Methods of preparation of semiconductor nanocrystals group IIIA and group VA elements
View Patent ↗A method for preparing semiconductor nanocrystals is disclosed. The method includes adding one or more cation precursors and one or more anion precursors in a reaction mixture including a solvent in a reaction vessel, maintaining the reaction mixture at a first temperature and for a first time period sufficient to produce semiconductor nanocrystal seed particles of the cation and the anion, and maintaining the reaction mixture at a second temperature that is higher than the first temperature for a second time period sufficient to enlarge the semiconductor nanocrystal seed particles to produce semiconductor nanocrystals from the cation and the anion.
1. A method of preparing semiconductor nanocrystals of a semiconductor material including one or more elements of Group IIIA of the Periodic Table of Elements and one or more elements of Group VA of the Periodic Table of Elements comprising:
subjecting a mixture including one or more Group IIIA element precursors in a first solvent included in a reaction vessel at a first temperature of between about 25° C. and about 130° C., wherein the one or more Group IIIA element precursors comprise indium organic precursors;
adding semiconductor nanocrystal seed particles comprising the semiconductor material including one or more elements of Group IIIA of the Periodic Table of Elements and one or more elements of Group VA of the Periodic Table of Elements to the reaction vessel at a second temperature of between about 150° C. and about 300° C., wherein the one or more elements of Group IIIA of the Periodic Table of Elements comprise indium and the one or more elements of Group VA of the Periodic Table of Elements comprise phosphorous; and
adding one or more Group VA element precursors to the reaction vessel in a dropwise manner over a period of time sufficient to enlarge the semiconductor nanocrystal seed particles and form semiconductor nanocrystal core particles of a predetermined size, wherein the one or more Group VA element precursors comprise phosphorous organic precursors.
2. The method of claim 1 wherein the one or more Group IIIA element precursors includes one or more cation salt precursors.
3. The method of claim 1 wherein the ratio of the one or more Group IIIA element precursors to the one or more Group VA element precursors is about 1:1 to about 2:1.
4. The method of claim 1 wherein the semiconductor nanocrystal core particles are isolated and then overcoated.
5. The method of claim 1 wherein the semiconductor nanocrystal core particles are overcoated in situ.
6. The method of claim 1 wherein the one or more Group IIIA element precursors and the one or more Group VA element precursors are present in the reaction mixture in a ratio of about 1.1:1 or about 1.2:1.
7. A method of preparing semiconductor nanocrystals of a semiconductor material including one or more elements of Group IIIA of the Periodic Table of Elements and one or more elements of Group VA of the Periodic Table of Elements comprising:
mixing one or more pure Group IIIA element precursors and a carboxylic acid in a solvent in a reaction vessel and heating at a first temperature of between about 25° C. and about 130° C., wherein the one or more Group IIIA element precursors comprise indium organic precursors;
adding semiconductor nanocrystal seed particles comprising the semiconductor material including one or more elements of Group IIIA of the Periodic Table of Elements and one or more elements of Group VA of the Periodic Table of Elements to the reaction vessel at a second temperature of between about 150° C. and about 300° C., wherein the one or more elements of Group IIIA of the Periodic Table of Elements comprise indium and the one or more elements of Group VA of the Periodic Table of Elements comprise phosphorous; and
adding one or more Group VA element precursors to the reaction vessel over a period of time sufficient to form semiconductor nanocrystal core particles of a predetermined size, wherein the one or more Group VA element precursors comprise phosphorous organic precursors.
8. The method of claim 7 wherein the carboxylic acid is added to the reaction vessel before the one or more pure Group IIIA element precursors are added to the reaction vessel.
9. The method of claim 7 wherein the one or more Group IIIA element precursors includes one or more cation salt precursors.
10. The method of claim 7 wherein the ratio of the one or more Group IIIA element precursors to the one or more Group VA element precursors is about 1:1 to about 2:1.
11. The method of claim 7 wherein the one or more Group IIIA element precursors includes indium myristate.
12. The method of claim 7 wherein the semiconductor nanocrystal core particles are isolated and then overcoated.
13. The method of claim 7 wherein the semiconductor nanocrystal core particles are overcoated in situ.
14. The method of claim 7 wherein the one or more Group IIIA element precursors and the one or more Group VA element precursors are present in the reaction mixture in a ratio of about 1.1:1 or about 1.2:1.