Copper CHA zeolite catalysts
View Patent ↗Zeolite catalysts and systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stable at high reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica to alumina ratio from about 15:1 to about 256:1 and a copper to alumina ratio from about 0.25:1 to about 1:1.
1. A catalyst comprising: an aluminosilicate zeolite having the CHA crystal structure and a mole ratio of silica to alumina from about 15 to about 150 and an atomic ratio of copper to aluminum from about 0.25 to about 1, the catalyst effective to promote the reaction of ammonia with nitrogen oxides to form nitrogen and H 2 O selectively, wherein the zeolite comprises Cu-SSZ-13.
2. The catalyst of claim 1 , wherein the mole ratio of silica to alumina is from about 15 to about 100.
3. The catalyst of claim 2 , wherein the mole ratio of silica to alumina is from about 25 to about 40.
4. The catalyst of claim 2 , wherein the mole ratio of silica to alumina is about 30.
5. The catalyst of claim 2 , wherein the atomic ratio of copper to aluminum is from about 0.30 to about 0.50.
6. The catalyst of claim 2 , wherein the atomic ratio of copper to aluminum is about 0.40.
7. The catalyst of claim 2 , wherein the mole ratio of silica to alumina is from about 25 to about 40 and the atomic ratio of copper to aluminum is from about 0.30 to about 0.50.
8. The catalyst of claim 2 , wherein the mole ratio of silica to alumina is about 30 and the atomic ratio of copper to alumina is about 0.40.
9. The catalyst of claim 2 , wherein the catalyst contains ion-exchanged copper and non-exchanged copper.
10. The catalyst of claim 9 , wherein the NO x conversion performance of the catalyst at about 200° C. after aging is at least 90% of the NO x conversion performance of the catalyst at about 200° C. prior to aging.
11. The catalyst of claim 9 , wherein the catalyst contains at least about 2.00 weight percent copper oxide.
12. The catalyst of claim 2 , wherein the catalyst is deposited on a honeycomb substrate.
13. The catalyst of claim 12 , wherein the honeycomb substrate comprises a wall flow filter substrate.
14. The catalyst of claim 12 , wherein the honeycomb substrate comprises a flow through substrate.
15. The catalyst of claim 14 , wherein at least a portion of the flow through substrate is coated with CuCHA adapted to reduce oxides of nitrogen contained in a gas stream flowing through the substrate.
16. The catalyst of claim 13 , wherein at least a portion of the wall flow substrate is coated with CuCHA adapted to reduce oxides of nitrogen contained in a gas stream flowing through the substrate.
17. An exhaust gas treatment system comprising the catalyst of claim 15 disposed downstream from a diesel engine and an injector that adds a reductant to an exhaust gas stream from the engine.
18. An exhaust gas treatment system comprising the catalyst of claim 16 disposed downstream from a diesel engine and an injector to add a reductant to an exhaust gas stream from the engine.
19. An exhaust gas treatment system comprising an exhaust gas stream containing NO x , and a catalyst in accordance with claim 2 effective for selective catalytic reduction of at least one component of NO x in the exhaust gas stream.
20. The catalyst of claim 12 , wherein the substrate comprises a high efficiency open cell foam filter.
21. An exhaust gas treatment system comprising the catalyst of claim 2 and further comprising a catalyzed soot filter.
22. The exhaust gas treatment system of claim 21 , wherein said catalyzed soot filter is upstream of said catalyst.
23. The exhaust gas treatment system of claim 21 , wherein said catalyzed soot filter is downstream of said catalyst.
24. The exhaust gas treatment system of claim 21 , further comprising a diesel oxidation catalyst.
25. The exhaust gas treatment system of claim 24 , wherein said diesel oxidation catalyst is upstream of said catalyst comprising Cu-SSZ-13.
26. The catalyst of claim 3 , wherein the catalyst is deposited on a honeycomb wall flow filter substrate to provide a catalyst article.
27. The catalyst of claim 3 , wherein the catalyst is deposited on a honeycomb flow through substrate to provide a catalyst article.
28. An exhaust gas treatment system comprising the catalyst article of claim 27 disposed downstream from a diesel engine and an injector that adds a reductant to an exhaust gas stream from the engine.
29. The catalyst of claim 1 , wherein the mole ratio of silica to alumina from about 15 to about 75.
30. The catalyst of claim 1 , wherein the mole ratio of silica to alumina from about 15 to about 50.