Cathode material composite having improved conductivity, cathode and electrochemical device having the same
The present disclosure refers to a cathode material composite having improved conductivity, and a cathode and electrochemical device having the cathode material composite. In accordance with one embodiment of the present disclosure, a conductive polymer is positioned on the surface of a shell present in the form of a tetragonal structure in the lithium manganese oxide, thereby enhancing electrical conductivity to be highly involved in reaction around 3V, and providing a conductive path to improve the capacity, life and rate characteristics of an electrochemical device.
1. A cathode material composite, comprising:
a spinel-structured lithium manganese oxide particle having a core-shell structure, wherein the core has a cubic structure and the shell has a tetragonal structure;
a conductive polymer disposed on the surface of the shell;
a conductive material; and
a polymer binder
wherein the conductive polymer is poly(3,4-ethylenedioxy)thiophene.
2. The cathode material composite of claim 1 , wherein the lithium manganese oxide is represented by the following formula (I):
Li 1+x M y Mn 2−x−y O 4−z Q z
wherein, x, y, and z satisfy 0≤x≤0.3, 0≤y≤1, and 0≤z≤1;
M is any one selected from the group consisting of Al, Mg, Ni, Co, Fe, Cr, V, Ti, Cu, B, Ca, Zn, Zr,Nb, Mo, Sr, Sb, W, Ti, Bi, and a mixture thereof; and
Q is any one selected from the group consisting of N, F, S, Cl, and a mixture thereof.
3. The cathode material composite of claim 1 , wherein the conductive material is any one selected from the group consisting of graphite, carbon fiber, carbon black, acetylene black, ketjen black, carbon nanotube, and a mixture thereof.
4. The cathode material composite of claim 1 , wherein the polymer binder is any one selected from the group consisting of polyvinylidene fluoride (PVDF), hexafluoro propylene (HFP), polyvinylidene fluoride-co-hexafluoro propylene, polyvinylidene fluoride-co-trichloroethylene, polymethyl methacrylate, polybutylacrylate, polyacrylonitrile, polyvinylpyrrolidone, polyvinylacetate, polyethylene-co-vinyl acetate, polyethylene oxide, polyarylate, cellulose acetate, cellulose acetate butyrate, cellulose acetate propionate, cyanoethyl pullulan, cyanoethyl polyvinyl alcohol, cyanoethyl cellulose, cyanoethyl sucrose, pullulan, carboxyl methyl cellulose, acrylonitrile-styrene-butadiene copolymer, polyimide, and a mixture thereof.
5. The cathode material composite of claim 1 , wherein the spinel-structured lithium manganese oxide is present in an amount ranging from 85 to 95 wt %, the conductive material is present in amount ranging from 1 to 7 wt %, the polymer binder is present in an amount ranging from 1 to 7 wt %, and the conductive polymer is present in an amount ranging from 0.5 to 1.5 wt %, based on the total weight of the cathode material composite.
6. A cathode, comprising a current collector and a cathode active material layer formed on the current collector,
wherein the cathode active material layer comprises the cathode material composite according to claim 1 .
7. An electrochemical device, comprising the cathode of claim 6 , an anode and a separator interposed between the cathode and the anode.
8. The electrochemical device according to claim 7 , wherein the electrochemical device is a lithium secondary battery.