IP Library Granted Patent US 9,454,092
Granted Patent B2
US 9,454,092 · App. 14/578,542 · Granted Sep 27, 2016

Electrophotographic photoreceptor, electrophotographic photoreceptor cartridge, and image forming apparatus

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Quick Facts
Patent No.
US 9,454,092
App. No.
14/578,542
Granted
Sep 27, 2016
Kind
B2
Abstract

An object of the invention is to provide an electrophotographic photoreceptor in which the adhesion of the photosensitive layer is highly satisfactorily maintained regardless of the magnitude of shrinkage, and both of excellent electrical properties and excellent image characteristics are achieved. The present invention relates to an electrophotographic photoreceptor comprising: a conductive support; and, provided thereon, at least an undercoat layer and a photosensitive layer, wherein the undercoat layer comprises a binder resin and the binder resin comprises a polyamide resin which has a degree of elastic deformation of 56.0% or higher.

Claims (53)

1. An electrophotographic photoreceptor, comprising:

a conductive support; and, provided thereon, at least an undercoat layer and a photosensitive layer,

wherein the undercoat layer comprises a binder resin and

wherein the binder resin comprises a polyamide resin having a degree of elastic deformation, as determined on the basis of the following measuring method, of 56.0% or higher:

[Measuring method] The polyamide resin is molded into a film having a thickness of 10 μm or larger, and examined with a Vickers indenter in an atmosphere having a temperature of 25° C. and a relative humidity of 50% under the conditions of a maximum indentation load of 5 mN, a load-increasing period of 10 seconds and a load-removing period of 10 seconds to obtain a maximum indentation depth, and the value at the maximum indentation depth is taken as the degree of elastic deformation.

2. The electrophotographic photoreceptor according to claim 1 , wherein the polyamide resin comprises a polyether structure.

3. The electrophotographic photoreceptor according to claim 1 , wherein the content of the polyamide resin is 25 parts by mass or higher per 100 parts by mass of the binder resin.

4. The electrophotographic photoreceptor according to claim 1 , wherein the photosensitive layer contains a polyarylate resin.

5. An electrophotographic photoreceptor cartridge, comprising:

the electrophotographic photoreceptor according to claim 1 ; and

at least one part selected from the group consisting of a charging part for charging the electrophotographic photoreceptor, an exposure part for exposing the charged electrophotographic photoreceptor to form an electrostatic latent image, a development part for developing the electrostatic latent image formed on the electrophotographic photoreceptor, and a cleaning part for cleaning the surface of the electrophotographic photoreceptor.

6. An image forming apparatus, comprising:

the electrophotographic photoreceptor according to claim 1 ;

a charging part for charging the electrophotographic photoreceptor;

an exposure part for exposing the charged electrophotographic photoreceptor to form an electrostatic latent image;

a development part for developing the electrostatic latent image formed on the electrophotographic photoreceptor; and

a cleaning part for cleaning the surface of the electrophotographic photoreceptor.

7. An electrophotographic photoreceptor comprising:

a conductive support; and, provided thereon, at least an undercoat layer and a photosensitive layer, which have been laminated in this order from the conductive-support side,

wherein the undercoat layer comprises a polyamide resin comprising:

at least one of a linear dicarboxylic acid component and a branched dicarboxylic acid component;

at least one of a lactam component and an aminocarboxylic acid component; and

polytetramethylene ether glycol as a polyether component.

8. The electrophotographic photoreceptor according to claim 7 , wherein the polyamide resin is a block copolymerized polyamide resin comprising: a polyamide block which comprises the at least one of a linear dicarboxylic acid component and branched dicarboxylic acid component and the at least one of a lactam component and aminocarboxylic acid component; and a polyether block which comprises the polyether component.

9. The electrophotographic photoreceptor according to claim 8 , wherein the block copolymerized polyamide resin has formula [1]:

-[HS-SS] n -  [1]

HS represents a hard segment, which is a polymer unit comprising at least one kind of polyamide block that comprises at least one of a lactam component and an aminocarboxylic acid component and at least one of a linear dicarboxylic acid component and a branched dicarboxylic acid component; and

SS represents a soft segment, which is a polymer unit comprising a polyether block that comprises at least one kind of polyether component.

10. The electrophotographic photoreceptor according to claim 9 , wherein the HS and SS in the block copolymerized polyamide resin represented by formula [1] are bonded to each other by an ester bond.

11. The electrophotographic photoreceptor according to claim 8 , wherein the polyether block includes polytetramethylene ether glycol or polypropylene ether glycol.

12. The electrophotographic photoreceptor according to claim 8 , wherein the content of the polyether block in the undercoat layer is 4% by mass or higher.

13. The electrophotographic photoreceptor according to claim 8 , wherein the polyamide block is obtained by polymerizing at least one of a lactam having a single structure and an aminocarboxylic acid having a single structure.

14. The electrophotographic photoreceptor according to claim 8 , wherein the block copolymerized polyamide resin contains no dimer acid component.

15. The electrophotographic photoreceptor according to claim 8 , wherein the block copolymerized polyamide resin contains no diamine component.

16. An electrophotographic photoreceptor comprising:

a conductive support; and, provided thereon, at least an undercoat layer and a photosensitive layer, which have been laminated in this order from the conductive-support side,

wherein the undercoat layer comprises a polyamide resin comprising:

at least one of a linear dicarboxylic acid component and a branched dicarboxylic acid component;

at least one of a lactam component and an aminocarboxylic acid component; and

a polyether component, and

wherein the polyamide resin has an ester bond.

17. The electrophotographic photoreceptor according to claim 16 , wherein the polyamide resin is a block copolymerized polyamide resin comprising: a polyamide block which comprises the at least one of a linear dicarboxylic acid component and branched dicarboxylic acid component and the at least one of a lactam component and aminocarboxylic acid component; and a polyether block which comprises the polyether component.

18. The electrophotographic photoreceptor according to claim 17 , wherein the block copolymerized polyamide resin has formula [1]:

-[HS-SS] n -  [1]

wherein:

HS represents a hard segment, which is a polymer unit comprising at least one kind of polyamide block that comprises at least one of a lactam component and an aminocarboxylic acid component and at least one of a linear dicarboxylic acid component and a branched dicarboxylic acid component; and

SS represents a soft segment, which is a polymer unit comprising a polyether block that comprises at least one kind of polyether component.

19. The electrophotographic photoreceptor according to claim 18 , wherein the HS and SS in the block copolymerized polyamide resin represented by formula [1] are bonded to each other by an ester bond.

20. The electrophotographic photoreceptor according to claim 17 , wherein the polyether block includes polytetramethylene ether glycol or polypropylene ether glycol.

21. The electrophotographic photoreceptor according to claim 17 , wherein the content of the polyether block in the undercoat layer is 4% by mass or higher.

22. The electrophotographic photoreceptor according to claim 17 , wherein the polyamide block is obtained by polymerizing at least one of a lactam having a single structure and an aminocarboxylic acid having a single structure.

23. The electrophotographic photoreceptor according to claim 17 , wherein the block copolymerized polyamide resin contains no dimer acid component.

24. The electrophotographic photoreceptor according to claim 17 , wherein the block copolymerized polyamide resin contains no diamine component.

Assignments (3)
CHANGE OF NAME Recorded Sep 5, 2017
From: MITSUBISHI RAYON CO., LTD.
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 043750/0834 →
MERGER Recorded Sep 4, 2017
From: MITSUBISHI CHEMICAL CORPORATION
To: MITSUBISHI RAYON CO., LTD.
Reel/Frame 043750/0207 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 22, 2014
From: YAMAZAKI, DAISUKE; HARADA, AIKO; IDA, KAZUTAKA
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 034563/0468 →