Methods of producing jet fuel from natural oil feedstocks through metathesis reactions
View Patent ↗Methods are provided for producing a jet fuel composition from a feedstock including a natural oil. The methods include reacting the feedstock with a low-weight olefin in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product. The methods further include hydrogenating the metathesized product under conditions sufficient to form a jet fuel composition.
1. A method of producing a jet fuel composition comprising:
providing a feedstock comprising natural oil glycerides or derivatives thereof, wherein the derivatives are obtained by saponification, esterification, hydrogenation, isomerization, oxidation, reduction, or a combination thereof;
reacting the feedstock with a low-weight olefin to provide a metathesized product having metathesized glycerides or metathesized derivatives thereof, wherein the metathesized glycerides or metathesized derivatives thereof comprise ester, acid, or alcohol moieties; and
hydrogenating the metathesized product to provide a jet fuel composition, wherein at least a portion of the metathesized glycerides or the metathesized derivatives thereof having the ester, acid, or alcohol moieties are converted into paraffin.
2. The method of claim 1 , further comprising isomerizing the jet fuel composition, wherein at least a portion of normal-paraffin compounds in the jet fuel composition are isomerized into iso-paraffin compounds.
3. The method of claim 1 , wherein the jet fuel composition comprises C 2 -C 4 hydrocarbons, C 18 + compounds, or water, and wherein the method further comprises separating at least a portion of the C 2 -C 4 hydrocarbons, at least a portion of the C 18 + compounds, or at least a portion of the water from the jet fuel composition.
4. The method of claim 3 , further comprising isomerizing the jet fuel composition after the separating, wherein at least a portion of normal-paraffin compounds in the jet fuel composition are isomerized into iso-paraffin compounds.
5. The method of claim 1 , wherein the low-weight olefin comprises at least one low-weight olefin selected from the group consisting of ethylene, propylene, 1-butene, and 2-butene.
6. The method of claim 1 , wherein the low-weight olefin comprises an alpha-olefin.
7. The method of claim 6 , wherein the alpha-olefin is a C 2 -C 10 alpha-olefin.
8. The method of claim 1 , wherein the low-weight olefin comprises 1-butene.
9. The method of claim 1 , wherein the low-weight olefin comprises at least one C 4 to C 10 branched olefin.
10. The method of claim 1 , wherein the jet fuel composition has a hydrocarbon distribution centered at C 10 to C 12 hydrocarbons.
11. The method of claim 1 , wherein the jet fuel composition comprises at least 70 wt % C 9 -C 15 alkanes based on a total weight of hydrocarbons in the jet fuel composition.
12. The method of claim 1 , wherein the jet fuel composition comprises at least 80 wt % C 9 -C 15 alkanes based on a total weight of hydrocarbons in the jet fuel composition.
13. The method of claim 1 , wherein the natural oil glycerides comprise natural oil triglycerides.
14. The method of claim 1 , wherein the natural oil glyceride derivatives comprise fatty acid methyl esters.