Granted Patent B2

US 9,660,306 · App. 14/586,005 · Granted May 23, 2017

Abstract

Claims (49)

1. A lead-acid battery processing system, comprising:

an imaging system configured to perform imaging of a lead-acid battery using penetrating radiation and perform image analysis to determine a break point that divides top lead from a remainder of the lead content of the lead-acid battery, wherein the penetrating radiation comprises X-rays, gamma rays, or beta radiation; and

a battery breaking device configured to break the lead-acid battery at the determined break point and separate the lead-acid battery into a first portion, which includes the top lead, from a second portion, which includes the remainder of the lead content, for separate processing of the first and second portions of the lead-acid battery.

2. The system of claim 1 , wherein the top lead comprises terminal posts, bushings, and straps of the lead-acid battery.

3. The system of claim 1 , wherein the imaging system is configured to determine the break point such that the break point traverses a plurality of lugs that couple one or more grids to one or more straps of the lead-acid battery.

4. The system of claim 3 , wherein the top lead comprises a portion of the plurality of lugs.

5. The system of claim 1 , wherein the remainder of the lead content of the lead-acid battery comprises a plurality of grids and lead-bearing paste disposed in the second portion of the lead-acid battery.

6. The system of claim 1 , comprising:

a grinding device configured to receive and grind the first portion of the lead-acid battery to yield a mixture comprising top lead particles and polymer particles; and

a separation device configured to separate the top lead particles from the polymer particles.

7. The system of claim 1 , comprising a remelting device configured to receive and remelt the top lead to form a lead alloy for use in a new lead-acid battery, wherein the remelt does not remove one or more alloying metals of the top lead.

8. The system of claim 1 , wherein the imaging system comprises an X-ray imaging system configured to perform X-ray imaging of the lead-acid battery and to perform X-ray image analysis to determine the break point.

9. The system of claim 1 , wherein the imaging system comprises a penetrating radiation source and a penetrating radiation detection system configured to probe an internal structure of the spent battery to determine the break point.

10. The system of claim 9 , wherein the penetrating radiation source is an X-ray source, a gamma ray source, or a beta radiation source.

11. The system of claim 1 , comprising a pyrometallurgical or hydrometallurgical lead recovery system configured to receive and convert at least a portion of the remainder of the lead content of lead acid battery to metallic lead, lead oxide, or a combination thereof, for use in a new lead-acid battery.

12. The system of claim 1 , comprising a polymer recycling system configured to recover a portion of the polymer content of the lead-acid battery and to prepare the recovered portion of the polymer content for use in a new lead-acid battery.

13. The system of claim 1 , comprising sulfuric acid recovery and purification devices configured to recover a portion of the sulfuric acid content of the lead-acid battery and to prepare the recovered portion of the sulfuric acid content for use in a new lead-acid battery.

14. A method for selectively breaking and separately processing portions of a lead-acid battery, comprising:

determining, using a battery imaging system, a break point that divides top lead from a remainder of the lead content of the lead-acid battery, wherein the battery imaging system images the lead-acid battery using X-rays, gamma rays, or beta radiation; and

breaking the lead-acid battery at the determined break point using a battery breaking device; and

separating the lead-acid battery into a first portion, which includes the top lead, and a second portion, which includes the remainder of the lead content of the lead-acid battery.

15. The method of claim 14 , wherein determining the break point comprises:

performing an X-ray analysis of the lead acid battery using the battery imaging system; and

determining, using a processor of the battery imaging system, the break point to be below one or more straps of the lead-acid battery based on the X-ray analysis.

16. The method of claim 14 , comprising:

separating the top lead from a remainder of the first portion of the lead-acid battery;

remelting, using a remelting device, the top lead to form a lead alloy, wherein remelting does not substantially reduce a concentration of alloying metals in the top lead; and

using the remelted lead alloy to manufacture a new lead-acid battery.

17. The method of claim 16 , comprising constructing a terminal post, a bushing, a strap, or a grid for the new lead-acid battery from the lead alloy.

18. The method of claim 14 , comprising separating the remainder of the lead content of the lead-acid battery bottom lead into lead-bearing paste and bottom lead.

19. The method of claim 18 , comprising:

remelting the bottom lead to yield metallic lead or a lead alloy;

forming grids using the remelted metallic lead or lead alloy; and

manufacturing a new lead-acid battery using the formed grids.

20. The method of claim 18 , comprising pyrometallurgically or hydrometallurgically treating the lead-bearing paste to yield metallic lead, lead oxide, or a combination thereof.

21. The method of claim 20 , comprising:

forming grids or battery paste using the metallic lead and/or lead oxide; and

manufacturing a new lead-acid battery using the formed grids or battery paste.

22. A lead-acid battery processing system, comprising:

a controller comprising a memory and a processor configured to execute instructions stored in the memory to control operation of the lead-acid battery processing system;

an imaging system that images a lead-acid battery using X-rays, gamma rays, or beta radiation and provides the processor with image data, wherein the processor analyzes the image data to determine a break point that divides top lead of the lead-acid battery from a remainder of the lead content of the lead-acid battery;

a battery breaking device that breaks the lead-acid battery at the break point based on control signals provided by the processor of the control system and separates the lead-acid battery into a first portion, which includes the top lead, from a second portion, which includes the remainder of the lead content of the lead-acid battery;

a remelting device that receives and remelts the top lead from the first portion based on control signals provided by the processor of the controller, wherein the remelt yields a lead alloy that has similar alloying metal composition as the top lead and is suitable for use in new lead-acid batteries; and

a pyrometallurgical or hydrometallurgical lead recovery system that receives and converts the remainder of the lead content of lead acid battery to metallic lead, lead oxide, or a combination thereof, suitable for use in new lead-acid batteries.

23. The system of claim 22 , comprising a polymer recycling system configured to receive a portion of the polymer content from the first and/or second portions of the lead-acid battery and to prepare the portion of the polymer content for use in new lead-acid batteries.

24. The system of claim 22 , comprising a sulfuric acid recovery device configured to recover a portion of the sulfuric acid content from the second portion of the lead-acid battery and to prepare the portion of the sulfuric acid content for use in new lead-acid batteries.

25. The system of claim 22 , wherein the top lead comprises most or all of the terminal posts, bushings, and straps of the lead-acid battery.

26. The system of claim 25 , wherein the top lead does not include bottom lead grids or lead-bearing paste of the lead-acid battery.

27. The system of claim 26 , wherein the top lead comprises metallic lead and alloying metals.

Assignments (8)