Thermally conductive plastic compositions, extrusion apparatus and methods for making thermally conductive plastics
View Patent ↗A thermally conductive filler composition and a resin composition comprising such filler compositions. The filler composition comprises a blend of a boron nitride, a graphite, or a combination thereof, a talc, and optionally a silane. The filler composition can further comprise other filler components including, for example, wollastonite, calcium carbonate, or a combination thereof. The filler compositions can be added to a resin composition to provide a thermally conductive resin such as, for example, a thermally conductive plastic.
1. A filler composition comprising a blend of:
(a) a boron nitride, a graphite, or a combination thereof;
(b) a talc having an aspect ratio of at least 40, and
(c) a silane, wherein the silane is chosen from a thiocarboxylate silane, a blocked mercapto silane, or a combination thereof.
2. The filler composition of claim 1 , wherein the boron nitride, graphite, or the combination thereof is present in an amount of from about 5 weight percent to about 98 weight percent; the talc is present in an amount of from about 5 weight percent to about 80 weight percent; and the silane is present in an amount of up to about 6 weight percent.
3. The filler composition of claim 1 wherein the boron nitride, graphite, or the combination thereof is present in an amount of from about 5 weight percent to about 40 weight percent; the talc is present in an amount of from about 60 weight percent to about 95 weight percent; and the silane is present in an amount of up to about 3.5 weight percent.
4. The filler composition of claim 1 comprising boron nitride, wherein the boron nitride is chosen from boron nitride particles, boron nitride agglomerates, or a mixture thereof.
5. The filler composition of claim 4 , wherein the boron nitride comprises platelets having a particle size of 0.3 microns to about 200 microns.
6. The filler composition of claim 4 , wherein the boron nitride comprises boron nitride agglomerates having a mean particle size of from about 5 microns to about 500 microns.
7. The filler composition of claim 4 comprising a silane, wherein the silane is condensed on the surface of the blend of the boron nitride and the talc.
8. The filler composition of claim 1 comprising a silane, wherein the silane further comprises a silane chosen from an alkacryloxy silane, a vinyl silane, a halo silane, a mercapto silane, or a combination of two or more thereof.
9. The filler composition of claim 8 comprising a silane, wherein the silane is chosen from 3-octanoylthio-1-propyltriethoxy silane; vinyl tris(2-methoxy-ethoxy)silane; gamma-methacryloxypropyltreimethoxy silane, or a combination of two or more thereof.
10. The filler composition of claim 1 further comprising an additional filler component chosen from glass fibers, glass flake, clays, exfoliated clays, calcium carbonate, mica, wollastonite, clays, exfoliated clays, alumina, aluminum nitride, metallic powders or flakes of aluminum, copper, bronze, or brass, or a combination of two or more thereof, fibers or whiskers of carbon, graphite, aluminum, copper, bronze, brass, silicon carbide, silicon nitride, aluminum nitride, alumina, zinc oxide, or a combination of two or more thereof, carbon nanotubes, graphene, boron nitride nanotubes, boron nitride nanosheets, zinc oxide nanotubes, or a combination of two or more thereof.
11. The filler composition of claim 1 further comprising wollastonite, calcium carbonate, or a combination thereof in an amount of from about 2 weight percent to about 30 weight percent.
12. The filler composition of claim 1 , wherein the filler has a color on the L*, a*, b* scale with L* greater than 90, a* of −1.3 to 1.3, and b* of −2.5 to 2.5.
13. The filler composition of claim 1 , wherein the talc has an aspect ratio of at least 50.
14. The filler composition of claim 1 comprising a blend of (a) boron nitride and graphite present in an amount of from about 5 weight percent to about 98 weight percent; (b) talc present in an amount of from about 5 weight percent to about 80 weight percent; and (c) silane present in the amount of from about 0.1 weight percent to about 6 weight percent.
15. The filler composition of claim 1 comprising a blend of (a) boron nitride and graphite present in an amount of from about 5 weight percent to about 98 weight percent; (b) talc present in an amount of from about 5 weight percent to about 80 weight percent; and (c) silane present in the amount of from about 0.1 weight percent to about 6 weight percent; and (d) wollastonite, calcium carbonate, or a combination thereof in an amount from about 0.1 weight percent to about 60 weight percent.
16. The filler composition of claim 1 comprising a blend of (a) boron nitride in an amount of from about 5 weight percent to about 98 weight percent; (b) talc present in an amount of from about 5 weight percent to about 80 weight percent; and (c) silane present in the amount of from about 0.1 weight percent to about 6 weight percent.
17. The filler composition of claim 1 comprising a blend of (a) graphite in an amount of from about 5 weight percent to about 98 weight percent; (b) talc present in an amount of from about 5 weight percent to about 80 weight percent; and (c) silane present in the amount of from about 0.1 weight percent to about 6 weight percent.
18. A thermally conductive composition comprising:
a resin material; and
a thermally conductive filler composition dispersed in the polymer material, wherein the thermally conductive filler composition comprises a blend of (a) a boron nitride, a graphite, or a combination thereof; (b) a talc having an aspect ratio of at least 40, and (c) a silane, wherein the silane is chosen from a thiocarboxylate silane, a blocked mercapto silane, or a combination thereof, and the thermally conductive composition has an in-plane thermal conductivity of about 2 W/mK or greater, a through-plane thermal conductivity of about 0.9 W/mK or greater, or both.
19. The composition of claim 18 having an in-plane thermal conductivity of 3.0 W/mK or greater.
20. The composition of claim 18 having an in-plane thermal conductivity of 5 W/mK or greater.
21. The composition of claim 18 comprising a total thermally conductive filler concentration of about 58% by weight or less of the total weight of the composition.
22. The composition of claim 18 having a total thermally conductive filler content of about 40% or less by volume (v/v) of the composition.
23. The composition of claim 18 , wherein in the thermally conductive filler composition comprises boron nitride, graphite, or the combination thereof present in an amount of from about 5 weight percent to about 95 weight percent; talc present in an amount of from about 5 weight percent to about 95 weight percent; and silane present in an amount of from about 0.1 weight percent to about 6 weight percent.
24. The composition of claim 18 , wherein the silane further comprises a silane chosen from an alkacryloxy silane, a vinyl silane, a halo silane, a mercapto silane, or a combination of two or more thereof.
25. The composition of claim 24 , wherein the silane is chosen from 3-octanoylthio-1-propyltriethoxy silane; vinyl tris(2-methoxy -ethoxy)silane; gamma-methacryloxypropyltreimethoxy silane, or a combination of two or more thereof.
26. The composition of claim 18 , wherein the thermally conductive filler composition further comprises an additional filler component chosen from glass fibers, glass flake, clays, exfoliated clays, calcium carbonate, mica, wollastonite, alumina, aluminum nitride, metallic powders or flakes of aluminum, copper, bronze, or brass, or a combination of two or more thereof, fibers or whiskers of carbon, graphite, aluminum, copper, bronze, brass, silicon carbide, silicon nitride, aluminum nitride, alumina, zinc oxide, or a combination of two or more thereof, carbon nanotubes, graphene, boron nitride nanotubes, boron nitride nanosheets, zinc oxide nanotubes, or a combination of two or more thereof.
27. The filler composition of claim 18 , wherein the thermally conductive filler composition further comprises wollastonite, calcium carbonate, or a combination thereof in an amount of from about 0 weight percent to about 60 weight percent.
28. The filler composition of claim 18 comprising a blend of (a) boron nitride and graphite present in an amount of from about 5 weight percent to about 98 weight percent; (b) talc present in an amount of from about 5 weight percent to about 80 weight percent; and (c) silane present in the amount of from about 0.1 weight percent to about 6 weight percent.
29. The filler composition of claim 18 comprising a blend of (a) boron nitride and graphite present in an amount of from about 5 weight percent to about 98 weight percent; (b) talc present in an amount of from about 5 weight percent to about 80 weight percent; and (c) silane present in the amount of from about 0.1 weight percent to about 6 weight percent; and (d) wollastonite, calcium carbonate, or a combination thereof in an amount from about 0.1 weight percent to about 60 weight percent.
30. The filler composition of claim 18 comprising a blend of (a) boron nitride in an amount of from about 5 weight percent to about 98 weight percent; (b) talc present in an amount of from about 5 weight percent to about 80 weight percent; and (c) silane present in the amount of from about 0.1 weight percent to about 6 weight percent.
31. The filler composition of claim 18 comprising a blend of (a) graphite in an amount of from about 5 weight percent to about 98 weight percent; (b) talc present in an amount of from about 5 weight percent to about 80 weight percent; and (c) silane present in the amount of from about 0.1 weight percent to about 6 weight percent.
32. The filler composition of claim 18 comprising boron nitride wherein the boron nitride is chosen from boron nitride particles, boron nitride agglomerates, or a mixture thereof.
33. The composition of claim 32 , comprising a boron nitride concentration of from about 5 weight percent to about 41 weight percent of the composition.
34. The composition of claim 32 , comprising a boron nitride concentration of from about 5 weight percent to about 60 weight percent of the composition.
35. A filler composition comprising a blend of:
(a) from about 5 weight percent to about 95 weight percent of a boron nitride, a graphite, or a combination thereof;
(b) from about 5 weight percent to about 95 weight percent of a talc having an aspect ratio of at least 40;
(c) from about 0.1 weight percent to about 6 weight percent of a silane, wherein the silane is chosen from a thiocarboxylate silane, a blocked mercapto silane, or a combination thereof; and
(d) from about 0.1 weight percent to about 60 weight percent of wollastonite, calcium carbonate, or a combination thereof.
36. The filler composition of claim 35 , wherein the boron nitride, the graphite, or the combination thereof is present in an amount of from about 5 weight percent to about 95 weight percent; the talc in is present an amount of from about 5 weight percent to about 95 weight percent; the silane is present in an amount of from about 1 weight percent to about 3.5 weight percent; and the wollastonite, calcium carbonate, or the combination thereof is present in an amount of from about 1 weight percent to about 30 weight percent.
37. The filler composition of claim 35 comprising a blend of (a) boron nitride and graphite present in an amount of from about 5 weight percent to about 95 weight percent; (b) talc present in an amount of from about 5 weight percent to about 95 weight percent; (c) silane present in the amount of from about 0.1 weight percent to about 6 weight percent; and wollastonite, calcium carbonate, or a combination thereof present in an amount of from about 0.1 weight percent to about 60 weight percent.
38. The composition of claim 35 , wherein the silane further comprising a silane chosen from an alkacryloxy silane, a vinyl silane, a halo silane, a mercapto silane, or a combination of two or more thereof.
39. The filler composition of claim 35 comprising boron nitride, wherein the boron nitride is chosen from boron nitride particles, boron nitride agglomerates, or a combination thereof.
40. The filler composition of claim 35 comprising boron nitride, wherein the silane is condensed onto the blend of the boron nitride and the talc.