SUNSCREEN COMPOSITIONS CONTAINING AN ULTRAVIOLET RADIATION-ABSORBING POLYESTER
Compositions including an oil phase emulsified in a continuous water phase, the oil phase including a sunscreen agent that includes a UV-absorbing polyester in an amount effective to provide the composition with an SPF of about 10 or greater and which is the polymerization reaction product of monomers including a UV-absorbing triazole, a diester, a diol and a tetrol polyol; an anionic oil-in-water emulsifier, and a nonionic oil-in-water emulsifier having an alcohol functional group, where the weight ratio of the anionic emulsifier to the nonionic emulsifier is about 2 or less and where the composition is substantially free of a non-polymeric UV-absorbing sunscreen agent and will have an SPF of less than 2 in the absence of the UV-absorbing polyester.
1 - 14 . (canceled)
15 . A composition, comprising:
a continuous water phase,
a discontinuous oil phase homogenously distributed in said water phase, said oil phase comprising about 15 percent or more by weight of a sunscreen agent comprising a UV-absorbing polyester in an amount effective to provide said composition with an SPF of about 20 or greater, which UV-absorbing polyester comprises the polymerization reaction product of monomers comprising a UV-absorbing triazole, a diester, a diol and a tetrol polyol,
from about 1% to about 10% by weight of an anionic oil-in-water emulsifier; and
from about 1% to about 10% by weight of a nonionic oil-in-water emulsifier comprising an alcohol functional group, wherein said nonionic oil-in-water emulsifier excludes an oil gelling polymer,
wherein the weight ratio of said anionic oil-in-water emulsifier to said nonionic oil-in-water emulsifier is about 1.5 or less, and wherein said composition comprises 1 percent or less by weight of a non-polymeric UV-absorbing sunscreen agent and has an SPF of less than 2 in the absence of said UV-absorbing polyester.
16 . The composition of claim 15 wherein said UV-absorbing polyester has a weight average molecular weight of about 4,000 or more.
17 . The composition of claim 15 wherein the UV-absorbing triazole, the diester, the diol and the tetrol polyol are reacted such that the mole fraction of UV-absorbing triazole, relative to the total number of moles of monomer used in the reaction, is from about 0.39 to about 0.60.
18 . The composition of claim 15 wherein the anionic oil-in-water emulsifier is present at a concentration by weight from about 3% to about 8%.
19 . The composition of claim 15 wherein the anionic oil-in-water emulsifier is selected from the group consisting of alkyl, aryl or alkylaryl, or acyl-modified versions of sulfates, ether sulfates, monoglyceryl ether sulfates, sulfonates, sulfosuccinates, ether sulfosuccinates, sulfosuccinamates, amidosulfosuccinates, carboxylates, amidoethercarboxylates, succinates, sarcosinates, amino acids, taurates, sulfoacetates and phosphates.
20 . The composition of claim 15 wherein the anionic oil-in-water emulsifier is a phosphate ester.
21 . The composition of claim 15 , wherein the composition is essentially free of cationic emulsifiers.
22 . The composition of claim 15 , wherein the ratio of said anionic emulsifier to said non-ionic emulsifier is about 1.2 or less.