IP Library Granted Patent US 10,106,710
Granted Patent B2
US 10,106,710 · App. 14/541,103 · Granted Oct 23, 2018

Insulator material composition and method

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Quick Facts
Patent No.
US 10,106,710
App. No.
14/541,103
Granted
Oct 23, 2018
Kind
B2
Abstract

An electrical insulator material includes a polymer and a solvent, and has a viscosity in the range of from about 1.0 to about 20.0 cP such that the electrical insulator material can be applied to a surface using an ink jet print head.

Claims (31)

1. An electrical insulator material comprising a polymer and a solvent, wherein the electrical insulator material has a viscosity in the range of from about 1.0 to about 20.0 cP such that the electrical insulator material can be applied to a surface in a layer using an ink jet print head and heated to form a void-free continuous film; and

wherein the polymer is present in an amount from about 0.5% to about 6.0% by weight, wherein the solvent is present in an amount from about 30.0% to about 99.5% by weight, and wherein the polymer comprises a poly(amide imide), a linear copolyester, or a combination thereof.

2. The electrical insulator material of claim 1 , wherein the viscosity is in the range of from about 3.4 cP to about 5.5 cP.

3. The electrical insulator of claim 1 , wherein the electrical insulator material has a dynamic surface tension in a range from about 25 dynes/cm to about 45 dynes/cm.

4. The electrical insulator material of claim 1 , wherein the solvent comprises n-methyl-2-pyrrolidone.

5. The electrical insulator material of claim 1 , wherein the insulator material does not degrade in gamma butyrolactone.

6. The electrical insulator material of claim 1 , further comprising a crosslinking agent.

7. The electrical insulator material of claim 1 , further comprising a device for use in an ink jet print operation comprising:

a housing;

a series of ejection nozzles mounted within the housing, each ejection nozzle capable of ejecting a drop on demand; and

a source of the electrical insulator material communicating with the nozzles.

8. The electrical insulator material of claim 1 , wherein the insulator material is disposed in a layer having a thickness of about 25 microns to about 100 microns.

9. The electrical insulator material of claim 8 , wherein the insulator material is disposed in a layer having a thickness of about 35 microns to about 45 microns.

10. The electrical insulator material of claim 1 , wherein the surface is one of a substrate and an intermediate layer disposed on the substrate.

11. The electrical insulator material of claim 10 , wherein the intermediate layer is an adhesive material.

12. An electrical insulator material comprising a polymer and a solvent, wherein the electrical insulator material has a viscosity in the range of from about 1.0 to about 20.0 cP such that the electrical insulator material can be applied to a surface in a layer using an ink jet print head and heated to form a void-free continuous film;

wherein the polymer comprises a linear copolyester;

wherein the linear copolyester is present in an amount of from about from about 1% to about 20% by weight and wherein the solvent is present in an amount of from about 1% to about 99% by weight; and

wherein the solvent comprises toluene, xylene, and cyclohexanone, and combinations thereof.

13. A method of manufacturing a battery using an ink jet print head comprising the steps of:

jetting an electrical insulator material onto a surface, wherein the electrical insulator material comprises a polymer and a solvent and has a viscosity in the range of from about 1.0 to about 20.0 cP such that the electrical insulator material can be applied to a surface in a layer using an ink jet print head and heated to form a void-free continuous film, and wherein the polymer is present in an amount from about 0.5% to about 6.0% by weight, wherein the solvent is present in an amount from about 30.0% to about 99.5% by weight, and wherein the polymer comprises a poly(amide imide), a linear copolyester, or a combination thereof; and

vaporizing a portion of the solvent.

14. The method of claim 13 , wherein the viscosity is in the range of from about 3.4 cP to about 5.5 cP.

15. The method of claim 13 , wherein the electrical insulator material forms a layer having a thickness of about 25 microns to about 100 microns.

16. The method of claim 13 , wherein the electrical insulator material forms a layer having a thickness of about 35 microns to about 45 microns.

17. The method of claim 13 , wherein the electrical insulator material forms a layer having an electrical resistance greater than 125 megaohms.

18. The method of claim 17 , wherein the electrical insulator material forms a layer having an electrical resistance greater than 550 megaohms.

19. The method of claim 13 , wherein the electrical insulator material is jetted from an ink jet print head, and the method further comprises relative movement of the ink jet print head over the substrate to form a layer thereon.

20. The method of claim 13 , wherein the surface comprises one of a substrate and an intermediate layer atop the substrate.

21. The method of claim 20 , wherein the intermediate layer is an adhesive material.

22. The method of claim 13 , wherein the substrate is heated to promote vaporization of the solvent.

Assignments (19)
INTELLECTUAL PROPERTY ASSIGNMENT AGREEMENT Recorded Apr 22, 2025
From: WELLS FARGO BANK, NATIONAL ASSOCIATION
To: BANK OF AMERICA, N.A.
Reel/Frame 070919/0394 →
PATENT SECURITY AGREEMENT Recorded Aug 9, 2024
From: R. R. DONNELLEY & SONS COMPANY; CONSOLIDATED GRAPHICS, INC.; VALASSIS COMMUNICATIONS, INC.; VALASSIS DIGITAL CORP.; VALASSIS DIRECT MAIL, INC.
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION
Reel/Frame 068534/0447 →
PATENT SECURITY AGREEMENT Recorded Aug 9, 2024
From: R. R. DONNELLEY & SONS COMPANY; CONSOLIDATED GRAPHICS, INC.; VALASSIS COMMUNICATIONS, INC.; VALASSIS DIGITAL CORP.; VALASSIS DIRECT MAIL, INC.
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION
Reel/Frame 068534/0366 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENT RIGHTS (R/F 064463/0597) Recorded Aug 9, 2024
From: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION
To: R. R. DONNELLEY & SONS COMPANY; CONSOLIDATED GRAPHICS, INC.
Reel/Frame 068534/0330 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENT RIGHTS (R/F 064462/0445) Recorded Aug 9, 2024
From: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION
To: R. R. DONNELLEY & SONS COMPANY; CONSOLIDATED GRAPHICS, INC.
Reel/Frame 068534/0306 →
PATENT SECURITY AGREEMENT Recorded Aug 9, 2024
From: R. R. DONNELLEY & SONS COMPANY; CONSOLIDATED GRAPHICS, INC.; VALASSIS DIGITAL CORP.; VALASSIS DIRECT MAIL, INC.; VALASSIS COMMUNICATIONS, INC.
To: APOLLO ADMINISTRATIVE AGENCY LLC
Reel/Frame 068533/0812 →
RELEASE OF SECURITY INTEREST Recorded Jul 22, 2024
From: APOLLO ADMINISTRATIVE AGENCY LLC, AS ADMINISTRATIVE AGENT
To: R.R. DONNELLEY & SONS COMPANY; CONSOLIDATED GRAPHICS, INC.
Reel/Frame 068467/0314 →
RELEASE OF SECURITY INTEREST RECORDED AT RF 056122/0839; ASSIGNED VIA RF 059203/0333 TO JEFFERIES AND RF 063487/0449 TO APOLLO Recorded Apr 17, 2024
From: APOLLO ADMINISTRATIVE AGENCY LLC
To: R.R. DONNELLEY & SONS COMPANY
Reel/Frame 067131/0845 →
SECURITY INTEREST Recorded Apr 3, 2024
From: R. R. DONNELLEY & SONS COMPANY; CONSOLIDATED GRAPHICS, INC.
To: APOLLO ADMINISTRATIVE AGENCY LLC, AS ADMINISTRATIVE AGENT
Reel/Frame 067000/0669 →
PATENT SECURITY AGREEMENT Recorded Aug 1, 2023
From: R.R. DONNELLEY & SONS COMPANY; CONSOLIDATED GRAPHICS, INC.
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS 2028 NOTES COLLATERAL AGENT
Reel/Frame 064463/0597 →
PATENT SECURITY AGREEMENT Recorded Aug 1, 2023
From: R.R. DONNELLEY & SONS COMPANY; CONSOLIDATED GRAPHICS, INC.
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
Reel/Frame 064462/0445 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS, PREVIOUSLY RECORDED AT REEL 056079, FRAME 0534 Recorded Jul 31, 2023
From: U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT
To: R. R. DONNELLEY & SONS COMPANY; CONSOLIDATED GRAPHICS, INC.
Reel/Frame 064441/0646 →
ASSIGNMENT OF SECURITY INTEREST IN INTELLECTUAL PROPERTY COLLATERAL RECORDED AT REEL/FRAME 056122/0839 AND 059203/0333 Recorded Apr 28, 2023
From: JEFFERIES FINANCE LLC
To: APOLLO ADMINISTRATIVE AGENCY LLC
Reel/Frame 063487/0449 →
INTELLECTUAL PROPERTY ASSIGNMENT AGREEMENT Recorded Feb 10, 2023
From: BANK OF AMERICA, N.A.
To: WELLS FARGO BANK, NATIONAL ASSOCIATION
Reel/Frame 062702/0648 →
ASSIGNMENT OF SECURITY INTEREST IN INTELLECTUAL PROPERTY COLLATERAL RECORDED AT R/F 056122/0839 Recorded Feb 25, 2022
From: BANK OF AMERICA, N.A.
To: JEFFERIES FINANCE LLC
Reel/Frame 059203/0333 →
SECURITY INTEREST Recorded May 3, 2021
From: R. R. DONNELLEY & SONS COMPANY
To: BANK OF AMERICA, N.A.
Reel/Frame 056122/0810 →
SECURITY INTEREST Recorded May 3, 2021
From: R. R. DONNELLEY & SONS COMPANY
To: BANK OF AMERICA, N.A.
Reel/Frame 056122/0839 →
SECURITY INTEREST Recorded Apr 28, 2021
From: R. R. DONNELLEY & SONS COMPANY; CONSOLIDATED GRAPHICS, INC.
To: U.S. BANK NATIONAL ASSOCIATION
Reel/Frame 056079/0534 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 8, 2016
From: CYMAN, THEODORE F., JR.; HOOK, KEVIN J.; GEDDES, PAMELA; MURZYNOWSKI, ALAN R.; BLEASE, JAMES W.; KANFOUSH, DANIEL E.
To: R.R. DONNELLEY & SONS COMPANY
Reel/Frame 037920/0413 →