IP Library Granted Patent US 9,388,320
Granted Patent B2
US 9,388,320 · App. 14/569,676 · Granted Jul 12, 2016

Water cleanable phase change ink for ophthalmic lens marking

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Quick Facts
Patent No.
US 9,388,320
App. No.
14/569,676
Granted
Jul 12, 2016
Kind
B2
Abstract

A water dispersible phase change ink composition for printing on ophthalmic lenses including a hydrophilic wax having at least one ethoxyl moiety; a low viscosity wax having at least one hydroxyl group, wherein the low viscosity wax is miscible with the hydrophilic wax; an optional stabilizer; and a colorant. A ink jet printer stick or pellet comprising the water dispersible phase change ink composition.

Claims (33)

1. A water dispersible phase change ink composition for printing on ophthalmic lenses comprising:

a hydrophilic wax having at least one ethoxyl moiety;

a low viscosity wax having at least one hydroxyl group, wherein the low viscosity wax is miscible with the hydrophilic wax;

wherein the low viscosity wax is selected from the group consisting of stearyl alcohol, behenyl alcohol, and combinations thereof;

an optional stabilizer; and

a colorant.

2. The water dispersible phase change ink composition of claim 1 , further comprising:

an amide.

3. The water dispersible phase change ink composition of claim 1 , wherein the hydrophilic wax is an ethoxylated alcohol.

4. The water dispersible phase change ink composition of claim 1 , wherein the hydrophilic wax is an ethoxylated alcohol of the formula

CH 3 —(CH 2 CH 2 ) n —(CH 2 CH 2 O) m —H

wherein n is an integer and wherein m is an integer, and wherein n and m are each independently selected such that the total number of carbon atoms is from about 20 to about 50.

5. The water dispersible phase change ink composition of claim 1 , wherein the low viscosity wax is a wax having a viscosity of from about 1 to about 15 centipoise at a temperature in the range of from about 80° C. to about 120° C.

6. The water dispersible phase change ink composition of claim 1 , wherein the low viscosity wax behenyl alcohol.

7. The water dispersible phase change ink composition of claim 1 , wherein the amide is selected from the group consisting of monoamide, triamide, tetra-amide, and combinations thereof.

8. The water dispersible phase change ink composition of claim 1 , wherein the amide comprises a branched triamide.

9. The water dispersible phase change ink composition of claim 1 , wherein the stabilizer is present and is selected from the group consisting of aromatic amine, hindered amine, phenol, and combinations thereof.

10. The water dispersible phase change ink composition of claim 1 , wherein the stabilizer is an aromatic amine antioxidant.

11. The water dispersible phase change ink composition of claim 1 , wherein the colorant is selected from the group consisting of dyes, pigments, and combinations thereof.

12. The water dispersible phase change ink composition of claim 1 , wherein the colorant comprises a yellow dye.

13. The water dispersible phase change ink composition of claim 1 , wherein the colorant comprises a black dye.

14. An ink jet printer stick or pellet comprising a water dispersible phase change ink composition for printing on ophthalmic lenses, wherein the phase change ink composition comprises:

a hydrophilic wax having at least one ethoxyl moiety;

a low viscosity wax having at least one hydroxyl group, wherein the low viscosity wax is miscible with the hydrophilic wax;

wherein the low viscosity wax is selected from the group consisting of stearyl alcohol, behenyl alcohol, and combinations thereof;

an optional stabilizer, wherein the optional stabilizer, if present, is selected from the group consisting of hindered amine, phenol, and combinations thereof; and

a colorant.

15. The ink jet printer stick or pellet of claim 14 , further comprising:

an amide.

16. The ink jet printer stick or pellet of claim 14 , wherein the hydrophilic wax is an ethoxylated alcohol.

17. The ink jet printer stick or pellet of claim 14 , wherein the low viscosity wax is behenyl alcohol.

18. The ink jet printer stick or pellet of claim 14 , wherein the amide is selected from the group consisting of monoamide, triamide, tetra-amide, and combinations thereof.

19. The ink jet printer stick or pellet of claim 14 , wherein the colorant is a black dye or a yellow dye.

Assignments (10)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 6, 2025
From: XEROX CORPORATION
To: GENESEE VALLEY INNOVATIONS, LLC
Reel/Frame 073842/0479 →
SECOND LIEN NOTES PATENT SECURITY AGREEMENT Recorded Jul 2, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 071785/0550 →
FIRST LIEN NOTES PATENT SECURITY AGREEMENT Recorded Apr 11, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 070824/0001 →
SECURITY INTEREST Recorded Feb 13, 2024
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 066741/0001 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT RF 064760/0389 Recorded Feb 13, 2024
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: XEROX CORPORATION
Reel/Frame 068261/0001 →
SECURITY INTEREST Recorded Nov 20, 2023
From: XEROX CORPORATION
To: JEFFERIES FINANCE LLC, AS COLLATERAL AGENT
Reel/Frame 065628/0019 →
SECURITY INTEREST Recorded Jun 22, 2023
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 064760/0389 →
RELEASE OF SECURITY INTEREST IN PATENTS AT R/F 062740/0214 Recorded May 18, 2023
From: CITIBANK, N.A., AS AGENT
To: XEROX CORPORATION
Reel/Frame 063694/0122 →
SECURITY INTEREST Recorded Nov 10, 2022
From: XEROX CORPORATION
To: CITIBANK, N.A., AS AGENT
Reel/Frame 062740/0214 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 13, 2014
From: WU, BO; THOMAS, JULE W., JR.
To: XEROX CORPORATION
Reel/Frame 034501/0920 →