Cathode materials for lithium battery having higher performance
Provided is a method for preparing the heat-treated mixture of an oxide powder (a) represented by Formula I and an oxide powder (b) represented by Formula II, LiCoO 2 (I) Li z MO 2 (II) wherein 0.95<z<1.1; M=Ni 1-x-y Mn x Co y , 0<y<0.5, and a ratio of Mn to Ni (x/(1-x-y)) is in the range of 0.4 to 1.1, comprising mixing (i) a Co-containing precursor, (ii) an Mn—Ni-containing precursor, and (iii) optionally, an Li-containing precursor, and heat-treating the mixture at a temperature of more than 400° C. under an oxygen-containing atmosphere.
1. A method for preparing the heat-treated mixture of an oxide powder (a) represented by Formula I and an oxide powder (b) represented by Formula II, wherein a mixing ratio of the oxide powder (a):oxide powder (b) is in the range of 30:70 to 90:10, the oxide powder (a) is monolithic particles having a D50 of more than 10 μm, and the oxide powder (b) is agglomerated particles having a D50 of less than 10 μm, and heat treatment is carried out at a temperature of 400° C. or higher:
LiCoO 2 (I)
Li z MO 2 (II)
wherein 0.95<z<1.1; M=Ni 1-x-y Mn x Co y , 0<y<0.5, and a ratio of Mn to Ni (x/(1-x-y)) is in the range of 0.4 to 1.1, comprising mixing (i) a Co-containing precursor, (ii) an Mn—Ni-containing precursor, and (iii) optionally, an Li-containing precursor, and heat-treating the mixture at a temperature of more than 400° C. under an oxygen-containing atmosphere.
2. The method according to claim 1 , wherein the heat treatment is carried out at a temperature of 700 to 1050° C. in air.
3. The method according to claim 2 , wherein the heat treatment is carried out at a temperature of 900 to 1000° C. in air.
4. The method according to claim 1 , wherein the Co-containing precursor is selected from the group consisting of a cobalt oxide, a cobalt hydroxide, a cobalt oxohydroxide, a cobalt carbonate, a cobalt carbonate-hydroxide, a lithium cobalt oxide and any combination thereof;
the Mn—Ni-containing precursor is selected from the group consisting of a mixed oxide, a mixed hydroxide, a mixed oxohydroxide, a mixed carbonate, a mixed carbonate-hydroxide, a lithium-mixed transition metal oxide and any combination thereof; and
the Li-containing precursor is LiCO 3 .
5. The method according to claim 1 , wherein the Co-containing precursor is Co 3 O 4 or LiCoO 2 .
6. The method according to claim 1 , wherein the Mn—Ni-containing precursor is a compound of Formula MOOH (M=Ni 1-x-y Mn x Co y : and x, y and z are as defined above) or a lithium-mixed transition metal oxide of Formula Li z Ni 1-x-y Mn x Co y O 2 (x, y and z are as defined above).
7. The method according to claim 1 , wherein the Co-containing precursor has a D50 of more than 10 μm, and the Mn—Ni containing precursor has a D50 of less than 10 μm.