Liquid crystal display device, method of manufacturing the same and alignment layer composition for the liquid crystal display device
A liquid crystal display device that includes an array substrate, an opposite substrate and a liquid crystal display layer is described. The array substrate includes a pixel electrode and a lower alignment layer. The pixel electrode has a plurality of slit portions extending in different directions. The lower alignment layer includes a reactive mesogen (RM) diamine is formed on the pixel electrode to induce an alignment direction of the liquid crystal molecules. An upper alignment layer is formed on a common electrode of the opposite substrate. The RM is cured at surfaces of the lower and upper alignment layers in response to ultraviolet (UV) light, so that liquid crystal molecules have a pretilt angle. Therefore, the aperture ratio and the response time may be improved, and afterimages may be decreased, so that display quality may be improved.
1. A method of manufacturing an LCD device, the method comprising:
forming a lower alignment layer on an array substrate comprising a pixel electrode having a plurality of slit portions inducing an alignment direction of liquid crystal molecules;
coupling an opposite substrate to the array substrate;
providing a liquid crystal layer between the lower alignment layer and the array substrate; and
irradiating the lower alignment layer with light under conditions in which an electric field is applied to the liquid crystal layer through the pixel electrode to provide a pretilt angle to liquid crystal molecules at a surface of the lower alignment layer,
wherein the lower alignment layer includes a polyimide including a reactive mesogen (RM) side chain chemically bonded to a backbone of the polyimide, wherein the polyimide is formed from an alignment layer composition including a reactive mesogen (RM) diamine,
wherein the reactive mesogen (RM) diamine includes a compound represented by
2. The method of claim 1 , further comprising:
forming an upper alignment layer on a common electrode of the opposite substrate before coupling the opposite substrate to the array substrate.
3. The method of claim 2 , wherein the upper alignment layer includes a polyimide formed from an alignment composition including a reactive mesogen (RM) diamine.
4. The method of claim 2 , wherein the common electrode corresponding to the pixel electrode has a continuous shape and does not include an opening.
5. The method of claim 2 , wherein the alignment layer composition further includes a base dianhydride, a base diamine, a crosslinker, and a vertical alignment diamine, the content of the reactive mesogen (RM) diamine being about 10 wt % to about 80 wt % based on a total weight of the base diamine, the vertical alignment diamine and the reactive mesogen (RM) diamine.
6. The method of claim 5 , wherein the alignment layer composition further comprises an initiator having the same structure as the reactive mesogen (RM) diamine.
7. The method of claim 1 , wherein the pixel electrodes are formed on a unit pixel area of the array substrate, and the slit portions are extended in different directions on a plurality of domains defined on each of the pixel electrodes.
8. The method of claim 7 , wherein the lower alignment and an upper alignment layer are configured so that a long axis of the liquid crystal molecules is vertically aligned when an electric field is not applied to the liquid crystal layer.
9. The method of claim 7 , wherein the lower alignment layer and an upper alignment layer are configured so that the long axis of the liquid crystal molecules is arranged in an extending direction of the slit portion at each of the domains when an electric field is applied to the liquid crystal layer.