HERBICIDAL COMPOSITION CONTAINING 4-AMINO-3-CHLORO-6-(4-CHLORO-2-FLUORO-3-METHOXYPHENYL) PYRIDINE-2-CARBOXYLIC ACID OR DERIVATIVES THEREOF, FLUROXYPYR OR DERIVATIVES THEREOF, AND PHENOXY AUXINS OR DERIVATIVES THEREOF
Provided herein are herbicidal compositions comprising a mixture comprising (a) 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid or an agriculturally acceptable ester, amide, or salt thereof, (b) fluroxypyr or an agriculturally acceptable ester, amide, or salt thereof, and (c) MCPA or 2,4-D or agriculturally acceptable esters, amides, or salts thereof. The compositions provide synergistic weed control of undesirable vegetation in areas including, but not limited to, cereals, rice, range and pasture areas, industrial vegetation management (IVM), and rights-of-way.
1 . A composition comprising a mixture comprising a herbicidally effective amount of (a) a compound of the formula (I):
or, with respect to its carboxylic acid moiety, an agriculturally acceptable salt, ester, or amide thereof,
(b) fluroxypyr or, with respect to its carboxylic acid moiety, an agriculturally acceptable ester, amide, or salt thereof, and
(c) one or more phenoxy auxins or an agriculturally acceptable ester, amide, or salt thereof.
2 . The composition of claim 1 , wherein the phenoxy auxin is MCPA.
3 . The composition of claim 1 , wherein the phenoxy auxin is 2,4-D.
4 . The composition of claim 1 , wherein the composition further comprises a herbicide safener.
5 . The composition of claim 4 , wherein the safener is cloquintocet acid or cloquintocet mexyl.
6 . The composition of claim 1 , wherein (a) is a C 1 -C 4 alkyl or benzyl ester of the compound of formula (I).
7 . The composition of claim 6 , wherein (a) is the methyl ester of the compound of formula (I).
8 . The composition of claim 1 , wherein (b) is fluroxypyr-meptyl.
9 . The composition of claim 1 , wherein (c) is MCPA 2-ethylhexyl ester.
10 . The composition of claim 1 , wherein (c) is 2,4-D 2-ethylhexyl ester.
11 . The composition of claim 1 , wherein the carboxylic acid equivalent weight ratio of (a) to (b) to (c) is from about 1:10:50 to about 1:30:120.
12 . The composition of claim 1 , wherein the carboxylic acid equivalent weight ratio of (a) to (b) to (c) is about 1 to about 15 to about 70.
13 . A method of controlling undesirable vegetation comprising contacting the undesirable vegetation, the area adjacent to the undesirable vegetation, water, or soil with a herbicidally effective amount of the composition of claim 1 .
14 . The method of claim 13 , wherein (a) is the methyl ester of the compound of formula (I), (b) is fluroxypyr-meptyl, and (c) is MCPA 2-ethylhexyl ester.
15 . The method of claim 13 , wherein (a) is the methyl ester of the compound of formula (I), (b) is fluroxypyr-meptyl, and (c) is 2,4-D 2-ethylhexyl ester.
16 . The method of claim 13 , wherein the undesirable vegetation is Canada fleabane ( Conyza canadensis , ERICA), chickweed ( Stellaria media , STEME), cleavers ( Galium aparine , GALAP), hemp-nettle ( Galeopsis tetrahit , GAETE), common lambsquarters ( Chenopodium album , CHEAL), kochia ( Kochia scoparia , KCHSC), common ragweed ( Ambrosia artemisiifolia , AMBEL), redroot pigweed ( Amaranthus retroflexus , AMARE), roundleaf mallow ( Malva pusilla , MALPU), stork's-bill ( Erodium cicutarium , EROCI), wild buckwheat ( Polygonum convolvulus , POLCO), ladysthumb ( Polygonum persicaria L., POLPE), absinth wormwood ( Artemisia absinthium , ARTAB), volunteer canola ( Brassica napus , BRSNN), volunteer alfalfa ( Medicago sativa , MEDSA), red clover ( Trifolium pretense, TRFPR), or giant ragweed ( Ambrosia trifida L., AMBTR).
17 . The method of claim 13 , wherein the composition is applied pre-emergently.
18 . The method of claim 13 , wherein the composition is applied post-emergently.
19 . The method of claim 13 , wherein the composition is applied at a use rate of 5 grams carboxylic acid equivalent weight per hectare (g ae/ha) of (a), 77 g ae/ha of (b), and 350 g ae/ha of (c).
20 . A kit for controlling undesirable vegetation comprising:
a first composition comprising a herbicidally effective amount of (a) a compound of the formula (I):
or, with respect to its carboxylic acid moiety, an agriculturally acceptable salt, ester, or amide thereof, and (b) fluroxypyr, or, with respect to its carboxylic acid moiety, an agriculturally acceptable ester, amide, or salt thereof, and
a second composition comprising a herbicidally effective amount of (c) one or more phenoxy auxins or an agriculturally acceptable ester, amide, or salt thereof,
wherein the first composition and the second composition are contained separately from each other in the kit.
21 . The kit of claim 20 , wherein the phenoxy auxin is MCPA.
22 . The kit of claim 20 , wherein the phenoxy auxin is 2,4-D.
23 . The kit of claim 20 , wherein the first and second compositions further comprise a herbicide safener.
24 . The kit of claim 23 , wherein the safener is cloquintocet acid or cloquintocet mexyl.
25 . The kit of claim 20 , wherein (a) is a C 1 -C 4 alkyl or benzyl ester of the compound of formula (I).
26 . The kit of claim 25 , wherein (a) is the methyl ester of the compound of formula (I).
27 . The kit of claim 20 , wherein (b) is fluroxypyr-meptyl.
28 . The kit of claim 20 , wherein (c) is MCPA 2-ethylhexyl ester.
29 . The kit of claim 20 , wherein (c) is 2,4-D 2-ethylhexyl ester.
30 . The kit of claim 20 , wherein the carboxylic acid equivalent weight ratio of (a) to (b) to (c) is from about 1:10:50 to about 1:30:120.
31 . The kit of claim 20 , wherein the carboxylic acid equivalent weight ratio of (a) to (b) to (c) is about 1 to about 15 to about 70.
32 . A method of controlling undesirable vegetation comprising contacting the undesirable vegetation, the area adjacent to the undesirable vegetation, water or soil with a herbicidally effective amount of
(a) a compound of the formula (I):
or, with respect to its carboxylic acid moiety, an agriculturally acceptable salt, ester, or amide thereof,
(b) fluroxypyr, or, with respect to its carboxylic acid moiety, an agriculturally acceptable ester, amide, or salt thereof, and
(c) one or more phenoxy auxins or an agriculturally acceptable ester, amide, or salt thereof.
33 . The method of claim 32 , wherein the phenoxy auxin is MCPA.
34 . The method of claim 32 , wherein the phenoxy auxin is 2,4-D.
35 . The method of claim 32 , wherein (a) is the methyl ester of the compound of formula (I), (b) is fluroxypyr-meptyl, and (c) is MCPA 2-ethylhexyl ester.
36 . The method of claim 32 , wherein (a) is the methyl ester of the compound of formula (I), (b) is fluroxypyr-meptyl, and (c) is 2,4-D 2-ethylhexyl ester.