IP Library Granted Patent US 9,687,437
Granted Patent B2
US 9,687,437 · App. 14/560,602 · Granted Jun 27, 2017

Methods and compositions for preventing or reducing frizzy appearance of hair

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Quick Facts
Patent No.
US 9,687,437
App. No.
14/560,602
Granted
Jun 27, 2017
Kind
B2
Abstract

Compositions and methods are disclosed for preventing or reducing frizzy appearance of keratin fibers, including hair, and reducing the amount of fly-away strands of hair, particularly in humid conditions, by forming a coating on hair that is resistant to water vapors from the air or surrounding environment. The compositions comprise a combination of a hydrophobic particulate material comprising a hydrophobically surface-modified aluminum oxide and one or more hydrophobic film formers in a cosmetically acceptable vehicle.

Claims (15)

1. A method for preventing or reducing frizzy appearance of hair comprising applying to the hair a composition comprising:

(a) a hydrophobic particulate material having a median particle size between about 10 nm and about 20 μm comprising a hydrophobically surface-modified aluminum oxide, said hydrophobic particulate material comprising from about 0.1% to about 2.0% by weight of said composition;

(b) a silicone-based hydrophobic film former comprising from about 0.5% to about 20% by weight of said composition; and

(c) a volatile hydrocarbon or silicone fluid having a vapor pressure above about 0.01 mmHg at 20° C.;

wherein the aggregate weight percentage of all non-volatile water-soluble or water-dispersible organic constituents in said composition is less than 5%, based on the entire weight of the composition.

2. The method according to claim 1 , wherein said aluminum oxide is surface modified with alkylsilane groups.

3. The method according to claim 2 , wherein said alkylsilane is caprylylsilane.

4. The method according to claim 3 , wherein said aluminum oxide is fumed alumina.

5. The method according to claim 1 , wherein said aluminum oxide is fumed aluminum oxide that is surface modified with alkylsilane groups.

6. The method according to claim 1 , wherein said silicone-based hydrophobic film former comprises dimethicone, amodimethicone, dimethiconol, silicone polyurethane, silicone acrylate, or a combination thereof.

7. The method according to claim 6 , wherein said silicone-based hydrophobic film former comprises a silicone acrylate copolymer.

8. The method according to claim 7 , wherein said silicone acrylate copolymer is a copolymer comprising a poly(alkyl)acrylate backbone and a dimethicone polymer grafted to an alkyl ester side chain.

9. The method according to claim 1 , wherein said composition is in the form of a liquid or emulsion.

10. The method according to claim 9 , wherein the composition applied to the hair further comprises ethyl alcohol.

11. The method according to claim 9 , wherein the composition applied to the hair is an emulsion further comprising water.

Assignments (9)
RELEASE OF SECURITY INTEREST Recorded Jan 28, 2026
From: NATURA &CO LUXEMBOURG HOLDINGS S.À R.L., AS A SECURED PARTY; NATURA &CO UK HOLDINGS LIMITED, AS A SECURED PARTY
To: AVON PRODUCTS, INC.
Reel/Frame 074508/0281 →
RELEASE OF SECURITY INTEREST Recorded Dec 11, 2024
From: NATURA &CO HOLDING S.A.; NATURA COSMETICOS S.A.; NATURA &CO LUXEMBOURG HOLDINGS S.A R.L. - LUXEMBOURG; NATURA &CO UK HOLDINGS LIMITED - UK
To: AVON PRODUCTS, INC
Reel/Frame 069591/0494 →
PATENT SECURITY AGREEMENT Recorded Aug 16, 2024
From: AVON PRODUCTS, INC.
To: NATURA &CO HOLDING S.A.; NATURA &CO LUXEMBOURG HOLDINGS S.À R.L.; NATURA COSMÉTICOS S.A.; NATURA &CO UK HOLDINGS LIMITED
Reel/Frame 068659/0915 →
SECURITY INTEREST Recorded Aug 11, 2023
From: AVON PRODUCTS, INC.
To: NATURA &CO LUXEMBOURG HOLDINGS S.À R.L., AS A SECURED PARTY; NATURA &CO UK HOLDINGS LIMITED, AS A SECURED PARTY
Reel/Frame 064566/0872 →
SECURITY INTEREST Recorded Nov 14, 2019
From: AVON PRODUCTS, INC.
To: CITIBANK, N.A., LONDON BRANCH
Reel/Frame 051032/0210 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 29, 2016
From: GARRISON, MARK S.; ROBINSON, FREDA E.; SANDSTROM, GIOVANA A.; BUCKRIDGE, KENNETH A.; YANG, SEN; LUO, XIAOCHUN
To: AVON PRODUCTS, INC.
Reel/Frame 039564/0285 →
RELEASE OF SECURITY INTEREST IN PATENTS Recorded Aug 15, 2016
From: CITIBANK, N.A.
To: AVON PRODUCTS, INC.
Reel/Frame 039690/0331 →
SECURITY INTEREST Recorded Jun 12, 2015
From: AVON PRODUCTS, INC.
To: CITIBANK, N.A.
Reel/Frame 035899/0776 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 4, 2014
From: GARRISON, MARK S.; ROBINSON, FREDA E.; SANDSTROM, GIOVANA A.; BUCKRIDGE, KENNETH A.; YANG, SEN
To: AVON PRODUCTS, INC.
Reel/Frame 034378/0535 →