To reduce size and weight of canister while improving adsorbing/desorbing performance by optimizing adsorbent that fills chamber located at air release side. Adsorbent filling chambers 8, 9 located at air port 5 side, of a plurality of chambers 5˜8 that are arranged in series along an air flow direction in case 2, is formed by macroscopic pore whose diameter is 50 nm or greater. The adsorbent has hollow cylindrical shape whose inside thickness is 0.6 to 1.5 mm and whose outside diameter is 4 to 6 mm or hollow spherical shape whose inside thickness is 0.6 to 1.5 mm and whose diameter is 4 to 6 mm. A ratio of volume of the macroscopic pore whose diameter is less than 500 nm to total volume of the macroscopic pore whose diameter is equal to or greater than 50 nm is within a range of 30 to 70%.
1. A canister comprising:
a case;
a plurality of chambers which are arranged in series along an air flow direction in the case and filled with an adsorbent; and
an inflow portion and an outflow portion of fuel vapor which are provided at one end in the air flow direction in the case and an air release opening of the fuel vapor which is provided at the other end in the air flow direction in the case, and
the adsorbent filling at least the chamber located at an air release opening side, of the plurality of chambers, having a macroscopic pore whose diameter is equal to or greater than 50 nm and is less than 100000 nm, which is obtained by adding a meltable core that disappears during baking to powdery activated carbon having a microscopic pore whose diameter is less than 50 nm together with a binder and molding and baking this mixture,
the adsorbent filling at least the chamber located at the air release opening side, having a hollow cylindrical shape whose inside thickness is 0.6 mm to 1.5 mm and whose outside diameter is 4 mm to 6 mm or a hollow spherical shape whose inside thickness is 0.6 mm to 1.5 mm and whose diameter is 4 mm to 6 mm, and
a ratio of volume of the macroscopic pore whose diameter is equal to or greater than 50 nm and is less than 500 nm to a total volume of the macroscopic pore whose diameter is equal to or greater than 50 nm and is less than 100000 nm being within a range of 30% to 70%.
2. The canister as claimed in claim 1 , wherein
the adsorbent filling the chamber located at the air release opening side is an adsorbent whose difference of an equilibrium adsorption amount of n-butane concentration between vapor concentrations of 5 vol % and 50 vol % n-butane is greater than 35 g n-butane/L.
3. A canister comprising:
a case;
at least four chambers which are arranged in series along an air flow direction in the case and filled with an adsorbent; and
an inflow portion and an outflow portion of fuel vapor which are provided at one end in the air flow direction in the case and an air release opening of the fuel vapor which is provided at the other end in the air flow direction in the case, and
the adsorbent filling the chamber located at a first position from an air release opening side and the chamber located at a second position from the air release opening side, of the at least four chambers, having a macroscopic pore whose diameter is equal to or greater than 50 nm and is less than 100000 nm, which is obtained by adding a meltable core that disappears during baking to powdery activated carbon having a microscopic pore whose diameter is less than 50 nm together with a binder and molding and baking this mixture,
the adsorbent filling the chamber located at the first position from the air release opening side and the chamber located at the second position from the air release opening side, having a hollow cylindrical shape whose inside thickness is 0.6 mm to 1.5 mm and whose outside diameter is 4 mm to 6 mm or a hollow spherical shape whose inside thickness is 0.6 mm to 1.5 mm and whose diameter is 4 mm to 6 mm, and a ratio of volume of the macroscopic pore whose diameter is equal to or greater than 50 nm and is less than 500 nm to a total volume of the macroscopic pore whose diameter is equal to or greater than 50 nm and is less than 100000 nm being within a range of 30% to 70%.