Methods for fabrication of nanostructures
Systems and methods for fabricating nanostructures using other nanostructures as templates. A method includes mixing a dispersion and a reagent solution. The dispersion includes nanostructures such as nanowires including a first element such as copper. The reagent solution includes a second element such as silver. The second element at least partially replaces the first element in the nanostructures. The nanostructures are optionally washed, filtered, and/or deoxidized.
1. A method comprising:
mixing a dispersion and a reagent solution, the dispersion including nanostructures comprising a first element, the reagent solution including a second element, the second element replacing at least 60% of the first element in the nanostructures,
wherein a concentration of the nanostructures in the dispersion is between about 0.1 g/L and about 1 g/L,
wherein a concentration of the reagent solution is between about 0.1 M and about 0.15 M, and
wherein the reagent solution comprises at least one selected from a group consisting of silver nitrate and silver ions.
2. The method of claim 1 , wherein the nanostructures comprise nanowires.
3. The method of claim 2 , wherein length of the nanowires is about 50 microns to about 150 microns.
4. The method of claim 1 , wherein a dimension of the nanostructures is less than 500 nm.
5. The method of claim 1 , wherein the nanostructures have a length to width ratio greater than about 1,000:1.
6. The method of claim 1 , further comprising deoxidizing the nanostructures.
7. The method of claim 6 , wherein deoxidizing comprises mixing an acid and a first dispersion including oxidized nanostructures.
8. The method of claim 7 , further comprising filtering the mixed acid and first dispersion through a filter.
9. The method of claim 7 , wherein the acid comprises 0.05 M hydrochloric acid.
10. The method of claim 1 , wherein the first element is copper and the second element is silver.
11. The method of claim 1 , wherein the dispersion comprises at least one selected from a group consisting of water, organic solvent, ethanol, polyvinylpyrrolidone, and bile salts.
12. The method of claim 1 , wherein mixing comprises adding the reagent solution at least one of drop-wise, shower-wise, or mist-wise.
13. The method of claim 1 , wherein mixing comprises stirring.
14. The method of claim 1 , wherein the second element replaces at least 75% of the first element.
15. The method of claim 1 , wherein the dispersion includes at least one selected from a group consisting of dispersants and surfactants.
16. The method of claim 1 , further comprising before mixing, filtering the dispersion including the nanostructures comprising the first element and dispersing the filtered nanostructures.
17. The method of claim 16 , wherein filtering the nanostructures comprises using a non-fibrous filter.
18. The method of claim 1 , further comprising dispersing the nanostructures in a solvent.
19. A method comprising:
mixing a dispersion and a reagent solution, the dispersion including nanowires comprising copper, the reagent solution including silver, wherein the silver replaces at least 60% of the copper in the nanowires,
wherein length of the nanowires is about 50 microns to about 150 microns.
20. The method of claim 19 , wherein the dispersion comprises at least one selected from a group consisting of water, organic solvent, ethanol, polyvinylpyrrolidone, and bile salts.
21. The method of claim 19 , wherein mixing comprises adding the reagent solution at least one of drop-wise, shower-wise, or mist-wise.
22. The method of claim 19 , wherein a concentration of the nanowires in the dispersion is between about 0.1 g/L and about 1 g/L, and wherein a concentration of the reagent solution is between about 0.1 M and about 0.15 M.