IP Library Granted Patent US 9,102,788
Granted Patent B2
US 9,102,788 · App. 14/548,499 · Granted Aug 11, 2015

Process for forming an aramid copolymer

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Quick Facts
Patent No.
US 9,102,788
App. No.
14/548,499
Granted
Aug 11, 2015
Kind
B2
Abstract

The invention concerns processes for forming polymer crumb comprising residues of 2-(4-amino phenyl)-5 (6) amino benzimidazole (DAPBI), paraphenylene diamine (PPD), and terephthaloyl dichloride (TCl), comprising the steps of: i) forming a slurry of b mole percent DAPBI in a solvent system comprising organic solvent and c weight percent of an inorganic salt, wherein the inorganic salt is present in an amount of at least 5 weight present of the organic solvent; ii) contacting the slurry with a less than stoichiometric amount of terephthaloyl chloride to form an prepolymer solution; and iii) contacting the prepolymer solution with y mole percent of PPD and additional TCL to form a polymer solution; wherein the total amount of TCL added in steps ii) and iii) is a stoichiometric amount based on the total amount of DAPBI and PPD added in steps i) and iii); the DAPBI and PPD are added in an amount sufficient for providing a polymer solution having a weight percent solids of 12 percent or greater on a polymer basis; and wherein the sum of y+b is 100 and the product of b×c is 225 or greater.

Claims (12)

1. A polymer comprising residues of 2-(4-amino phenyl)-5(6) amino benzimidazole (DAPBI), paraphenylene diamine (PPD) and terephthaloyl dichloride (TCL), made by a process comprising the steps of:

i) forming a slurry of b mole percent DAPBI in a solvent system comprising organic solvent and c weight percent of an inorganic salt, wherein the inorganic salt is present in an amount of at least 5 weight percent of the organic solvent;

ii) contacting the slurry with a less than stoichiometric amount of terephthaloyl chloride, based on the amount of DAPBI in step i), to form an prepolymer solution; and

iii) contacting the prepolymer solution with y mole percent of PPD and additional TCL to form a polymer solution;

wherein the total amount of TCL added in steps ii) and iii) is a stoichiometric amount based on the total amount of DAPBI added in step i) and PPD added in step iii);

wherein the DAPBI and PPD are added in an amount sufficient for providing a polymer solution having a weight percent solids of 12 percent or greater on a polymer basis; and

wherein the sum of y+b is 100 and the product of b×c is 225 or greater.

2. The polymer of claim 1 wherein the product of (b×c) is equal to 300 or greater.

3. The polymer of claim 2 wherein the product of (b×c) is equal to 350 or greater.

4. The polymer of claim 1 wherein the DAPBI and PPD are present in a molar ratio in the range of from 0.25 to 4.

5. The polymer of claim 1 wherein the polymer has an inherent viscosity of 4 dl/g or greater.

6. The polymer of claim 1 in the form of a crumb.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 25, 2019
From: E. I. DU PONT DE NEMOURS AND COMPANY
To: DUPONT SAFETY & CONSTRUCTION, INC.
Reel/Frame 049585/0450 →