Reverse emulsion breaker polymers
View Patent ↗The present invention generally relates to methods for resolving water and oil emulsions in the produced fluid of an oil production system comprising adding a reverse emulsion breaker to the produced fluid of the crude oil production system in an amount effective for resolving an oil-in-water emulsion. In particular, these methods for resolving an oil-in-water emulsion can be used in separation processes where the oil and solids in the produced fluid are separated from the produced water in the produced fluid.
1. A method of resolving a reverse emulsion in produced fluid of an oil production system comprising adding a reverse emulsion breaker to a produced fluid of the oil production system in an amount effective for resolving the reverse emulsion, the reverse emulsion breaker comprising a terpolymer, the terpolymer comprising repeat units of Formulae 1, 2, and 3:
wherein
R 1 , R 2 , and R 3 are independently hydrogen or alkyl;
R 4 , R 5 , R 6 , R 7 , and R 8 are independently alkyl;
p is an integer from 1 to 6; and
m, n, and o are integers wherein the molecular weight of the terpolymer is from about 20,000 to about 20,000,000 Daltons.
2. The method of claim 1 wherein the reverse emulsion is an oil-in-water emulsion, a water-in-oil-in-water emulsion, or a combination thereof.
3. The method of claim 2 wherein the reverse emulsion is a water-in-oil-in-water emulsion.
4. The method of claim 1 wherein R 1 , R 2 , and R 3 are independently hydrogen or methyl.
5. The method of claim 4 wherein R 1 and R 2 are hydrogen.
6. The method of claim 4 wherein R 4 , R 5 , R 6 , R 7 , and R 8 are independently methyl, ethyl, propyl, butyl, pentyl, or hexyl.
7. The method of claim 6 wherein R 4 , R 5 , R 6 , R 7 , and R 8 are methyl.
8. The method of claim 6 wherein p is 1 to 3.
9. The method of claim 1 wherein R 1 and R 2 are hydrogen; R 3 is methyl; R 4 , R 5 , R 6 , R 7 , and R 8 are methyl, and p is 3.
10. The method of claim 9 , wherein the molecular weight of the terpolymer is from about 800,000 to about 1,000,000 Daltons.
11. The method of claim 1 wherein the reverse emulsion breaker is water-soluble.
12. The method of claim 1 wherein the produced fluid of the oil production system is produced fluid from a steam-assisted gravity drainage production system or a cyclic steam stimulation system.
13. The method of claim 1 wherein the effective amount of the reverse emulsion breaker is from about 10 to about 500 based on the total volume of the produced fluid.
14. The method of claim 13 wherein the effective amount of the reverse emulsion breaker is from about 50 ppm to about 200 ppm based on the total volume of the produced fluid.
15. The method of claim 1 further comprising adding an emulsion breaker to the produced fluid of the oil production system.
16. The method of claim 15 wherein the emulsion breaker comprises an oxyalkylated phenol-formaldehyde resin, a resin ester, an oxyalkylated polyalkylamine, a polyol, a cross-linked polyol with a di- or multi-functional cross-linker, an isocyanate, an acid, or a combination thereof.
17. The method of claim 15 wherein the emulsion breaker and the reverse emulsion breaker have a synergistic effect for resolving the water-in-oil-in-water emulsion in the produced fluid of an oil production system.
18. The method of claim 1 wherein the value of m provides from about 28 mole percent to about 32 mole percent of the repeat unit of Formula 1, the value of n provides from about 51 mole percent to about 55 mole percent of the repeat unit of Formula 2, and the value of o provides from about 14 mole percent to about 18 mole percent of the repeat unit of Formula 3.