PDC cutter with chemical addition for enhanced abrasion resistance
A superabrasive cutter and a method of making the superabrasive cutter are disclosed. The superabrasive cutter may comprise a plurality of polycrystalline superabrasive particles and about 0.01% to about 4% by weight of the superabrasive particles of a dopant as evaluated prior to a high pressure/high temperature process. The dopant may be immiscible with a catalyst for forming the polycrystalline superabrasive particles.
1. A superabrasive cutter comprising:
a substrate;
a polycrystalline superabrasive composite bonded to the substrate, the polycrystalline superabrasive composite comprising:
a plurality of polycrystalline superabrasive particles that are sintered to form the polycrystalline superabrasive composite in a high pressure/high temperature process;
a catalyst that promotes sintering between the superabrasive particles; and
about 0.01% to about 4% by weight of the superabrasive particles of a dopant evaluated prior to the high pressure/high temperature process, wherein the dopant is substantially immiscible with the catalyst,
wherein:
the polycrystalline superabrasive composite comprises a first polycrystalline superabrasive zone that is substantially free of the catalyst and that is positioned distally from the substrate and a second polycrystalline superabrasive zone that is rich in the catalyst material and that is positioned proximally to the substrate.
2. The superabrasive cutter of claim 1 , wherein a wear rate of the superabrasive cutter evaluated after the second polycrystalline superabrasive zone is exposed in a wear scar is within about one standard deviation of the wear rate of the superabrasive cutter evaluated prior to second polycrystalline superabrasive zone being exposed.
3. The superabrasive cutter of claim 2 , wherein the wear rate of the superabrasive cutter evaluated after the second polycrystalline superabrasive zone is exposed in the wear scar is within about two standard deviations of the wear rate of the superabrasive cutter evaluated prior to the second polycrystalline superabrasive zone being exposed.
4. The superabrasive cutter of claim 1 , wherein a wear rate of the superabrasive cutter evaluated after the second polycrystalline superabrasive zone is exposed in a wear scar is within about 10% of the wear rate of the superabrasive cutter evaluated prior to second polycrystalline superabrasive zone being exposed.
5. The superabrasive cutter of claim 1 , wherein subjecting the superabrasive cutter to abrasion introduces a wear scar to the superabrasive cutter.
6. The superabrasive cutter of claim 1 , wherein the dopant comprises at least one of copper, gallium, lead, tin, or alloys thereof.
7. The superabrasive cutter of claim 1 , wherein the dopant has a lower melting temperature than the catalyst.
8. The superabrasive cutter of the claim 1 , wherein the dopant is present in an amount by weight of the superabrasive particles of less than about 1.0% evaluated prior to the high pressure/high temperature process.
9. The superabrasive cutter of the claim 1 , wherein the dopant is present in an amount by weight of the superabrasive particles in a range from about 1.0% to about 2.0% evaluated prior to the high pressure/high temperature process.
10. The superabrasive cutter of the claim 9 , wherein the dopant is present in an amount by weight of the superabrasive particles of less than about 1.5% evaluated prior to the high pressure/high temperature process.
11. The superabrasive cutter of claim 1 , wherein dopant is present in the polycrystalline superabrasive composite following the high pressure/high temperature process.
12. The superabrasive cutter of claim 1 , wherein dopant and catalyst are present in the first polycrystalline superabrasive zone in interstitial regions between adjacent superabrasive particles.
13. The superabrasive cutter of claim 1 , wherein a concentration of the dopant following the high pressure/high temperature process is less than the concentration of the dopant prior to the high pressure/high temperature process.
14. The superabrasive cutter of claim 1 , wherein a concentration of the dopant following the high pressure/high temperature process is less than a concentration of the catalyst as evaluated in the second polycrystalline superabrasive zone.
15. The superabrasive cutter of claim 1 , wherein a concentration of catalyst in the substrate prior to the high pressure/high temperature process is less than about 9.5 wt %.