Adhesive film for polarizing plate, polarizing plate including the same and optical display including the same
An adhesive film for polarizing plates, a polarizing plate, and an optical display, the adhesive film being prepared from an adhesive composition including an isocyanate crosslinking agent and an imide crosslinking agent, and having a ΔG′ of about 50% to about 80%, ΔG′ being represented by Equation 1: Δ G ′=( G 1− G 2)/ G 1×100 [Equation 1] in which G1 is a storage modulus of the adhesive film for polarizing plates as measured at 25° C., and G2 is a storage modulus of the adhesive film for polarizing plates as measured at 85° C.
1. An adhesive film for polarizing plates, the adhesive film:
being prepared from an adhesive composition including an isocyanate crosslinking agent, an imide crosslinking agent, a first (meth)acrylic copolymer, and a second (meth)acrylic copolymer, and
having a ΔG′ of about 50% to about 80%, ΔG′ being represented by Equation 1:
Δ G ′=( G 1− G 2)/ G 1×100 [Equation 1]
wherein G1 is a storage modulus of the adhesive film for polarizing plates as measured at 25° C., and G2 is a storage modulus of the adhesive film for polarizing plates as measured at 85° C., and
wherein:
the isocyanate crosslinking agent and the imide crosslinking agent are included together in the composition in an amount of 1.1 parts by weight to 6 parts by weight, based on 100 total parts by weight of the first (meth)acrylic copolymer and the second (meth)acrylic copolymer,
the first (meth)acrylic copolymer is a copolymer of a monomer mixture including:
about 65 wt % to about 90 wt % of an alkyl group-containing (meth)acrylic monomer,
about 0.1 wt % to about 5 wt % of a hydroxyl group-containing (meth)acrylic monomer,
about 1 wt % to about 15 wt % of an aromatic group-containing (meth)acrylic monomer, and
about 1 wt % to about 20 wt % of a nitrogen-containing vinyl monomer, and
the second (meth)acrylic copolymer is a copolymer of a monomer mixture including:
about 50 wt % to about 90 wt % of an alkyl group-containing (meth)acrylic monomer,
about 0.1 wt % to about 5 wt % of a hydroxyl group-containing (meth)acrylic monomer,
about 1 wt % to about 20 wt % of an aromatic group-containing (meth)acrylic monomer, and
about 1 wt % to about 20 wt % of a nitrogen-containing vinyl monomer.
2. The adhesive film as claimed in claim 1 , wherein G2 of the adhesive film is about 1.0×10 4 Pa to about 1.0×10 5 Pa.
3. The adhesive film as claimed in claim 1 , wherein G2 of the adhesive film is about 2.5×10 4 Pa to about 4.0×10 4 Pa.
4. The adhesive film as claimed in claim 1 , wherein the isocyanate crosslinking agent includes a modified polyisocyanate of hexamethylene diisocyanate.
5. The adhesive film as claimed in claim 1 , wherein the imide crosslinking agent includes an isocyanate group.
6. The adhesive film as claimed in claim 1 , wherein:
the first (meth)acrylic copolymer has:
a weight average molecular weight of about 300,000 g/mol to about 700,000 g/mol, and
a glass transition temperature (Tg) of about −50° C. to about −40° C.; and
the second (meth)acrylic copolymer has:
a weight average molecular weight of about 100,000 g/mol to about 300,000 g/mol, and
a glass transition temperature (Tg) of about −10° C. to about 0° C.
7. The adhesive film as claimed in claim 6 , wherein, when the glass transition temperature of the first (meth)acrylic copolymer in Kelvin is X and the glass transition temperature of the second (meth)acrylic copolymer in Kelvin is Y, (Y−X)/Y is about 0.1 to about 0.15.
8. The adhesive film as claimed in claim 6 , wherein a difference between the weight average molecular weight of the first (meth)acrylic copolymer and the weight average molecular weight of the second (meth)acrylic copolymer is about 50,000 g/mol to about 500,000 g/mol.
9. The adhesive film as claimed in claim 6 , wherein the adhesive composition further includes an epoxy group-containing silane coupling agent.
10. The adhesive film as claimed in claim 1 , wherein:
the monomer mixture of the first (meth)acrylic copolymer further includes (meth)acrylic acid, and
the monomer mixture of the second (meth)acrylic copolymer further includes (meth)acrylic acid.
11. The adhesive film as claimed in claim 10 , wherein:
the first (meth)acrylic copolymer has an acid value from about 1.5 mg/KOH to about 5.0 mg/KOH, and
the second (meth)acrylic copolymer has an acid value from about 1.5 mg/KOH to about 5.0 mg/KOH.
12. A polarizing plate comprising the adhesive film for polarizing plates as claimed in claim 1 .
13. An optical display, comprising:
a liquid crystal display panel;
a light source;
a first polarizing plate on one surface of the liquid crystal display panel; and
a second polarizing plate on another surface of the liquid crystal display panel, the second polarizing plate being between the liquid crystal display panel and the light source,
wherein:
the liquid crystal display panel includes an upper substrate, a lower substrate, and a liquid crystal cell layer enclosed between the upper and lower substrates,
the liquid crystal display panel has a thickness of about 0.05 mm to about 5 mm, and
at least one of the first polarizing plate and the second polarizing plate includes the adhesive film for polarizing plates as claimed in claim 1 .
14. A method of manufacturing optical display, the method comprising:
providing a liquid crystal display panel;
providing a light source at one side of the liquid crystal display panel;
providing a first polarizing plate on one surface of the liquid crystal display panel; and
providing a second polarizing plate on another surface of the liquid crystal display panel, the second polarizing plate being between the liquid crystal display panel and the light source,
wherein at least one of the first polarizing plate and the second polarizing plate includes the adhesive film for polarizing plates as claimed in claim 1 .