Continuous silica production process and silica product prepared from same
View Patent ↗Disclosed herein is a continuous process for preparing a silica product, comprising: (a) continuously feeding an acidulating agent and an alkali metal silicate into a loop reaction zone comprising a stream of liquid medium; wherein at least a portion of the acidulating agent and the alkali metal silicate react to form a silica product in the liquid medium of the loop reaction zone; (b) continuously recirculating the liquid medium through the loop reaction zone; and (c) continuously discharging from the loop reaction zone a portion of the liquid medium comprising the silica product. Silica products and dentifrice compositions comprising the silica products are also disclosed. A continuous loop reactor is also disclosed.
1. A continuous process for preparing a silica product, comprising: (a) continuously feeding an acidulating agent and an alkali metal silicate into a loop reaction zone comprising a stream of liquid medium; wherein at least a portion of the acidulating agent and the alkali metal silicate react to form a silica product in the liquid medium of the loop reaction zone; (b) continuously recirculating the liquid medium through the loop reaction zone; and (c) continuously discharging from the loop reaction zone a portion of the liquid medium comprising the silica product, wherein the silica product comprises silica particles having an oil absorption value of up to 100 cc/100 g; wherein at least 80% of the silica particles are rounded to well rounded; and wherein the silica particles have a sphericity (S 80 ) factor of greater than 0.9 and a Brass Einlehner Abrasion value of less than 8 mg lost/100,000 revolutions.
2. The process of claim 1 , wherein the liquid medium is recirculated through the loop reaction zone at a rate of at least 15 L/min.
3. The process of claim 1 , wherein the liquid medium comprising the silica product is recirculated through the loop reaction zone from 10 to 200 times prior to being discharged from the loop reaction zone.
4. The process of claim 1 , wherein the liquid medium is recirculated through the loop reaction zone at a rate of from 97 vol. % to 645 vol. % per minute, based on the volume of the liquid medium in the loop reaction zone.
5. A continuous process for preparing a silica product, comprising: (a) continuously feeding an acidulating agent and an alkali metal silicate into a loop reaction zone comprising a stream of liquid medium; wherein at least a portion of the acidulating agent and the alkali metal silicate react to form a silica product in the liquid medium of the loop reaction zone; (b) continuously recirculating the liquid medium through the loop reaction zone; and (c) continuously discharging from the loop reaction zone a portion of the liquid medium comprising the silica product, wherein the silica product comprises silica particles having a median particle size of from 3 to 15 μm, an oil absorption value of greater than 100 cc/100 g, a Pellicle Cleaning Ratio (PCR) value at 20% silica loading of at least 85, and a Perspex Abrasion Value of from 3.3 to 8.7.
6. The process of claim 5 , wherein the liquid medium is recirculated through the loop reaction zone at a rate of at least 15 L/min.
7. The process of claim 5 , wherein the liquid medium comprising the silica product is recirculated through the loop reaction zone from 10 to 200 times prior to being discharged from the loop reaction zone.
8. The process of claim 5 , wherein the liquid medium is recirculated through the loop reaction zone at a rate of from 97 vol. % to 645 vol. % per minute, based on the volume of the liquid medium in the loop reaction zone.