IP Library Granted Patent US 10,059,778
Granted Patent B2
US 10,059,778 · App. 14/589,165 · Granted Aug 28, 2018

Production of poly alpha-1,3-glucan films

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Quick Facts
Patent No.
US 10,059,778
App. No.
14/589,165
Granted
Aug 28, 2018
Kind
B2
Abstract

The present invention is directed toward a process for making a poly alpha-1,3-glucan film. These films can be transparent or translucent and used in packaging applications.

Claims (16)

1. A process for making a poly alpha-1,3-glucan film comprising:

(a) dissolving poly alpha-1,3-glucan in a solvent composition to provide a solution of poly alpha-1,3-glucan, wherein the solvent composition is selected from the group consisting of aqueous sodium hydroxide, aqueous potassium hydroxide, and aqueous tetraethyl ammonium hydroxide;

(b) contacting the solution of poly alpha-1,3-glucan with a surface;

(c) removing the solvent composition to form a poly alpha-1,3-glucan film; and

(d) determining the film to have at least one of:

(i) haze less than about 10%;

(ii) breaking stress from about 10 to about 80 MPa;

(iii) tear strength from about 250 to about 3000 gf/mm;

(iv) Gurley air permeability less than about 10 s; and

(v) oxygen permeation rate less than about 0.3 cc-mm/m 2 day at 23° C., 0% relative humidity (RH).

2. The process according to claim 1 , wherein the process further comprises the addition of a plasticizer additive to the solution of the poly alpha-1,3-glucan of step (a) and wherein the plasticizer additive is glycerol.

3. The process according to claim 1 , wherein the step (c) removing the solvent composition comprises evaporation and coagulation in water, acid or alcohol.

4. A poly alpha-1,3-glucan film made according to claim 1 .

5. The process of claim 1 , wherein the solvent composition is aqueous sodium hydroxide.

6. The process of claim 1 , wherein the solvent composition is aqueous potassium hydroxide.

7. The process of claim 1 , wherein the solvent composition is aqueous tetraethyl ammonium hydroxide.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 28, 2020
From: DUPONT INDUSTRIAL BIOSCIENCES USA, LLC
To: NUTRITION & BIOSCIENCES USA 4, INC.
Reel/Frame 055028/0496 →
CORRECTIVE ASSIGNMENT TO CORRECT THE ENTITY TYPE PREVIOUSLY RECORDED AT REEL: 049879 FRAME: 0043. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Sep 6, 2019
From: E. I. DU PONT DE NEMOURS AND COMPANY
To: DUPONT INDUSTRIAL BIOSCIENCES USA, LLC
Reel/Frame 050300/0408 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 26, 2019
From: E. I. DU PONT DE NEMOURS AND COMPANY
To: DUPONT INDUSTRIAL BIOSCIENCES USA, LLC
Reel/Frame 049879/0043 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 19, 2015
From: MISHRA, VINDHYA; DENNES, T. JOSEPH
To: E. I. DU PONT DE NEMOURS AND COMPANY
Reel/Frame 035671/0381 →