Pressure sensitive adhesive light guides
Optical devices include a light source and an optical article, where the optical article is an acid-free, non-yellowing pressure sensitive adhesive light guide. The light source is optically coupled to the light guide such that light emitted by the light source enters the light guide and is transported within the light guide by total internal reflection. The light guide includes a plurality of features oriented to extract light being transported within the light guide.
1. An optical device comprising:
a light source; and
an optical article comprising:
an acid-free, non-yellowing pressure sensitive adhesive light guide, wherein the light source is optically coupled to the acid-free, non-yellowing pressure sensitive adhesive light guide such that light emitted by the light source enters the acid-free, non-yellowing pressure sensitive adhesive light guide and is transported within the acid-free, non-yellowing pressure sensitive adhesive light guide by total internal reflection, and wherein the acid-free, non-yellowing pressure sensitive adhesive light guide comprises a first plurality of features oriented to extract light being transported within the acid-free, non-yellowing pressure sensitive adhesive light guide.
2. The optical device of claim 1 , wherein the acid-free, non-yellowing pressure sensitive adhesive light guide does not yellow upon exposure to UV radiation, heat, or a combination thereof.
3. The optical device of claim 1 , wherein the acid-free, non-yellowing pressure sensitive adhesive light guide comprises a (meth)acrylate pressure sensitive adhesive, the (meth)acrylate pressure sensitive adhesive being prepared from a reaction mixture comprising:
a first monomer comprising a monoethylenically unsaturated alkyl (meth)acrylate monomer;
a second monomer wherein, the second monomer is an acid-free reinforcing monomer,
and wherein a homopolymer of the second monomer has a Tg of at least about 20° C.; and
at least one initiator.
4. The optical device of claim 1 , wherein the acid-free, non-yellowing pressure sensitive adhesive light guide is also a base-free, non-yellowing pressure sensitive adhesive light guide.
5. The optical device of claim 1 , wherein the optical article further comprises an additional layer disposed on the acid-free, non-yellowing pressure sensitive adhesive light guide.
6. The optical device of claim 1 , further comprising a second plurality of features oriented to extract light being transported within the acid-free, non-yellowing pressure sensitive adhesive light guide, wherein the second plurality of features oriented to extract light being transported within the acid-free, non-yellowing pressure sensitive adhesive light guide is located opposite to the first plurality of features oriented to extract light being transported within the acid-free, non-yellowing pressure sensitive adhesive light guide.
7. The optical device of claim 1 , wherein the first plurality of features oriented to extract light being transported within the acid-free, non-yellowing pressure sensitive adhesive light guide comprises a nanovoided polymeric layer comprising a plurality of interconnected nanovoids.
8. The optical device of claim 3 , wherein the first monomer comprises a (meth)acrylate monomer having from 1-14 carbon atoms.
9. The optical device of claim 3 wherein the first monomer comprises a (meth)acrylate monomer having 6-14 carbon atoms.
10. The optical device of claim 3 , wherein the second monomer comprises a (meth)acrylate monomer comprising at least one hydroxyl group.
11. The optical device of claim 3 , wherein the second monomer comprises a (meth)acrylate monomer selected from 2,2-(diethoxy)ethyl acrylate, methyl methacrylate, isobornyl acrylate, 2-(phenoxy)ethyl acrylate, 2-(phenoxy)ethyl methacrylate, biphenylyl acrylate, tert-butylphenyl acrylate, cyclohexyl acrylate, dimethyladamantyl acrylate, 2-naphthyl acrylate, phenyl acrylate, or combinations thereof.
12. The optical device of claim 3 , wherein the reactive mixtures comprises 60-95% by weight first monomer; and 2-40% by weight second monomer.
13. The optical device of claim 3 , wherein the initiator comprises a photoinitiator.
14. The optical device of claim 3 , wherein the reaction mixture further comprises a crosslinker.
15. The optical device of claim 5 , wherein the additional layer disposed on the acid-free, non-yellowing pressure sensitive adhesive light guide comprises a substrate.
16. The optical device of claim 5 , wherein the additional layer comprises a multilayer optical film, a reflector, a mirror, a polarizer, a prismatic film, a three-quarter polarizer, a retroreflective film, a touch sensor, polymer, metal, glass, ceramic, a graphic, paper, fabric or a combination thereof.
17. The optical device of claim 10 , wherein the (meth)acrylate monomer comprising at least one hydroxyl group is selected from 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, 3-hydroxypropyl acrylate, 3-hydroxypropyl methacrylate, 4-hydroxybutyl acrylate, or a combination thereof.
18. The optical device of claim 14 , wherein the crosslinker comprises a di-fuctional or higher-functional (meth)acrylate crosslinker.
19. The optical device of claim 15 , wherein at least some of the light being transported within the acid-free, non-yellowing pressure sensitive adhesive light guide is emitted from the substrate.