Pressure-sensitive adhesive composition
Provided are a pressure-sensitive adhesive composition, a protective film, an optical device, and a display device. The pressure-sensitive adhesive composition may exhibit excellent storage stability, suitable low speed and high speed peel-off strengths after a crosslinking structure is formed, and have an excellent balance between them. Accordingly, the pressure-sensitive adhesive composition may exhibit an excellent protective effect when applied to a protective film, may be easily peeled in high speed peel-off and thus advantageous for a high speed process, and may exhibit an excellent antistatic property in the process.
1. A surface protective film comprising:
a surface protective base layer; and
an antistatic pressure-sensitive adhesive layer formed on one or both surfaces of the base layer, and comprising a pressure-sensitive adhesive composition in a crosslinked state, where the pressure-sensitive adhesive composition, having a low speed peel-off strength measured at a peeling angle of 180° and a peeling speed of 0.3 m/min with respect to an adherent having a surface energy of 30 mN/m or less is 1 to 40 gf/25 mm and high speed peel-off strength measured at a peeling angle of 180° and a peeling speed of 30 m/min with respect to an adherent having a surface energy of 30 mN/m or less is 10 to 150 gf/25 mm comprises:
an acrylic polymer comprising polymerization units of: 0.1 to 6.0 parts by weight of a monomer of Formula 1, 1 to 15 parts by weight of a dialkyl (meth)acrylamide, and 12 to 20 parts by weight of a hydroxyl group-containing monomer;
an ionic compound; and
a crosslinking agent;
where Q is hydrogen or an alkyl group having 1 to 4 carbon atoms, U is an alkylene group having 1 to 4 carbon atoms, Z is hydrogen, an alkyl group having 1 to 4 carbon atoms, or an aryl group having 6 to 20 carbon atoms, and m is a number of 1 to 12,
wherein the hydroxyl group-containing monomer comprises 0.1 to 15 parts by weight of a first monomer represented by Formula 2, in which an alkylene group of A and B has 1 to 3 carbon atoms, and 0.1 to 5 parts by weight of a second monomer represented by Formula 2, in which an alkylene group of A and B has 4 to 8 carbon atoms, and wherein a weight ratio (A/B) of the first monomer in the acrylic polymer and the second monomer in the acrylic polymer is in a range of from 4 to 10,
where Q is hydrogen or an alkyl group having 1 to 4 carbon atoms, A and B may be each independently an alkylene group, and n is a number of 0 to 10,
and wherein the crosslinking agent is an aliphatic isocyanate crosslinking agent.
2. The surface protective film according to claim 1 , wherein the ionic compound is an inorganic salt or an organic salt.
3. The surface protective film according to claim 1 , wherein the aliphatic isocyanate crosslinking agent is at least one selected from aliphatic cyclic isocyanate compound or an aliphatic non-cyclic isocyanate compound.
4. The surface protective film according to claim 3 , wherein the aliphatic cyclic isocyanate compound is an isocyanate compound selected from isophorone diisocyanate, methylene dicyclohexyl diisocyanate, or cyclohexane diisocyanate; a dimer and trimer of the isocyanate compound; or a reaction product of the isocyanate compound with a polyol.
5. The surface protective film according to claim 3 , wherein the aliphatic non-cyclic isocyanate compound is an alkylene diisocyanate compound having 1 to 20 carbon atoms; a dimer or trimer of the isocyanate compound; or a reaction product of the isocyanate compound with a polyol.
6. The surface protective film according to claim 1 , wherein the crosslinking agent is comprised at 0.01 to 20 parts by weight relative to 100 parts by weight of the polymer.
7. An optical device comprising the surface protective film according to claim 1 .
8. A display device comprising the optical device of claim 7 .
9. The surface protective film according to claim 1 , wherein the ratio (H/L) of the high speed peel-off strength (H) and the low speed peel-off strength (L) is from 1 to 15.