Method for determining reducing agent slippage and motor vehicle employing the method

1. A method for determining reducing agent slippage from an exhaust-gas treatment device, the method comprising the following steps:

providing the exhaust-gas treatment device with:

an SCR catalytic converter;

a reducing agent metering-in location disposed upstream of the SCR catalytic converter in an exhaust-gas flow direction;

a device configured to determine a nitrogen oxide compound quantity upstream of the SCR catalytic converter in the exhaust-gas flow direction and configured to emit a sensor signal; and

a second nitrogen oxide sensor disposed downstream of the SCR catalytic converter in the exhaust-gas flow direction and emitting a sensor signal;

the device for determining a nitrogen oxide compound quantity and the second nitrogen oxide sensor not distinguishing between reducing agent and nitrogen oxide compounds;

regulating a quantity of reducing agent metered into the exhaust-gas treatment device by using a controlling element having an integral controlling component and a target value; and

with a controller:

a) determining a difference between the sensor signals of the second nitrogen oxide sensor and the device for determining a nitrogen oxide compound quantity;

b) determining a controlling deviation from the difference and the target value of the controlling element;

c) determining a gradient of the integral controlling component; and

d) identifying reducing agent slippage if the controlling deviation exceeds a first threshold value and the gradient exceeds a second threshold value.

2. The method according to claim 1 , which further comprises providing a storage catalytic converter for storing reducing agent upstream of the second nitrogen oxide sensor and downstream of the metering-in location in the exhaust-gas flow direction.

3. The method according to claim 1 , which further comprises activating the method when an internal combustion engine connected to the exhaust-gas treatment device is in a constant operating state.

4. The method according to claim 1 , which further comprises limiting the integral controlling component to a maximum value for a first time interval if reducing agent slippage has been identified in step d).

5. The method according to claim 1 , wherein the controller forms the controlling deviation by obtaining a difference between the target value and the difference between the sensor signals.

6. A motor vehicle, comprising:

an internal combustion engine emitting exhaust gases in an exhaust-gas flow direction;

an exhaust-gas treatment device for purification of the exhaust gases of said internal combustion engine, said exhaust-gas treatment device having:

an SCR catalytic converter;

a reducing agent metering-in location disposed upstream of said SCR catalytic converter in said exhaust-gas flow direction;

a device for determining a nitrogen oxide compound quantity upstream of said SCR catalytic converter in said exhaust-gas flow direction, said device emitting sensor signals and not distinguishing between reducing agent and nitrogen oxide compounds; and

a second nitrogen oxide sensor disposed downstream of said SCR catalytic converter in said exhaust-gas flow direction, said second nitrogen oxide sensor emitting sensor signals and not distinguishing between reducing agent and nitrogen oxide compounds;

a controlling element having an integral controlling component and a target value, said controlling element regulating a quantity of reducing agent metered into said exhaust-gas treatment device; and

a controller configured for:

a) determining a difference between said sensor signals of said second nitrogen oxide sensor and said device for determining a nitrogen oxide compound quantity;

b) determining a controlling deviation from said difference and said target value of said controlling element;

c) determining a gradient of said integral controlling component; and

d) identifying reducing agent slippage if said controlling deviation exceeds a first threshold value and said gradient exceeds a second threshold value.

7. The motor vehicle according to claim 6 , wherein said controller is configured to form the controlling deviation by obtaining a difference between said target value and said difference between said sensor signals.