FUEL CELLS AND METHODS WITH REDUCED COMPLEXITY
Described herein are methods, articles, and systems relating to planar fuel cells having simplified structures. The planar fuel cells include current collection circuits that are disposed between a planar array of unit fuel cells and associated cover layers. The associated cover layers are porous, dielectric, and define a network of interconnected pores.
1 . A fuel cell assembly, comprising:
a planar array of unit fuel cells, each unit fuel cell including
an electrolyte layer,
a first electrode disposed on a first side of the electrolyte layer, and
a second electrode disposed on a second side of the
electrolyte layer opposite the first side of the electrolyte layer;
a first dielectric cover layer disposed over a first side of the planar array;
a second dielectric cover layer disposed over a second side of the planar array opposite the first side of the planar array, wherein the first dielectric cover layer and the second dielectric cover layer both define a network of interconnected pores; and
a first portion of a current collecting component disposed on the first dielectric cover layer and in electrical communication with the planar array, wherein the first portion of a current collecting circuit contacts the first electrode of a plurality of the unit fuel cells; and
a second portion of a current collecting circuit disposed between the second dielectric cover layer and the planar array, wherein the second portion of a current collecting circuit contacts the second gas electrode of a plurality of the unit fuel cells.
2 . The fuel cell assembly of claim 1 , wherein the planar array includes a single continuous portion of material that forms the electrolyte layer of each unit fuel cell.
3 . The fuel cell assembly of claim 1 , wherein the planar array includes a plurality of insulating material layers disposed between neighboring unit fuel cells.
4 . The fuel cell assembly of claim 1 , wherein each unit fuel cell further includes a catalyst material.
5 . The fuel cell assembly of claim 4 , wherein the catalyst material is disposed as a catalyst layer between the electrolyte layer and the first electrode.
6 . The fuel cell assembly of claim 4 , wherein the catalyst material is located within the first electrode.
7 . The fuel cell assembly of claim 1 , wherein the first dielectric cover layer and the second dielectric cover layer are formed from a single sheet of material.
8 . The fuel cell assembly of claim 1 , wherein the first and second dielectric cover layers are formed from a material that does not substantially shrink or expand when exposed to water vapor, substantially shrink or expand in response to changes of temperatures within a range of about −40° C. to about 120° C., and does not substantially corrode when exposed to an acidic environment.
9 . The fuel cell assembly of claim 1 , wherein the first dielectric cover layer is bonded to the first side of the planar array and the second dielectric cover layer is bonded to the second side of the planar array.
10 . The fuel cell assembly of claim 1 , wherein a first portion of a current collecting circuit is bonded to the first dielectric cover layer and a second portion of a current collecting circuit is bonded to the second dielectric cover layer.
11 . The fuel cell assembly of claim 1 , wherein the current collecting circuit includes a wire, a trace on a PCB, or a ribbon.
12 . The fuel cell assembly of claim 1 , wherein the first electrode is made of carbon fiber paper or a combination of an electrically conductive material and a binder.
13 . The fuel cell assembly of claim 1 , further including a gasket surrounding an outer perimeter of the first dielectric cover layer.
14 . The fuel cell assembly of claim 1 , wherein the first dielectric cover layer is between about 100 μm and about 200 μm thick.
15 . The fuel cell assembly of claim 1 , wherein the first dielectric cover layer is thinner than the second dielectric cover layer.
16 . The fuel cell assembly of claim 1 , wherein the interconnected pores of the first dielectric cover layer make up between about 80% and about 90% of the total volume of the first dielectric cover layer.
17 . The fuel cell assembly of claim 1 , wherein the network of interconnected pores has an average pore size of less than 100 μm.
18 . The fuel cell assembly of claim 1 , wherein the first dielectric cover layer is less porous than the second dielectric cover layer.
19 . A method of producing electricity, comprising:
providing the fuel cell assembly of claim 1 ;
directing a fuel through the first dielectric cover layer and into contact with the first electrode; and
directing an oxidant through the second dielectric cover layer and into contact with the second electrode.
20 . A method of making a fuel cell assembly, comprising:
providing a planar array of unit fuel cells by disposing a first electrode layer on a first side of an electrolyte layer and disposing a second electrode layer on a second side of the electrolyte layer opposite the first side of the electrolyte layer;
disposing a first portion of a current collecting circuit on the first electrode layer, wherein the first portion of the current collecting circuit contacts the first electrode layer of a plurality of the unit fuel cells;
disposing a second portion of a current collecting circuit on the second electrode layer, wherein the second portion of the current collecting circuit contacts the second electrode layer of a plurality of the unit fuel cells;
disposing a first dielectric cover layer over a first side of the planar array; and
disposing a second dielectric cover layer over a second side of the planar array opposite the first side of the planar array, wherein the first dielectric cover layer and the second dielectric cover layer both define a network of interconnected pores.
21 . The method of claim 20 , wherein each unit fuel cell further includes a catalyst material.
22 . The method of claim 20 , wherein the first dielectric cover layer and the second dielectric cover layer are formed from a single sheet of material and disposing the first dielectric cover layer and disposing the second dielectric cover layer includes folding the single sheet of material around the planar array.
23 . The method of claim 20 , wherein disposing the first dielectric cover layer includes bonding the first dielectric cover layer to the first side of the planar array.
24 . The method of claim 20 , wherein disposing the first portion of a current collecting circuit includes bonding the first portion of a current collecting circuit to the first dielectric cover layer.