Cathode active material and lithium secondary battery including the same
View Patent ↗Disclosed are a cathode active material including a lithium transition metal oxide based on at least one transition metal selected from the group consisting of Ni, Mn and Co, wherein at least one hetero element selected from the group consisting of Ti, Co, Al, Cu, Fe, Mg, B, Cr, Bi, Zn and Zr is located at a surface portion of or inside the lithium transition metal oxide, and a secondary battery including the same. The cathode active material according to the present invention includes predetermined hetero elements at a surface thereof and therein, and, as such, a secondary battery based on the cathode active material may exhibit excellent high-speed charge characteristics and lifespan characteristics.
1. A method of preparing a lithium transition metal oxide, comprising:
reacting a Mn—Ni-containing transition metal precursor with 0.001 to 0.9 mol % M x′ A y′ to form a surface treated transition metal precursor,
wherein M is at least one selected from the group consisting of Ti, Co, Al, Cu, Fe, Mg, B, Cr, Bi, Zn, and Zr;
A is at least one selected from the group consisting of O, OH, SO 4 , PO 4 , NO 3 , CO 3 , BO 3 , and F; and
when 0<x′<4 and 0<y′<4, an oxidation number of M times x′ plus an oxidation number of A times y′ is 0;
mixing the surface treated transition metal precursor with a lithium containing material; and
sintering the mixture to form the lithium transition metal oxide based on Ni and Mn, wherein at least one hetero element selected from the group consisting of Ti, Co, Al, Cu, Fe, Mg, B, Cr, Bi, Zn and Zr is located at a surface portion of or inside the lithium transition metal oxide.
2. The method according to claim 1 , wherein M x′ A y′ is at least one selected from the group consisting of TiO 2 , Co 3 O 4 , Al 2 O 3 , CuO, Fe 2 O 3 , Fe 3 O 4 , MgO, B 2 O 3 , Cr 2 O 3 , Ti(SO 4 ) 2 , CoSO 4 , Al 2 (SO 4 ) 3 , CuSO 4 , FeSO 4 , MgSO 4 , Ti 3 (PO 4 ) 4 , CoPO 4 , AlPO 4 , Mg 3 (PO 4 ) 2 , TiF 4 , CoF 3 , AlF 3 , CuF 2 , FeF 3 , Al(NO 3 ) 3 and MgF 2 .
3. The method according to claim 1 , wherein M x′ A y′ dissolved in water or sodium hydroxide is added to a reactor.