Pressure-sensitive adhesive composition
Provided are a pressure-sensitive adhesive composition, an optical laminate, a pressure-sensitive adhesive polarizing plate and a display device. When a particular block copolymer forming a micro phase separation region in a crosslinking structure is used, and a cohesive strength of the block copolymer is controlled, a pressure-sensitive adhesive composition having excellent physical properties required for an optical member, and particularly having excellent bending preventability, cuttability and pressure-sensitive adhesive durability may be provided. Such a pressure-sensitive adhesive composition may be used for optical uses, for example, to laminate various optical members, or apply an optical member to a display device.
1. A pressure-sensitive adhesive composition, comprising:
a block copolymer including a first block having a glass transition temperature of 50° C. or more and including a polymerization unit of 80 to 99.9 parts by weight of a (meth) acrylic acid ester monomer and a polymerization unit of 0.1 to 20 parts by weight of a monomer providing a crosslinkable functional group, and a second block having a glass transition temperature of −10° C. or less and including a monomer providing a crosslinkable functional group; and
a multifunctional crosslinking agent,
wherein the monomers providing a crosslinkable functional group included in the first and second blocks are represented by Formula 1, and the number of carbon atoms included in alkylene groups of A and B in Formula 1 of the monomer included in the second block is larger than that of the monomer included in the first block:
where Q is hydrogen or an alkyl group having 1 to 4 carbon atoms, A and B may be each independently a linear alkylene group, and n is a number of 0 to 10,
wherein the block copolymer includes 500 to 1,500 parts by weight of the second block with respect to 100 parts by weight of the first block.
2. The composition according to claim 1 , wherein the glass transition temperature of the first block is 70 to 100° C.
3. The composition according to claim 1 , wherein the (meth)acrylic acid ester monomer is an alkyl methacrylate.
4. The composition according to claim 1 , wherein the second block includes a polymerization unit of 80 to 99.9 parts by weight of a (meth)acrylic acid ester monomer and a polymerization unit of 0.1 to 20 parts by weight of a monomer providing a crosslinkable functional group.
5. The composition according to claim 3 , wherein the (meth)acrylic acid ester monomer of the second block is an alkyl acrylate.
6. The composition according to claim 1 , wherein the number of carbon atoms included in the alkylene groups of A and B of the monomer included in the first block ranges from 1 to 3, and the number of carbon atoms included in the alkylene groups of A and B of the monomer included in the second block ranges from 4 to 10.
7. The composition according to claim 1 , wherein the block copolymer has a number average molecular weight of 3,000 to 300,000.
8. The composition according to claim 1 , wherein the block copolymer has a polydispersity index (Mw/Mn) of 1.0 to 2.5.
9. The composition according to claim 1 , wherein the block copolymer is a diblock copolymer having the first block and the second block.
10. The composition according to claim 1 , wherein the multifunctional crosslinking agent is included at 0.01 to 10 parts by weight with respect to 100 parts by weight of the block copolymer.
11. A pressure-sensitive adhesive optical laminate, comprising:
an optical film; and
a pressure-sensitive adhesive layer formed on one or both surfaces of the optical film and including the crosslinked pressure-sensitive adhesive composition of claim 1 .
12. A polarizing plate, comprising:
a polarizer; and
a pressure-sensitive adhesive layer formed on one or both surfaces of the polarizer, and including the crosslinked pressure-sensitive adhesive composition of claim 1 .
13. A display device comprising the optical laminate of claim 11 or the polarizing plate of claim 12 .