Carbon black in effect pigments
The present application is directed to combination effect pigments comprising an effect pigment and carbon black, wherein the carbon black is adherently deposited on the effect pigment interposed within the substrate and at least one subsequent layer of the effect pigment. This structure of the combination effect pigment results in advantageous non-staining properties of the pigment and maximizes color effects of the carbon black.
1. A combination effect pigment comprising
i) an effect pigment, which effect pigment comprises a platelet like substrate and at least one optical layer, and
ii) a layer of a hydrous oxide or a hydroxide precipitate of carbon black and a polyvalent cation and the layer of the hydrous oxide or a hydroxide precipitate of carbon black precipitate is between the substrate and the at least one optical layer, and the at least one optical layer is different than the layer of hydrous oxide or hydroxide precipitate of carbon black;
wherein the weight ratio of hydrous oxide or a hydroxide precipitate of carbon black to the polyvalent cation is from about 3 to 1 to about 1 to 3.
2. The combination effect pigment according to claim 1 , wherein the at least one optical layer is a SiO 2 layer.
3. The combination effect pigment according to claim 1 , wherein the combination effect pigment has only one optical layer.
4. The combination effect pigment according to claim 1 , wherein the hydrous oxide or the hydroxide precipitate of carbon black is interposed between two optical layers.
5. The combination effect pigment according to claim 1 , wherein the hydrous oxide or the hydroxide precipitate of carbon black is interposed between an optical layer and an SiO 2 layer.
6. The combination effect pigment according to claim 1 , wherein the hydrous oxide or the hydroxide precipitate of carbon black is in direct contact with the substrate.
7. The combination effect pigment according to claim 1 , wherein the optical layer is a metal oxide.
8. The combination effect pigment according to claim 7 , wherein the metal oxide is selected from the group consisting of TiO 2 , In 2 O 3 , ZrO 2 , Fe 2 O 3 , Fe 3 O 4 , Cr 2 O 3 , CeO 2 , ZnO, SnO 2 and mixtures thereof.
9. The combination effect pigment according to claim 1 , wherein the substrate is selected from the group consisting of iron oxide, synthetic mica, natural mica, basic lead carbonate, flaky barium sulfate, SiO 2 , Al 2 O 3 , TiO 2 , glass, ZnO, ZrO 2 , SnO 2 , BiOCl, chromium oxide, BN, MgO flakes, Si 3 N 4 , graphite, aluminum, titanium, aluminum alloys, bronzes, iron and perlite.
10. The combination effect pigment according to claim 1 wherein the polyvalent cation is selected from the group consisting of Al, Cr, Ti, Zn, Mg, Zr, Fe, Ce and Sn.
11. The combination effect pigment according to claim 10 , wherein the polyvalent cation is selected from the group consisting of Al(III), Zn(II), Mg(II), Ti(IV), Zr(IV), Fe(II), Fe(III), Ce(III) and Sn(IV).
12. The combination effect pigment according to claim 11 , wherein the polyvalent cation has a suitable anionic counterion selected from the group consisting of chloride, nitrate and sulfate.
13. The combination effect pigment according to claim 1 , wherein the carbon black loading on the effect pigment ranges from about 0.01 to about 3 wt. % based on the total weight of the uncoated substrate.
14. The combination effect pigment according to claim 9 , wherein the polyvalent cation ranges from about 0.01 to about 1 wt. % based on the total weight of the uncoated substrate.
15. A paint, ink-jet, coatings, printing ink, plastic, cosmetic, glazes for ceramics and glass containing the combination effect pigment according to claim 1 .
16. A cosmetic containing the combination effect pigment according to claim 1 .
17. The cosmetic according to claim 16 , wherein the cosmetic is in the form of sticks, ointments, creams, emulsions, suspensions, dispersions, powders or solutions.
18. The cosmetic according to claim 16 , wherein the cosmetic is a lipstick, mascara preparation, blusher, eye-shadows, foundation, eyeliners, powder or nail varnishes.
19. A method of preparing the combination effect pigment according to claim 1 comprising
providing a slurry or suspension of carbon black, platelets and a polyvalent cation,
forming a hydrous oxide or hydroxide precipitate with the polyvalent cation and carbon black at a given pH,
forming at least one optical layer over the precipitate, and
drying the formed combination effect pigment, with the proviso that the at least one optical layer is different than the carbon black.
20. A method of reducing carbon black staining in an effect pigment according to claim 1 comprising the steps of:
forming a hydrous oxide or a hydroxide precipitate of carbon black and a polyvalent cation on a platelet substrate and
at least partially covering of said precipitate with at least one subsequent layer,
with the proviso that the at least one subsequent layer is different than the precipitate of carbon black and the polyvalent cation.
21. The combination effect pigment according to claim 1 comprising a layer structure that is
Substrate/SiO 2 /Carbon Black Precipitate/SiO 2 ;
Substrate/Carbon Black Precipitate/SiO 2 ;
Substrate/Carbon Black Precipitate/TiO 2 ;
Substrate/TiO 2 /Carbon Black Precipitate/TiO 2 ;
Substrate/Carbon Black Precipitate/TiO 2 /SiO 2 ;
Substrate/TiO 2 /Carbon Black Precipitate/SiO 2 ;
Substrate/SiO 2 /TiO 2 /Carbon Black Precipitate/Fe 2 O 3 ;
Substrate/TiO 2 /Carbon Black/SiO 2 /Carbon Black Precipitate/TiO 2 ;
Substrate/Fe 2 O 3 /SiO 2 /Carbon Black Precipitate/TiO 2 /SiO 2 ;
Substrate/SnO 2 /TiO 2 /Carbon Black Precipitate/TiO 2 ;
Substrate/TiO 2 /SiO 2 /Carbon Black Precipitate/Fe 2 O 3 ;
Substrate/TiO 2 /SiO 2 /Carbon Black Precipitate/TiO 2 ;
Substrate/TiO 2 /Carbon Black Precipitate/SiO 2 /Fe 2 O 3 ;
Substrate/TiO 2 /Carbon Black Precipitate/SiO 2 /TiO 2 ;
Substrate/Fe 2 O 3 /SiO 2 /Carbon Black Precipitate/Fe 2 O 3 ;
Substrate/Fe 2 O 3 /SiO 2 /Carbon Black Precipitate/TiO 2 ;
Substrate/Fe 2 O 3 /Carbon Black Precipitate/SiO 2 /Fe 2 O 3 ;
Substrate/Fe 2 O 3 /Carbon Black Precipitate/SiO 2 /TiO 2 ; or
Substrate/TiO 2 /SiO 2 /Carbon Black Precipitate/Cr 2 O 3 .
22. The combination effect pigment according to claim 1 , wherein the weight ratio of hydrous oxide or a hydroxide precipitate of carbon black to the polyvalent cation is from about 2 to 1 to about 1 to 2.
23. The combination effect pigment according to claim 1 , wherein the weight ratio of hydrous oxide or a hydroxide precipitate of carbon black to the polyvalent cation is from about 1 to 1.5 to about 1.5 to 1.