 to 1500 meters.

7. The method of claim 1 wherein at least a portion of the gas of the enhanced oil recovery formulation is produced from the formation.

8. The method of claim 1 wherein the oil in the formation has a viscosity of at most 15 cP prior to contact with the enhanced oil recovery formulation.

9. The method of claim 1 wherein a displacement fluid is injected into the formation subsequent to the injection of the enhanced oil recovery formulation into the formation.

10. The method of claim 9 wherein the displacement fluid is water.

11. The method of claim 1 wherein the ether is dimethyl ether.

12. The method of claim 1 wherein the formation has a pressure of at most 45 MPa.

Assignments (2)
CHANGE OF NAME Recorded Mar 7, 2022
From: SHELL OIL COMPANY
To: SHELL USA, INC.
Reel/Frame 059694/0819 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 10, 2014
From: BLOM, CAROLUS PETRUS ADRIANUS; HEDDEN, RALF; MATZAKOS, ANDREAS NICHOLAS; UEHARA-NAGAMINE, ERNESTO
To: SHELL OIL COMPANY
Reel/Frame 034138/0215 →