Heat treatments of ALM formed metal mixes to form super alloys
View Patent ↗A method of forming an article includes forming a layer of a mixture of at least two distinct metal powders selected such that when combined they are chemically in the proportions of a superalloy containing a gamma prime phase, and fusing the powders locally without diffusion to define the shape of a part of the article such that the materials of the distinct metal powders remain substantially chemically segregated forming regions of different chemical composition. The method further includes repeating the forming and fusing until the derived article is formed, and heat treating the finished article such that at least one of the distinct separate materials diffuses to form a gamma prime phase containing superalloy with the other.
1. A method of forming a superalloy article using additive layer manufacturing (ALM) building and heat treatment processes, the method comprising:
(i) procuring a mixture of two or more powder components that each chemically make up only part of the composition of a desired superalloy but which together are chemically proportionate to the composition of the desired superalloy;
(ii) performing an ALM process using the mixture, the ALM process comprising building the article layer-by-layer by forming layers comprising the mixture one on another and selectively applying sufficient energy to regions of each of layers to fully melt said two or more powder components in the layers and produce a substantially dense ‘mix’ in the shape of an article that is not the desired superalloy but which is characterised as having a sufficiently low stress and so as not to crack during the building or a specified heat treatment process; and
(iii) subsequently performing the specified heat treatment process, wherein the heat treatment process comprises heat treating the article to form the desired superalloy, whereby the desired superalloy does not crack during the heat treatment process.
2. A method as claimed in claim 1 to form a superalloy containing an additive X at a concentration C, and wherein the step of procuring two or more powder components includes:
blending two powders A and B wherein powder A is an intended bulk constituent of the superalloy and is provided in a concentration of x=(C x ) A selected to allow processing without cracking;
powder B is a minor constituent of the intended superalloy and is provided with a concentration of x=(C x ) B ; and
powders A and B are blended together so that B is a fraction of the whole such that C x =f (C x ) B +(1−f) (C x ) A and wherein (C x ) B >(C x ) A .
3. A method as claimed in claim 1 wherein the superalloy is a nickel based superalloy.
4. A method as claimed in claim 1 wherein the superalloy includes an additive x.
5. A method as claimed in claim 4 wherein x is aluminium or titanium or both.
6. A method as claimed in claim 5 wherein x forms more than 3.5% by weight of the powders.
7. A method as claimed in claim 1 wherein more than 50% by weight of the mixture of powder components is powder comprising at least one metal which when forming parts of the article in said ‘mix’ during the ALM process does not crack during.
8. A method as claimed in claim 7 wherein the more than 50% of the mixture is of Ni, Cr or Fe or a mixture or alloy of at least two of them.
9. A method as claimed in claim 1 wherein during the ALM process the two or more powder components are fully melted but resulting materials of the metal powders remain as substantially segregated forming regions of the article with differing chemical compositions.
10. A method as claimed in claim 1 , wherein the heat treating includes solutioning and aging steps.
11. A method as claimed in claim 1 , wherein the heat treating of the article to form the desired superalloy comprises forming a desired microstructure of the desired superalloy.
12. A method of forming a superalloy article including:
(i) procuring a mixture of two or more powder components that each chemically make up only part of the composition of a desired superalloy but which together are chemically proportionate to the composition of the desired superalloy;
(ii) performing an additive layer manufacturing (ALM) process, comprising building an article layer-by-layer using the mixture, to produce a substantially dense ‘mix’ in the shape of the article that is not the desired superalloy but which is characterised as having a sufficiently low stress and so as not to crack during the building or a specified heat treatment process; and
(iii) subsequently performing the specified heat treatment process, wherein the heat treatment process comprises heat treating the article to form the desired superalloy, whereby the desired superalloy does not crack during the heat treatment process; and
wherein during the ALM process the two or more powder components are fully melted but resulting materials of the metal powders remain substantially segregated forming regions of the article with differing chemical compositions.
13. A method as claimed in claim 12 , wherein the heat treating of the article to form the desired superalloy comprises forming a desired microstructure of the desired superalloy.
14. A method as claimed in claim 12 wherein the superalloy includes an additive x.
15. A method as claimed in claim 14 , wherein the heat treating causes the additive to diffuse out of at least one of the substantially segregated regions, having a concentration of the additive highest among those of the segregated regions, into at least another of the substantially segregated regions to form the desired superalloy.