Amorphous propylene-ethylene copolymers
View Patent ↗Amorphous propylene-ethylene copolymers are described herein that can include high amounts of ethylene and exhibit desirable softening points and needle penetrations. The desirable combinations of softening points and needle penetrations in these propylene-ethylene copolymers allow them to have a broad operating window. Due their broad operating window, the propylene-ethylene copolymers can be utilized in a wide array of applications and products, including hot melt adhesives.
1. A copolymer comprising propylene and ethylene, wherein said copolymer has a softening point in the range of 90 to 137° C., wherein said copolymer has a needle penetration that is equal to y, wherein y is defined by the following formula:
y≦− 0.000000262249 x 6 +0.000172031278 x 5 −0.046669720165 x 4 +6.7017467794−38 x 3 −537.286013331959 x 2 +22,802.983472587 x −400,204.018086126
wherein x in the above formula is the softening point of said copolymer, wherein said copolymer comprises at least 14 weight percent of ethylene.
2. The copolymer of claim 1 , wherein said copolymer comprises in the range of 14 to 30 weight percent of ethylene.
3. The copolymer of claim 1 , wherein said copolymer comprises in the range of 40 to 85 weight percent of propylene.
4. The copolymer of claim 1 , wherein the weight ratio of propylene to ethylene in said copolymer is in the range of 1:1 to 15:1.
5. The copolymer of claim 1 , wherein said copolymer comprises at least one C 4 -C 10 alpha-olefin.
6. The copolymer of claim 1 , wherein said softening point of said copolymer is in the range of 110 to 138° C., wherein said needle penetration of said copolymer is in the range of 1 to 15 dmm.
7. The copolymer of claim 1 , wherein said softening point of said copolymer is in the range of 110 to 137° C., wherein said needle penetration of said copolymer is in the range of 1 to 22 dmm.
8. The copolymer of claim 1 , wherein said softening point of said copolymer is in the range of 110 to 120° C., wherein said needle penetration of said copolymer is in the range of 30 to 50 dmm.
9. The copolymer of claim 1 , wherein said softening point of said copolymer is in the range of 110 to 134° C, wherein said needle penetration of said copolymer is in the range of 1 to 25 dmm, wherein the weight ratio of propylene to ethylene in said copolymer is in the range of 1:1 to 10:1.
10. The copolymer of claim 1 , wherein said softening point of said copolymer is in the range of 110 to 124° C., wherein said needle penetration of said copolymer is in the range of 1 to 30 dmm, wherein the weight ratio of propylene to ethylene in said copolymer is in the range of 1:1 to 10:1.
11. The copolymer of claim 1 , wherein said copolymer has a Brookfield viscosity at 190° C., in the range of 500 to 30,000 cps.
12. An article comprising said copolymer of claim 1 .
13. An adhesive comprising said copolymer of claim 1 .
14. An adhesive of claim 1 wherein said copolymer has a softening point in the range of 110 to 140° C.
15. The adhesive of claim 14 , wherein said adhesive comprises in the range of 5 to 95 weight percent of said copolymer.
16. The adhesive of claim 14 , wherein said adhesive comprises in the range of 5 to 95 weight percent of at least one polymer.
17. The adhesive of claim 14 , wherein said adhesive comprises in the range of 0 to 70 weight percent of at least one tackifier.
18. The adhesive of claim 14 , wherein said needle penetration is in the range of 0.5 to 70 dmm.
19. The adhesive of claim 14 , wherein said adhesive has a peel strength in the range of 1 to 200 g/mm when applied at temperatures in the range of 100 to 145° C., wherein said adhesive has a peel strength in the range of 1 to 250 g/mm when applied at temperatures in the range of 145 to 180° C.
20. The adhesive of claim 14 , wherein said adhesive has a loop tack in the range of 0.1 to 50 lbf.