Fluorescent sheet and light unit and liquid crystal display including the same
A color conversion film includes fluorescent dots and a polymer layer, the fluorescent dots distributed within the polymer layer; a barrier film at one surface of the color conversion film; and a transflective film at another surface of the color conversion film. An organic or inorganic phosphor may be partially or entirely applied to the fluorescent sheet and the transflective film is applied to a bottom surface of the fluorescent sheet, thereby enhancing light efficiency without causing harm to the environment, as well as reducing a manufacturing cost.
1. A fluorescent sheet comprising:
a color conversion film including a polymer layer and fluorescent dots, the fluorescent dots distributed within the polymer layer;
a barrier film at one surface of the color conversion film; and
a transflective film at another surface of the color conversion film,
wherein the fluorescent dots include an organic compound and an inorganic compound,
the fluorescent sheet does not comprise a semiconductor nanocrystal,
the organic compound and the inorganic compound include one or more of a green phosphor and a red phosphor,
the color conversion film contains 0.4 to 0.8 wt % of the fluorescent dots based on its total weight, and
the color conversion film is formed to have a thickness of 20 μm to 150 μm.
2. The fluorescent sheet of claim 1 , wherein
the green organic compound includes one or more of coumarin-based, fluorescein-based, cyanine-based, boron dipyrromethene-based, dansyl-based, acridine-based, SYBR green-based, and rhodamine-based compounds, and
the red organic compound includes one or more of rhodamine-based, DCM dicyanomethane-based, benzophenoxazine-based, boron dipyrromethene-based, perylene-based, and Nile red-based compounds.
3. The fluorescent sheet of claim 1 , wherein
the green inorganic compound includes one or more selected from oxide-based, sulfide-based, and nitride-based compounds, wherein
the oxide-based compound is (Sr,Ba,Ca,Mg) 2 SiO 4 :Eu 2+ or (Sr,Ba,Ca,Mg) 3 SiO 5 :Eu 2+ ,
the sulfide-based compound is SrGa 2 S 4 :Eu,
the nitride-based compound is (β-SiAlON:Eu 2+ ), (Sr,Ba)Si 2 O 2 N 2 :Eu 2+ , (Ba,Sr,Ca) 2 SiO 4 :Eu 2+ , or Ba 3 Si 6 O 12 N 2 :Eu 2+ , and
the red inorganic compound includes a nitride-based compound and one or more selected from (Sr,Ca)AlSiN 3 :Eu 2 and (Ba,Sr,Ca) 2 Si 5 N 8 :Eu 2+ .
4. The fluorescent sheet of claim 1 , wherein
the barrier film includes one or more selected from a polyethylene terephthalate (PET) film, polycarbonate (PC), and co-polyethylene terephthalate (CoPET).
5. The fluorescent sheet of claim 4 , wherein
the color conversion film and the barrier film further include an inorganic oxide, and
the inorganic oxide includes one or more selected from silica, alumina, titania, and zirconia.
6. The fluorescent sheet of claim 1 , wherein
the transflective film transmits blue light but reflects green and red light.
7. The fluorescent sheet of claim 6 , wherein
the transflective film includes a dielectric multilayer of a silicon oxide and a titanium oxide.
8. The fluorescent sheet of claim 6 , wherein
the transflective film is formed to have a thickness of 0.1 μm to 1.5 μm.
9. A light unit comprising:
a light source;
a fluorescent sheet installed to be spaced apart from the light source and converting incident light from the light source into white light to emit it toward a liquid crystal panel; and
a light guide panel positioned between the light source and the fluorescent sheet, wherein the fluorescent sheet includes:
a color conversion film including fluorescent dots and a polymer layer where the fluorescent dots are distributed;
a barrier film positioned at one surface of the color conversion film; and
a transflective film positioned at another surface of the color conversion film,
wherein the fluorescent dots include an organic compound and an inorganic compound, the fluorescent sheet does not comprise a semiconductor nanocrystal,
the organic compound and the inorganic compound include one or more of a green phosphor and a red phosphor,
the color conversion film contains 0.4 to 0.8 wt % of the fluorescent dots based on its total weight, and
the color conversion film is formed to have a thickness of 20 μm to 150 μm.
10. The light unit of claim 9 , wherein
the transflective film transmits blue light but reflects green and red light.
11. The light unit of claim 10 , wherein
the transflective film includes a dielectric multilayer of a silicon oxide and a titanium oxide, and is formed to have a thickness of 0.1 μm to 1.5 μm.
12. A liquid crystal display comprising:
a liquid crystal panel; and
a light unit positioned under the liquid crystal panel, wherein the light unit includes:
a light source;
a fluorescent sheet installed to be spaced apart from the light source and converting incident light from the light source into white light to emit it toward the liquid crystal panel; and
a light guide panel positioned between the light source and the fluorescent sheet, wherein the fluorescent sheet includes:
fluorescent dots and a polymer layer where the fluorescent dots are distributed;
a barrier film positioned at one surface of the color conversion film; and
a transflective film positioned at another surface of the color conversion film,
wherein the fluorescent dots include an organic compound and an inorganic compound, the fluorescent sheet does not comprise a semiconductor nanocrystal,
the organic compound and the inorganic compound include one or more of a green phosphor and a red phosphor,
the color conversion film contains 0.4 to 0.8 wt % of the fluorescent dots based on its total weight, and
the color conversion film is formed to have a thickness of 20 μm to 150 μm.
13. The liquid crystal display of claim 12 , wherein
the transflective film transmits blue light but reflects green and red light and includes a dielectric multilayer of a silicon oxide and a titanium oxide, and is formed to have a thickness of 0.1 μm to 1.5 μm.