Fuel cell interconnect with reduced voltage degradation over time
View Patent ↗A method of making an interconnect for a solid oxide fuel cell stack includes providing a chromium alloy interconnect and providing a nickel mesh in contact with a fuel side of the interconnect. Formation of a chromium oxide layer is reduced or avoided in locations between the nickel mesh and the fuel side of the interconnect. A Cr—Ni alloy or a Cr—Fe—Ni alloy is located at least in the fuel side of the interconnect under the nickel mesh.
1. A method of making an interconnect for a solid oxide fuel cell stack, comprising:
providing a chromium alloy interconnect; and
providing a nickel mesh in contact with a fuel side of the interconnect;
wherein formation of a chromium oxide layer is reduced or avoided in locations between the nickel mesh and the fuel side of the interconnect.
2. The method of claim 1 , further comprising a Cr—Ni alloy or a Cr—Fe—Ni alloy located at least in the fuel side of the interconnect under the nickel mesh.
3. The method of claim 1 , wherein the formation of the chromium oxide layer is reduced or avoided by at least one of increasing compression pressure between the nickel mesh and the interconnect, providing undiffused Fe in the interconnect under the nickel mesh, reducing surface contamination between the interconnect and the nickel mesh, attaching the nickel mesh to the interconnect, or adding nickel to the interconnect alloy.
4. The method of claim 3 , wherein the formation of the chromium oxide layer is reduced or avoided by at least two of increasing compression pressure between the nickel mesh and the interconnect, providing undiffused Fe in the interconnect under the nickel mesh, reducing surface contamination between the interconnect and the nickel mesh, attaching the nickel mesh to the interconnect, and adding nickel to the interconnect alloy.
5. The method of claim 3 , wherein the formation of the chromium oxide layer is reduced or avoided by increasing the compression pressure between the nickel mesh and the interconnect by generating a pressure field or gradient on the mesh.
6. The method of claim 5 , wherein interconnect ribs in a middle of the interconnect have a greater height than interconnect ribs in a periphery of the interconnect to generate the pressure field or gradient on the mesh in a solid oxide fuel cell stack.
7. The method of claim 3 , wherein the formation of the chromium oxide layer is reduced or avoided by providing the undiffused Fe in the interconnect under the nickel mesh.
8. The method of claim 7 , wherein providing the undiffused Fe in the interconnect under the nickel mesh comprises pressing a chromium and iron containing powder to form the interconnect followed by partially sintering the interconnect at a lower temperature or a shorter duration than that required for fully alloying the iron and chromium powder particles.
9. The method of claim 7 , wherein providing the undiffused Fe in the interconnect under the nickel mesh comprises pressing mixture of a chromium powder having a first average particle size and iron powder having a second particle size larger than the first particle size to form the interconnect followed by sintering the interconnect.
10. The method of claim 3 , wherein the formation of the chromium oxide layer is reduced or avoided by attaching the nickel mesh to the interconnect using thermal fusing or welding.
11. The method of claim 3 , wherein the formation of the chromium oxide layer is reduced or avoided adding nickel to the interconnect alloy.
12. The method of claim 11 , wherein the nickel fully or partially substitutes iron at least in a fuel side of the interconnect.
13. The method of claim 12 , wherein the nickel fully or partially substitutes iron only in the fuel side of the interconnect by providing nickel powder having a different average particle size than chromium powder in a mold cavity.
14. The method of claim 12 , wherein the nickel fully or partially substitutes iron only in the fuel side of the interconnect by:
providing first metallic powder particles comprising Cr and Fe in a mold cavity;
providing second powder particles comprising nickel in the mold cavity; and
compacting the first and second powder particles to form the interconnect.
15. The method of claim 14 , wherein the first powder particles are provided in the mold cavity first and the second powder particles provided on top of the first powder particles in the mold cavity.
16. The method of claim 14 , wherein the second powder particles are provided in the mold cavity first and the first powder particles provided on top of the second powder particles in the mold cavity.
17. The method of claim 14 , wherein:
the first or the second powder particles are provided to the mold first and the other ones of the first or the second powder particles are electrostatically attracted to a bottom surface of a punch used to compact the powder particles; and
the punch presses the first powder and the second powder to compact the first and the second power particles.
18. An interconnect for a solid oxide fuel cell stack, comprising:
a chromium alloy interconnect; and
a nickel mesh in contact with a fuel side of the interconnect;
wherein a Cr—Ni alloy or a Cr—Fe—Ni alloy is located at least in the fuel side of the interconnect under the nickel mesh.
19. The interconnect of claim 18 , wherein interconnect ribs in a middle of the interconnect have a greater height than interconnect ribs in a periphery of the interconnect to generate a pressure field or gradient on the mesh in a solid oxide fuel cell stack.
20. The interconnect of claim 18 , wherein undiffused Fe is located in the fuel side of the interconnect under the nickel mesh.
21. The interconnect of claim 18 , wherein the nickel mesh is welded or thermally fused to the interconnect.
22. The interconnect of claim 18 , wherein the interconnect alloy contains nickel.