IP Library Granted Patent US 10,532,349
Granted Patent B2
US 10,532,349 · App. 14/594,244 · Granted Jan 14, 2020

Disordered molecular sieve supports for the selective catalytic reduction of NO

Inventors: Paul J. Andersen (Plymouth Meeting, PA); John Leonello Casci (Redcar, GB); Hai-Ying Chen (Conshohocken, PA); Joseph M. Fedeyko (Malvern, PA)
Assignee: Johnson Matthey Public Limited Company
B01J29/80B01D53/9418B01J29/005B01J29/061B01J29/72B01J29/78B01J35/04B01J37/0246B01D2251/2062B01D2255/1021B01D2255/2073B01D2255/20738B01D2255/20746B01D2255/20761B01D2255/50B01D2257/404B01D2258/012B01J29/723B01J29/783B01J29/85B01J2029/062B01J2229/18B01J2229/62
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Quick Facts
Patent No.
US 10,532,349
App. No.
14/594,244
Granted
Jan 14, 2020
Kind
B2
Abstract

A catalyst for selective catalytic reduction of NO x having one or more transition metals selected from Cr, Mn, Fe, Co, Ce, Ni, Cu, Zn, Ga, Mo, Ru, Rh, Pd, Ag, In, Sn, Re, Ir, Pt, and mixtures thereof supported on a support, wherein the support has a molecular sieve having at least one intergrowth phase having at least two different small-pore, three-dimensional framework structures.

Claims (12)

1. A catalyst for selective catalytic reduction of NO x comprising:

a. one or more transition metals selected from the group consisting of Cr, Mn, Fe, Co, Ce, Ni, Cu, Zn, Ga, Mo, Ru, Rh, Pd, Ag, In, Sn, Re, Ir, Pt, and mixtures thereof, and

b. a support comprising a molecular sieve having at least one intergrowth phase consisting of an aluminosilicate, a silico-aluminophosphate, or aluminosilicate/silico-aluminophosphate combination having two different small-pore, three-dimensional framework structures,

wherein the first framework structure is CHA and the second framework structure is GME,

wherein the one or more transition metals are disposed inside the pores of the molecular sieve, on the external surface of the molecular sieve, or both inside the pores and on the external surface of the molecular sieve, and

wherein said transition metal is present in an amount of about 0.01 to about 6 weight percent, based on the total weight of the molecular sieve.

2. The catalyst of claim 1 , wherein the first and second framework structures are present in a mole ratio of about 1:99 to 99:1.

3. The catalyst of claim 1 , wherein the first and second framework structures are present in a mole ratio of about 5:95 to about 15:85.

4. The catalyst of claim 1 , wherein said transition metal is selected from the group consisting of Cu, Fe, Co, Pt, and Mn.

5. The catalyst of claim 1 , wherein said transition metal is Cu.

6. The catalyst of claim 1 , wherein said transition metal is present in an amount of about 1 to about 3 weight percent based on the total weight of the molecular sieve.

7. The catalyst of claim 5 , wherein said transition metal is present in an amount of about 1 to about 3 weight percent based on the total weight of the molecular sieve.

Assignments (2)
CHANGE OF ADDRESS Recorded Jan 14, 2026
From: JOHNSON MATTHEY PUBLIC LIMITED COMPANY
To: JOHNSON MATTHEY PUBLIC LIMITED COMPANY
Reel/Frame 074703/0733 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 24, 2015
From: ANDERSEN, PAUL J.; CASCI, JOHN LEONELLO; CHEN, HAI-YING; FEDEYKO, JOSEPH M.
To: JOHNSON MATTHEY PUBLIC LIMITED COMPANY
Reel/Frame 035486/0356 →
Continuity (4)
Continuation 13353873 · Jan 19, 2012
Continuation PCTUS2011028123 · Mar 11, 2011
Provisional Application 61312832 · Mar 11, 2010
Related Publication 20150141237A1 · May 21, 2015